, , Title , Contents

20. United States


Acronyms


ADI Acceptable Daily Intake
AEC Army Environmental Centre
AFB Air Force Base
AST Aboveground Storage Tank
ARAR Applicable or Relevant and Appropriate Requirement
ARSDR Agency of Toxic Substances and Desease Registry
ATTIC Alternative Treatment Technology Information Centre
BBS Bulletin Board System
Bldg. Building
BRAC Base Realignment and Closure
CAP Corrective Action Plan
CCS Contaminated Civil Site
CDI Chronic Daily Intake
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
CES Cost Estimating System
CFR Code of Federal Regulations
CHF Contaminant Hazard Factor
CLEAN Comprehensive Long-Term Environmental Action Navy
CMI Corrective Measures Implementation
CMS Contaminated Military Site
CMSt Corrective Measures Study (Note: the common acronym for this term is "CMS"; however, CMSt is used in this document)
COPC Contaminants of Potential Concern
CS Confirmation Study
DERA Defence Environmental Restoration Account
DERP Defence Environmental Restoration Programme
DLA Defence Logistics Agency
DOD Department of Defence
DOE Department of Energy
DOI Department of Interior
DPM Defence Priority Model
DSMOA Defence and State Memorandum of Agreement
EA Environmental Assessment
EBS Environmental Baseline Survey
EE/CA Engineering Evaluation and Cost Analysis
EPA Environmental Protection Agency
EPC Exposure Point Concentration
EPCRA Emergency Planning and Community Right-to-Know
ERA Ecological Risk Assessment
ERPS Environmental Restoration Priority System
FDA Food and Drug Administration
FR Federal Register
FS Feasibility Study
FUDS Formerly Used Defence Site
FY Fiscal Year
GAO General Accounting Office
HEAST Health Effects Assessment Summary Tables
HI Hazard Index
HHBRA Human Health Baseline Risk Assessment
HQ Hazard Quotient
HRS Hazard Ranking System
HSWA Hazardous and Solid Waste Amendments
IAS Initial Assessment Study
IRA Interim Remedial Action
IRIS Integrated Risk Information System
IRP Installation Restoration Programme
LOAEL Lowest Observed Adverse Effects Level
LTM Long-Term Monitoring
MCACES Microcomputer Aided Cost Estimating System
MCL Maximum Concentration Level
MF Modifying Factor
MILCON Military Construction
NAVFAC Naval Facilities
NCP National Contingency Plan
NECA Navy Environmental Compliance Act
NEPA National Environmental Policy Act
NIOSH National Institute of Safety and Health
NOAEL No Observed Adverse Effects Level
NPDES National Pollutant Discharge Elimination System
NPL National Priorities List
O&M Operation and Maintenance
OMB Office of Management and Budget
OSHA Federal Occupational Safety and Health Administration
PA Preliminary Assessment
PCB Polychlorinated Biphenyl
POL Petroleum, Oil, and Lubricants
POTW Publicly Owned Treatment Works
PRG Preliminary Remediation Goal
PRP Primary Responsible Party
RA Remedial Action
RAB Restoration Advisory Board
RAC Remediation Action Contract
RAGS Risk Assessment Guidance for Superfund
RBC Risk-Based Concentration
RCRA Resource Conservation and Recovery Act
R&D Research & Development
RD Remedial Design
REAMS Risk Exposure and Analysis Modelling System
RfC Reference Concentration
RfD Reference dose
RFA RCRA Facility Assessment
RFI RCRA Facility Investigation
RFI/CMSt RCRA Facility Investigation/Corrective Measures Study
RI Remedial Investigation
RI/FS Remedial Investigation and Feasibility Study
ROD Record of Decision
SARA Superfund Amendments and Reauthorization Act of 1986
SCS Suspected Contaminated Site
SDWA Safe Drinking Water Act
SF Slope Factor
SI Site Inspection
SOFA Status of Forces Agreements
SMCL Secondary Maximum Contaminant Level
SWMU Solid Waste Management Unit
TRC Technical Review Committee
UCL Upper Confidence Limit
UF Uncertainty Factor
UR Unit Risk
US United States
USCG US Coast Guard
UST Underground Storage Tank
UXO Unexploded Ordnance
WWTP Wastewater Treatment Plant

20.-1.0 Introduction


The United States of America consists of 50 states and one district (District of Columbia) which occupy approximately 9,372,610 square kilometres. The US population exceeds 260 million people with approximately 75 percent of the population living in urban areas. The US covers a large range of terrain consisting of the vast central plain, mountains in the west, hills and low mountains in the east, rugged mountains in Alaska and rugged volcanic topography in Hawaii.
The US Department of Defence (DOD) directs the operations of the US military consisting of the Department of Army (Army), the Department of Navy (Navy), and Department of Air Force. The Marine Corps is included in the Department of Navy. DOD is headed by the Secretary of Defence. The DOD was organized in 1949 as an outgrowth of the National Security Act of 1947. The DOD replaced the separate War and Navy departments with a unified military establishment. DOD is by far the largest of the federal departments.
For decades, the United States (US) Federal activities and industrial facilities generated, stored, recycled, and disposed of hazardous waste, which often contaminated nearby soil and groundwater. In many instances, these problems predate existing environmental regulations and laws. The DOD and the Department of Energy (DOE) own and operate thousands of installations, ranging from training bases to industrial production facilities. Many of these defence facilities have been operating for over a century. During this time, the agencies, like much of American society, operated them without full respect for the environment. As a result, the defence agencies now have more than 17,000 sites that require environmental clean-up.
The United States government has established various programmes, regulations, and funds for the purpose of investigating and remediating contaminated sites throughout the United States for military, civil, and other government facilities.

20.-2.0 Definitions


Suspected Contaminated Site (SCS)
A suspected contaminated site is a site that, due to the nature of historical or current operations and/or disposal practices, is considered to have the potential to be classified as a contaminated site, but there is no data or only limited data available to suggest that the site is contaminated. Identification of suspected contaminated sites is essential in establishing where preliminary site assessments and investigations will be required.
Contaminated Site
In general, a site is considered to be a contaminated site when the concentration of one or more substances in the soil, groundwater, surface water or other media degrade the natural quality of the environment; impair the usefulness of natural resources; offend the senses of sight, taste or smell; or cause a health hazard. In order to identify a site as contaminated, the United States (US) Environmental Protection Agency (EPA), the Federal environmental regulating agency in the US, has established regulatory threshold levels for different contaminants (e.g., maximum contaminant levels (MCLs), action levels, clean-up levels, etc.).
Once these regulatory threshold levels are exceeded, the site is considered to be contaminated. These threshold levels are identified in different US EPA regulations, depending on the type of contaminant, source of contamination and the media contaminated. EPA regulatory threshold levels have been established for contaminants in groundwater and surface water; however, in most cases, regulatory levels for soil and sediment contaminants do not exist. The US EPA has developed health-based and risk-based concentrations (RBCs) to be used as guidelines for evaluating site investigation data and preliminary remediation goals.
Although EPA has established regulatory threshold levels, State and local agencies can develop and enforce stricter regulatory levels for contaminated sites located within their region.
For the purpose of this document, contaminated sites have been divided into three categories (and defined below in this Section): (1) contaminated military sites (CMSs), (2) contaminated civil sites (CCSs), and (3) other contaminated government sites.
Contaminated Military Site
A contaminated military site (CMS) is a contaminated site (as defined above) that is owned or operated by the United States Department of Defence (DOD) or was formerly owned or operated by the DOD. The DOD components includes the Army, Navy, Air Force, Defence Logistics Agency (DLA), and Formerly Used Defence Sites (FUDSs). Examples of types of CMSs include the following DOD-owned or operated facilities/installations: research and development facilities; production sites for military goods (weapons, chemicals, etc.); test areas; disposal sites; training areas; barracks or other housing areas; storage areas; airfields; hangars; and other DOD-owned or operated facilities or areas.
These CMSs can be located within the US or can be located overseas. One military installation or base may have a number of CMSs within its boundaries; therefore, the number of CMSs reported throughout this report does not reflect the number of military bases that are contaminated.
CMSs do not include privately or commercially owned facilities which may support DOD in such operations as production of military goods, waste disposal, and other non-military operated or owned operations. Although not considered a CMS, DOD can share the financial responsibilities associated with the investigation and remediation of CCSss if DOD is identified as a partially or potentially responsible party. These sites are typically commercially operated waste disposal facilities at which waste generated by DOD was disposed. DOD can also share financial responsibility with private parties on DOD-owned property where DOD contractors are responsible for the contamination; these sites are referenced as CMSs because the property is owned by DOD.
CMS Categories
The DOD has established nine different categories of CMSs which are further divided into forty-four site types. The number of site types was expanded from 25 to 44 in fiscal year 1994 in order to better characterize and account for the types of sites and progress at these sites with regards to investigation and clean-up. The CMS categories and site types are identified in Appendix 20-2 and further described in Section 20.-5.0.

20.-3.0 Legislative Framework, Administrative System, Responsi-bility


Legislative Framework/Administrative System
* Historical DOD Legislation/DERP
Federal agencies such as DOD, Department of Energy (DOE), Department of Interior (DOI) and others must comply with the fundamental requirements established by EPA, state and local regulatory agencies. Each of the Federal agencies have developed their own protocols for the purpose of achieving and maintaining compliance with applicable regulations. Additionally, DOD components (e.g., Army, Navy, etc.) have developed parallel and similar environmental programmes for establishing and maintaining compliance. DOD established the Installation Restoration Programme (IRP) in 1975 to study and remediate contaminated DOD sites. In 1984, this programme was made a part of the Defence Environmental Restoration Programme (DERP) (see Sections 20.-6.0 and 20.-7.0).
* Public (Civil) Legislation
CERCLA and the Resource Conservation and Recovery Act (RCRA) are the primary Federal laws established by EPA that govern the investigations and clean-up activities of contaminated sites. A DOD installation typically consists of multiple contaminated sites regulated by either CERCLA or RCRA or by both. State and local environmental laws and regulations can also apply to investigations and remedial activities performed at DOD installations. In many instances, both Federal (EPA) and state regulations apply to the same site and application of these regulations are in conflict. Simultaneous negotiations with multiple agencies is then necessary to develop a mutually acceptable plan of action.
CERCLA/SARA. The Comprehensive Environmental Response, Compensation and Liability Act (CERCLA or Superfund) provides EPA with the authority to respond to releases of hazardous wastes (as defined by the Clean Water Act, Clean Air Act, Toxic Substances Control Act, Solid Waste Disposal Act, and the EPA Administrator) from "inactive" hazardous waste sites which endanger public health and the environment. It also establishes a Federal "Superfund" to finance response actions, establishes regulations controlling inactive hazardous waste sites, and establishes liability to recover clean-up costs. These funds, however, are not available for federally owned or operated sites. Federal agencies including DOD are responsible for funding the investigation and remedial actions at DOD active and inactive sites. Superfund Amendments and Reauthorization Act (SARA) (1986) revises and extends CERCLA to continue Superfund activities. Title III of SARA, Emergency Planning and Community Right-to-Know Act (EPCRA) of 1986, provides for "emergency planning and preparedness, community right-to-know reporting and toxic chemical release reporting." Under this law, facility owners and operators are required to provide certain information relating to regulated substances within their facilities to the appropriate state and local authorities so that they may be better prepared for environmental emergencies. This law also establishes a comprehensive framework of procedures to be followed by facility owners or operators to identify, investigate, and clean-up releases of hazardous substances to the environment. Through Executive Order 12580 (January 1987), the President of the United States directs the Secretary of Defence to implement investigation and clean-up measures in consultation with EPA for hazardous substances releases from DOD installations. EPA's response policy and key response steps for implementing CERCLA are established by the National Oil and Hazardous Substances Pollution Contingency Plan (NCP).
EPA, in pursuant to CERCLA Section 105, compiled a list of uncontrolled hazardous substance releases in the US that are identified as priorities for long term remedial evaluation and response. This list is referred to as the National Priorities List (NPL). The mechanism for identifying NPL sites is further described in Section 20.-7.0 and 20.-7.1.
RCRA. The Resource Conservation and Recovery Act (RCRA) of 1976 addresses solid waste issues, and provides EPA with the authority to regulate the disposal of hazardous waste. RCRA also encourages the development of solid waste management plans and nonhazardous waste regulatory programmes by the states; prohibits open dumping of waste; regulates underground storage tanks (USTs); and provides for a national research, development, and demonstration programme for improved solid waste management and resource conservation techniques. RCRA provides EPA with "cradle-to-grave" control, from generation, transportation, treatment, storage, and disposal, of hazardous waste. RCRA also provides a framework for dealing with non-hazardous wastes.
RCRA was amended in 1984 to include the Hazardous and Solid Waste Amendments (HSWA). HSWA required the phase-out of land disposal of hazardous waste; increased enforcement authority for EPA; developed more stringent hazardous waste management standards; and provided provisions to deal with USTs. HSWA provides authority for the investigation and clean-up of past waste sites, which create a corrective action programme substantially equivalent to programmes under CERCLA. For those DOD installations that require a RCRA permit to manage hazardous wastes, EPA or authorized states may impose corrective action requirements for any known or suspected releases of hazardous wastes or hazardous substances from Solid Waste Management Units (SWMUs) or other identified SCSs at the DOD installation.
The UST programme was created by HSWA in 1986 to regulate both petroleum products and hazardous substances. RCRA Subtitle I establishes requirements concerning the management of USTs that contain petroleum products and any substance defined as hazardous under CERCLA; however, USTs containing RCRA hazardous waste are not regulated by Subtitle I. Responses to petroleum product releases at CMSs and CCSs are conducted in accordance with UST regulations under RCRA Subtitle I or state laws, if existing. States, counties or other local agencies can develop their own UST regulations with requirements that are equivalent to or stricter than EPA's UST regulations.
Clean-up of CMSs may be governed by both CERCLA and RCRA statutory and regulatory authorities. Circumstances are dependent on many factors such as the source and cause of the contamination, status of the installation as either an NPL or non-NPL site, and whether the installation is seeking a RCRA permit to manage hazardous waste.
Conflicts between RCRA and CERCLA are not uncommon as the different regulatory agencies exercise their respective authorities. Partnering efforts are assisting DOD, EPA and the states with cooperating through regulatory overlaps and inconsistencies to allow for the most effective and timely clean-up of CMSs.
* Federal Compliance Requirements
In most instances, Federal facilities are required to comply with environmental statutes such as RCRA and CERCLA to the same extent as non-Federal (or civil) facilities. Methods of enforcing compliance at Federal facilities, funding the investigations and remedial activities, and public involvement in clean-up activities at Federal installations are the major differences. For both CMSs and CCSs, if a site is determined to pose an immediate risk to human health, interim measures are to be taken to eliminate or reduce the human health risk as soon as possible.
* Overseas Requirements
The policies of the US DOD that apply to remediation of environmental contamination on DOD installations or facilities located overseas or caused by DOD operations that occur within the territory of a nation other than the US are discussed in the following documents:
· Country-Specific Final Governing Standards
· Overseas Environmental Baseline Guidance Document, Department of Defence, October 1992.
· Memorandum for Secretaries of the Military Departments Under Secretary of Defence: Environmental Remediation Policy for DOD Activities Overseas (October 1995).
The overseas Commanders have the responsibility to provide implementing directives, although this has not yet occurred at all overseas bases. The Status of Forces Agreements (SOFA) for troops stationed in foreign NATO countries does also cover liabilities associated with the use of land.
In general, it is the policy of the US to take prompt action to remediate known imminent and substantial endangerments to human health that are caused by environmental contamination caused by DOD operations on overseas active DOD installations and on overseas DOD installations that have been designated for return to the host nation. The 1995 Memorandum allows commanders to remediate beyond requirements in case of imminent and substantial endangerments to health and safety, which otherwise would result in shutting down operations. Other additional remediation must be approved by appropriate parties.
International agreements may require US to fund environmental remediation; such required measures may be more extensive than that necessary to remediate known imminent and substantial endangerments to human health and safety. Remediation may be completed after return of the property as long as only environmental contamination caused by DOD operations are addressed and remediation activities do not exceed those approved prior to the return of the property.
Prior to the return of DOD installations to the host nation, DOD and the host nation must agree on sites to be remediated and acceptable contaminant levels and/or measures to be implemented. After return of an installation, DOD will not fund any environmental remediation beyond that required by binding international agreement or previously approved remediation measures. Host nations using their funds may remediate installations to a greater extent during the US occupancy of the installation with the cooperation of the US.
The decision of whether or not a CMS poses a known imminent and substantial endangerment shall be made by the appropriate DOD personnel. Remediation may range from institutional responses, such as restricting access, to permanent remedies.
Responsibilities
CERCLA, RCRA, UST and other regulations have reporting requirements when a spill, leak or other contamination to a site has occurred. Threshold levels for various contaminants are identified by different regulations. When a threshold level for a contaminant is exceeded, a facility is required to report the contamination to the appropriate Federal, state or local regulatory agency. EPA uses the Hazard Ranking System (HRS) to determine if a site is to be listed on the NPL, a list of the nation's worst sites. The HRS is further described in Section 20.-7.1. Various databases are maintained that consist of a compilation of reported environmental incidents. Examples of existing Federal or state databases include state leaking UST databases, NPL list, State NPL list (depending on the state), RCRA violators, CERCLIS database and others. Federal facilities are required to report to the applicable Federal, state and/or local regulatory agencies and the reported CMSs are included in the Federal, state and local database.
It is the responsibility of the owner or operator of a facility to register, assess and remediate a contaminated site. This applies to civil, military and other government sites. The Commander or head of the military base or installation is typically considered the "owner" or "operator" and is, therefore, responsible for registering, assessing and remediating their base or installation. Typically, an environmental officer or coordinator at the military installation or facility is delegated these responsibilities.
DOD prioritizes the different military sites in order to distribute funding for investigation and remediation activities. Contaminated sites are initially prioritized using limited data that may be available. Once further investigation is completed that better defines the extent of contamination, the priority of the site is reevaluated in order to identify high priority sites for clean-up. The methods for prioritizing the different military sites are further discussed in Sections 20.-5.0 and 20.-10.0. Sites may be prioritized both by EPA and by DOD.
Public Involvement
SARA requires DOD to establish technical review committees (TRC) at installations with environmental restoration programmes. TRCs review technical documents and discuss progress in implementing and completing environmental restoration activities. By the end of FY 1994, TRCs had been formed at most installations with environmental restoration programmes, and at nearly all installations listed on EPA´s NPL.
DOD policy also requires that community involvement is further strengthened by the establishment of Restoration Advisory Boards (RABs) installations where there is sufficient, sustained community interest in the environmental restoration programme. One of the following criteria must be met to determine that community interest is sufficient and sustained:
· Closure of the installation involves transfer of property to the community;
· at least 50 citizens petition for an advisory board;
· the Federal, state, or local government requests formation of an advisory board;
· the installation determines the need for an advisory board.
RABs were first established in September 1993. Consequently, at many installations TRCs are being converted to RABs to include more local citizens. At the end of FY 1995, RABs had been formed at more than 250 operational and closing installations.
DOD perceives that RABs have become a significant forum through which members of affected communities can provide input to an installation´s ongoing environmental restoration programme. Addressing community concerns early in the clean-up process enhances efforts under, and increases the credibility of, the environmental restoration programme.

20.-4.0 Financing


Sources of Funds for Investigation and Remediation/Clean-Up
DOD has organized the environmental restoration programme into five elements:
· clean-up,
· compliance,
· conservation,
· pollution prevention, and
· technology.
The Secretary of Defence has delegated clean-up responsibility to the Air Force, Army, Navy and DLA and private firms, which are monitored by the services.
Funding for the DOD's five environmental programme elements is divided into three broad categories consisting of
(1) environmental compliance,
(2) environmental restoration, and
(3) BRAC clean-up costs.
Congress provides clean-up funds for work at active DOD facilities and formerly used defence sites in the Defence Environmental Restoration Account (DERA), which is considered DOD's equivalent of Superfund. DERA is centrally managed. The majority of the DERA funds are allocated to DOD NPL sites. Congress provides funds through the Base Realignment and Closure (BRAC) account for investigation and clean-up of closing installations. BRAC environmental funding also includes closure related environmental compliance and environmental planning. Compliance efforts may include, but are not necessarily limited to, such actions as
· UST removals;
· closure of hazardous waste treatment, storage, and disposal facilities;
· radon surveys; and
· asbestos abatement.
Environmental planning involves environmental analyses required under the National Environmental Policy Act (NEPA) to assist decisions related to property reuse and redevelopment. Actions to achieve or maintain compliance at DOD installations are funded through accounts set up within each DOD component, such as the Navy Environmental Compliance Act (NECA).
States and US territories can be reimbursed for technical services in support of investigation and clean-up efforts at DOD installations within their boundaries under the Defence and State Memorandum of Agreement (DSMOA).
Responsible Party Identification
One of EPA's responsibilities with NPL sites is to attempt to identify responsible parties that potentially contributed to the contamination. Responsible parties that are identified must share the financial responsibilities associated with the investigation and remediation of that contaminated site. However, in cases, the responsible party identified may no longer exist or may not be capable of financially contributing to the remediation of the site.
There may be responsible parties for some CMSs other than DOD. Examples of such CMSs are sites that are owned by DOD but were operated by contractors who were responsible for contaminating the site. If the contractor still exists and is financially capable of contributing to the investigation and remediation of the CMS, then they are held responsible for sharing the burden with DOD. DOD has also been identified as a potentially responsible party at CCSs. These sites are typically commercially operated waste disposal facilities at which DOD generated waste was disposed.
DOD Environmental Restoration Streamlining
The overall downward pressure on the defence budget has affected DOD's environmental programmes. DOD is being forced to do more with lower budgets. The decreased budgets and increased public pressure to remediate CMSs have caused DOD to work closely with regulatory agencies and stakeholders to streamline and increase efficiencies in the restoration process. Because of legal mandates, the majority of DOD's past efforts in environmental restoration were devoted to investigating the environmental impacts. The shift to focusing on actual clean-up and reducing real environmental risks did not truly begin until fiscal year 1993. This shift includes
· using more interim actions to remove sources of contamination and to reduce immediate threats;
· more appropriately prioritizing site clean-up efforts;
· balancing clean-up levels against expected future land use and life cycle costs;
· promoting technologies to target the most immediate needs;
· identifying better management and contracting approaches; and
· overcoming regulatory or statutory impediments to successful execution of the restoration programme.
The DOD has developed the "Fast-Track Clean-up Programme" which represents a new approach to environmental restoration. This programme acknowledges that environmental policies must consider economic realities and real-world risk, rather than solely regulations. DOD is fundamentally shifting environmental policy by encouraging more flexibility in the regulatory process and focusing on achieving measurable and practical performance-based goals. The new approach incorporates risk-based assessment when prioritizing sites as well as allows for evaluation of different sites on an installation separately so not to require spending of environmental restoration funds on the clean-up of low priority sites at an installation that has an overall classification as a high priority installation.
Contracting
Changes to DOD contracting mechanisms have assisted in the improved efficiency of completing investigations and clean-up activities at CMSs. Under prior contracting methods, it was more difficult for DOD to retain the same contractor to complete the different stages of investigation or remediation at the same site; this caused a loss in experience and familiarity with a site when a new contractor was selected to complete work that was initiated by a different contractor. More recently, procurements have been for multiple years and increased dollars that allow increased continuity. Another improvement in the contracting strategies is that larger open-end contracts are being awarded where individual tasks are negotiated; this prevents the need to undergo the lengthy contracting procedures for every task to be completed.
DOD contracting strategies differ depending on the issues, agency, and programme needs. The Navy, Army and Air Force have differences in contracting strategies. In general, the Navy primarily uses a combination of two major remediation contracts:
· the Comprehensive Long-Term Environmental Action Navy (CLEAN) contract during the investigation and design phase and
· the Remedial Action Contract (RAC) during the remedial action phase.
The Air Force advocates a "one base-one contractor" approach to manage their remediation. The Army's approach incorporates central programme management by the Army Environmental Centre (AEC) for investigation studies, with design and remediation handled by the Corps of Engineers.
Potential Cost Savings from Research & Development (R&D)
Many research projects now in the laboratories or being tested in the field are providing results that foreshadow lower costs (see also Sections 20.-12.0 and 20.-13.0). According to DOD´s estimates in 1994, for example, new technologies for cleaning-up metals in contaminated groundwater could reduce costs from as high as $40 to as low as 10 cents per thousand gallons; and for metals in contaminated soils, from as high as $250 to as low as $20 per ton. DOD estimated in January 1995 that it might be able to cut cost of remediating buried ordnance by 33 percent using technology that is being developed.
New technologies for studying contaminated sites could also achieve significant savings. For example, new penetrometer technologies could reduce the cost of surveying property containing buried ordnance from $5,000 to as low as $600 per acre (1 acre = 4046.8 m²). New well-drilling techniques could reduce sampling costs from $280 to as low as $10 per well-foot (1 foot = 30.48 cm).
Of course, those estimates are preliminary and require additional testing and application to confirm their validity.
Overseas Bases
Funding for remediation projects comes from commander's operations and maintenance (O&M) budget. There are no specific or "fenced" funds for overseas remediation requirements.

20.-5.0 Profile of Contamination


Contamination at Different Site Types
In order to better characterize and account for the types of sites and progress of the investigations and remedial activities at the various DOD site types, the DOD developed site categories and site types for CMSs. Descriptions of the different site types of CMSs are provided in Appendix 20-3. The primary contaminants typically found at each type of CMS are also summarized in Appendix 20-3.
The number of CMSs for each site category in fiscal year (FY) 1994 is provided in Appendix 20-4. The number of sites presented in Appendix 20-4 includes sites where investigations and/or remedial activities are in progress as well as sites where investigations and/or remedial activities have been completed.
The majority of these sites are associated with past practices involving the use of petroleum, oil and lubricants for operations and maintenance (O&M) activities at military installations. In addition, other common contamination refers to solvents, heavy metals, paints, and other hazardous materials including acids, asbestos, and pesticides. The 10 most common types of contaminants found at DOD sites are listed in Table 20-1.


Table 20-1:
Most Common Types of Contaminants on Defence Facilities (End Fiscal Year 1993)



Type of Contaminant


Number of Contaminated Areas


Petroleum, Oil, Lubricants


5,324


Solvents


1,857


Heavy Metals


1,344


Paint


1,017


Ordnance Components


620


PCB


606


Acid


555


Refuse (without hazardous waste)


429


Explosive Chemicals


405


Pesticides


402


Source: Congressional Budget Office: Cleaning up Defense Installations: Issues and Options, January 1995
Leaks or spills occurring as a result of O&M activities may have potentially affected the immediate surface or subsurface areas surrounding the source or site. At some CMSs, contaminants may have been transported to other areas via surface or subsurface migration pathways such as groundwater movement or surface water runoff. Some site types are relatively unique to CMSs and not commonly found on CCSs. These site types include: ordnance disposal areas where munitions have been used; fire fighting training areas where fuels and other flammable substances have been burned; and low-level radioactive waste areas where slightly radioactive instruments (e.g., aircraft dials) have been disposed.
In general, the complexity of the contamination at CMSs is greater than that found at CCSs. This is primarily due to the large variety of historic and current operations at individual installations and the uniqueness of some contaminants such as explosives, radioactive waste, and other DOD specialty wastes.
Evaluation of Sizes of Contaminated Areas
There are limited data available indicating the size of the areas that have been found contaminated compared to the size of the sites that were investigated. This information could be determined for specific installations where investigations have been completed that define the extent of contamination, but a comprehensive comparison is not available.
In the DERP Annual Report to Congress for the fiscal year 1994, data were provided on the size of the installation versus the size of the environmentally suitable acreage for DOD installations on the list for Base Closure and Realignment. These data are provided in Table 20-2. Based on these data, approximately 57 percent of the total installation land area has been identified as contaminated and not suitable for other uses until remediated or otherwise proven to be environmentally suitable. However, the entire installation at each location has not necessarily been investigated but could have been considered "environmentally suitable" based on land use. Alternatively, land identified as "environmentally suitable" could have been investigated but analytical results may have proved certain areas to be classified as "environmentally suitable".


Table 20-2:
Installation and Environmentally Suitable Acreage Base Realignment and Closure






Facility


Installation Land Area
(hectares)



Environmental Suitable Land Area
(hectares)



Army


103,698


43,627


Navy


40,991


12,836


Air Force


37,432


22,658


DLA


101


42


TOTAL


182,492


79,163


Source: DERP FY 1994 Annual Report

20.-6.0 Registration of Suspected Contaminated Sites (SCS)


Reasons to Investigate CMSs
There are many different mechanisms which can initiate the investigation processes of suspected contaminated sites. A preliminary site assessment can be ordered by a regulatory agency with authority under RCRA, UST regulations (state or Federal), CERCLA, Clean Water Act, or other laws or regulations. A regulatory agency can order an investigation if there is any reason or cause to suspect contamination may have occurred to the site. Suspect contamination may be identified by community or individual complaints; contamination detected on property located down gradient of the site; SCSs identified during NPDES, RCRA, or other regulatory inspections; improper closure of hazardous waste areas; or other such sources.
An investigation may also be triggered if contamination from a known or an unknown source is detected during routine monitoring. Routine monitoring requirements include leak detection monitoring of USTs, landfill groundwater monitoring, groundwater monitoring required for facilities with large petroleum aboveground storage capacities, RCRA closure plan monitoring requirements and other regulatory O&M monitoring requirements. Initial investigations can be triggered if a spill or release of a hazardous substance occurs. UST regulations require tanks to be upgraded or replaced to include leak detection by 1998 and to be tightness tested until upgraded or replaced. These UST regulations have lead to the identification of numerous leaking UST sites requiring investigations; many of these USTs have been leaking for years and investigations have not been required until the UST regulations took effect.
A site assessment can also be initiated during property transactions or refinancing in order to evaluate potential liabilities associated with potential environmental impacts. Constructions activities, where soil staining, chemical odours, buried chemical or waste containers, sudden employee sicknesses or other hazards are identified, can trigger the need for environmental investigations. Preliminary assessments of DOD-owned parcels are required prior to the transfer of ownership.
DOD´s Environmental Clean-up Programme
DOD established the Installation Restoration Programme (IRP) in 1975 (See Section 20.-3.0) to study and remediate contaminated DOD sites. The IRP is DOD's programme to implement its remedial responsibilities under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) as amended by the Superfund Amendments and Reauthorisation Act of 1986 (SARA) and for cleaning up environmentally contaminated sites that are regulated under other statutes. The IRP is a four-phase programme (see Section 20.-7.0).
In 1984, this programme was made a part of the Defence Environmental Restoration Programme (DERP), and Congress provided funding through the Defence Environmental Restoration Account (DERA). In 1990, separate clean-up funding was provided by Congress for closing and realigning installations under the Base Realignment and Closure (BRAC) account. In May 1993, DOD created the Under Secretary of Defence (Environmental Security) position to oversee clean-up and other environmental efforts.
Progression of CMSs
DOD has devoted most of its efforts during the past two decades to locating and studying the characteristics of contaminated military sites. Having essentially completed the initial investigatory phase at most sites, it is now devoting most of its current efforts to characterizing contaminated sites and developing technical plans and schedules for cleaning them up. Although DOD has completed more then thousand interim clean-up measures (see Section 20.-9.0), it has completed relatively few permanent clean-up actions.
One measure of evaluating the progress of DOD's environmental restoration programme is to compare the number of sites in progress to previous fiscal years. However, when comparing the number of CMSs in progress at the end of fiscal year 1994 (11,785 sites) to fiscal years 1993 (10,439 sites) and 1992 (10,158 sites), the number of sites undergoing investigations and remedial activities at the end of each fiscal year appears to be increasing.
As identified in Appendix 20-5, the number of sites requiring investigations and/or remediation continues to fluctuate as existing sites are determined to require no further action and new sites are identified.
New sites are identified predominantly as a result of newly discovered historic contamination and not typically as a result of current deficiencies in environmental compliance. These new sites can be identified as a result of conducting RCRA Facility Assessments, Environmental Baseline Surveys required for BRAC installations and other newly discovered CERCLA and UST sites. For instance, many new contaminated sites have been discovered as a result of achieving compliance with UST regulations that require USTs to be upgraded or replaced by 1998.
The number of sites in progress also increases as a result of sites previously determined as no further action sites or closed sites are reopened when a regulatory agency does not agree with DOD's determination that clean-up is not required or is complete. Similar fluctuations occur with the number of FUDS sites in progress. The breakdown of the number of sites in the different stages of investigation and remediation is provided in Section 20.-7.0. According to the FY 1994 DERP Annual Report, a total of 21,425 CMSs on 1,764 military installations have been identified; remedial response has been completed at approximately 45 percent of these CMSs. The number of CMSs reported to be in progress in FY 1994 (11,785 CMSs) are located on 760 military installations.
Registration of Overseas Bases
In terms of registration for overseas bases there are no requirements to register CMS with DOD. Commands keep data bases to manage their contaminated sites and prioritize and develop projects, but no formal registration of overseas CMS is required.

20.-7.0 Methods of the Investigation for CMS


DOD´s Environmental Clean-up Programme
Implemented in 1975, the IRP was DOD's programme to implement its remedial responsibilities under the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) as amended by the Superfund Amendments and Reauthorisation Act of 1986 (SARA) and for cleaning up environmentally contaminated sites that are regulated under other statutes. The IRP is a four-phase programme consisting of:
· Phase I - record search to identify requirements for physical examination of sites. (Preliminary Assessment PA)
· Phase II - field study to confirm and qualify the presence or absence of a contamination problem requiring remedial action (Site Inspection SI)
· Phase III - technology development for CMSs. (Remedial Investigation/Feasibility Study)
· Phase IV - corrective action: physical clean-up activity (Remedial Design/Remedial Action)
Phase IV may require several years given the complexity of problems at some locations. Some actions may require indefinite operations of containment or purification systems; however, in these cases, Phase IV is considered complete when the construction activity is complete.
The breakdown of number of sites in the different stages of investigation and remediation is provided in Table 20-3.


Table 20-3:
Investigation/Remediation Phases of CMSs





Phase


Completed


Underway


Future


DOD Installation Sites:





Investigation


10,851


10,476


98


Interim Action


1,173


551


--


Design


716


485


6,067


Clean-up


810


462


6,950


FUDS:





Investigation


881


2,568


24


Interim Action


11


41


--


Design


433


251


765


Clean-up


265


266


2,381


Source: DERP Annual Report FY 1994

20.-7.1 Registration and Preliminary Assessment


Preliminary Assessment
The initial step in investigating a CERCLA site is to complete a preliminary assessment (PA) which is designed to distinguish between sites that pose little or no threat to human health and the environment and those sites which require further investigation. The PA is based on site information obtained in installation records searches, visual site inspections, interviews of site personnel, deed records of ownership, maps, aerial photographs, and other applicable information sources. The PA is completed typically by a DOD contractor. Information to be documented as part of a PA includes general site description; previous ownership; historical usage of properties; hazardous chemicals and wastes stored, generated or disposed on the property; and results of visual inspection such as potential impacts to flora, fauna, food chain and other areas to the property being assessed and surrounding properties.
Pas have been completed at the majority of the CMSs identified to date. The Corrective Action investigation programme under RCRA consists of a RCRA Facility Assessment (RFA), a RCRA Facility Investigation (RFI) and a Corrective Measures Study (CMSt). A RFA, which is the initial step in the RCRA corrective action process, acts as a screen for first identifying and then eliminating Solid Waste Management Units (SWMUs), environmental media, or entire installations from further consideration for corrective action. RFAs are performed as part of the RCRA permitting process.
The corrective action investigation process for release of a substance not regulated as a RCRA hazardous waste from USTs vary from the RCRA Corrective Action Investigation process. The first step, the Initial Site Characterization, requires an installation to submit information regarding local communities, subsurface soil conditions, climate and land use to the appropriate state or Federal regulatory agency. Data may be compiled from readily available sources or generated by site investigations. Specific requirements commonly vary depending on the state in which the site is present, if the state is the appropriate regulatory agency.
Hazard Ranking System
The HRS was developed by the USEPA to evaluate the relative potential of uncontrolled hazardous substance facilities to cause health or safety problems or ecological or environmental damage. The HRS is the principal mechanism that the USEPA uses to determine if a site should be registered on the NPL. The HRS provides a measure of relative risks, not absolute risks. EPA also uses the HRS scores to identify military sites that are to be listed on the NPL. If a site is listed on the NPL, the DOD then gives that CMS a high priority for completing necessary investigations and remediation. For DOD, NPL status generally refers to the entire installation, not an individual site on the installation. A HRS is determined using data and information collected in PAs and site inspections (SIs) and can be reevaluated once additional data are collected. The details of the HRS are provided in Appendix A of the CERCLA Pollution Contingency Plan (40 CFR 300) and are summarized below.
The HRS site score is a result of the evaluation of four pathways:
(1) groundwater migration,
(2) surface water migration,
(3) soil exposure, and
(4) air migration.
An individual score for each pathway is first identified, then used to calculate the HRS site score. Evaluations common to each of the individual pathway scores include:
· Likelihood of release (observed release or potential for release).
· Characterization of contaminant sources (identify sources, hazardous substances associated with each source, and hazardous substances available to a pathway).
· Nature of materials that may be released (evaluation of contaminant characteristics such as toxicity, mobility, persistence, bioaccumulation potential, and quantities present or potentially present).
· Potential targets (such as humans through ingestion, inhalation, or other pathways; resources affected or potentially affected; and other targets dependent on the pathway.
The groundwater and air migration pathways use single threat evaluations, whereas surface water migration and soil exposure pathways are multiple threat evaluations. Three threats, drinking water, human food chain and environmental, are evaluated for surface water migration pathways and two threats, residential populations and nearby populations, are evaluated for soil exposure. The HRS does not address the feasibility, desirability, timing, or degree of clean-up required.

20.-7.2 First Investigation, Detailed Investigation, and Risk Assessment


RI/FS Process (CERCLA)
If the results of the PA indicate the need for further investigation, a Site Inspection (SI) is performed. SI investigations commonly include the collection of limited waste and environmental samples to confirm whether or not hazardous substances are present at a site. These data are used to perform the HRS Scoring. If determined to be necessary, additional samples can be collected to further refine or support the HRS. As mentioned earlier, the HRS is used to determine whether or not the site is considered to be an NPL site. Next, a Remedial Investigation (RI), which is more extensive than an SI, is performed in order to characterize the nature and extent of contamination at a site.
The risks posed by on-site contamination to human health and the environment are also evaluated as part of the RI. Data collected in the RI are used to develop options for final clean-up actions as part of the Feasibility Study (FS). A detailed analysis of feasible remedial alternatives includes cost-effectiveness, short and long-term effectiveness and overall human health and environmental protection. The FS can be conducted separately or, more commonly, immediately following the RI to provide one consolidated report. EPA has published a guidance document outlining requirements and recommendations for conducting RI/FS studies under CERCLA. The publication is titled: Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA (1988). An engineering evaluation/cost analysis (EE/CA) documents the selection of a remedial action where time is not critical (i.e., when there are no immediate risks to human health).
RFI/CMSt Process (RCRA)
The step following the RFI in the RCRA corrective action process is an RFI which characterizes the nature, extent and migration of releases of hazardous substances into the environment and the risk posed by the degree of contamination. The CMSt identifies and evaluates potential remedial measures for the releases identified and investigated in the RFI.
Leaking UST Investigations/CAP
If the Initial Site Characterization identifies evidence of a release, an Investigation for Soil and Groundwater Clean-up is conducted. This investigation is performed to determine the extent of soil and groundwater contamination at a UST site. If the soil and groundwater data prove necessary, a site-specific Corrective Action Plan (CAP) is conducted to address releases from UST(s). If the extent of contamination does not justify active remediation or removal activities or if it is determined to be technologically not feasible to actively remediate, the CAP may include requirements for long-term monitoring, continued control of the groundwater flow at the site, and placement of a notice of continuing hazard in the property deed. CAPs may involve more detailed studies that establish the design and implementation of a clean-up.
Defining Site-Specific Investigation Requirements
The method of sampling, number of samples to collect, analytes to test for, and degree of complexity of the investigations is highly dependent on the extent and type of contamination and the degree of uncertainty. If records, interviews or other documentation are available to identify the specific suspected contaminated sites, potential contaminants of concern, potential magnitude of contamination (e.g., known quantity of spills, known quantities used in area, etc.), site-specific geology and hydrogeology, and other pertinent information, then the investigation efforts necessary to define the contamination for remediation is greatly reduced. Because of the complexity of defining necessary procedures for investigations, DOD sites are largely dependent on contractors which specialize in the appropriate fields.
General guideline documents for assisting the development of the scope of different investigations are available; however, because investigations at different suspected contaminated sites (SCSs) within one installation are largely dependent on site-specific characteristics, the documents are very general and professional opinions are required in order to adequately identify investigation needs.

20.-7.3 Technical Instruments for Risk Assessment


Introduction
The USEPA and similar agencies at the state and local levels within the United States are embracing Risk Assessment as the cornerstone of the decision-making process concerning formulation of clean-up requirements for CCS/CMS. Such agencies, and the general public, are becoming aware of the staggering site clean-up costs faced by the nation if it is continued to rely on clean-up requirements such as "cleaning to background" or "removing all detectable contamination". If unnecessarily funds are overspent during management of CCS/CMS, the risks to public health can increase by pulling funding away from other programmes where greater risk reduction per dollar spent can be obtained.
A vast number of guidance documents has been issued on Risk Assessment and related issues, as is detailed further below in this report. As there is not one single approach to conducting risk assessments, in practice some heterogenicity exists concerning the evaluation of contaminated sites. Such heterogenicity may be observed between individual EPA documents and between individual EPA regions as well (Note: the US is divided into 10 EPA regions). The evaluation of former military installations and production sites also follows different procedures.
In the USA all important, decommissioned production sites for explosives dating back to World War II had been evaluated by a risk assessment performed by the Agency of Toxic Substances and Disease Registry (ATSDR). However, this type of risk assessment mainly represents a description of the site status. Opposed to that approach the evaluation performed for the Alabama Army Ammunition Plant (which was guided by the US Army) follows strongly the requests of the US EPA and the Superfund program, respectively. Based on use-specific scenarios exposure is estimated and finally, acceptable limits for soil contamination are established.
The idea of quantitative risk assessment has also been applied to other studies, for instance, by Tom McKone from the Lawrence Livermore Institute. In particular it may be referred to his modeling work on the environmental risk assessment for demilitarization of conventional weapons (see References).
What follows is a brief overview of the expansion of the role of risk assessment within the United States, followed by a summary of some of the details concerning application of risk assessment to CCS/CMS, including references to computer programmes, lists, index values, etc.
The basis for estimating safe levels of exposure form experimental studies with animals that result in the development of "dose-response" curves (the animals were dosed with chemicals and then monitored to see the response of the animals to the chemical). Such experimentation resulted in determination of "acceptable daily intakes" (ADI), the intake level below which no adverse health effects would result. USEPA has introduced the term "reference dose (RfD) " in lieu of ADI. For chemicals that exhibit carcinogenic potential, similarities were drawn to radiation exposure, and it was argued by some that any exposure, regardless of dose, was interpreted by some as having the potential to initiate cancer.
The USEPA's application of risk assessment to hazardous waste sites utilizes the interpretation of what is considered negligible risk to the effect: "site risks should not exceed the acceptable risk range of one chance in a million to one chance in ten thousand (1 x 10-6 to 1 x 10-4)". This muddies the situation by encouraging inconsistency across the US concerning what risk level activates remedial requirements or, alternatively, to what risk level site risks must be reduced during remediation. Generally, however, in the context of hazardous waste site investigations, a criteria risk level of 1 x 10-4 is more frequently being embraced by the USEPA and the States. To date, however, most Records of Decisions (RODs) that document site decisions cite the more conservative end of the risk range (1 x 10-6).
The USEPA has also expanded the risk assessment process to address environmental (ecological) risks posed by CCS/CMS, in addition to human health risks. This was motivated by the National Contingency Plan (NCP) which requires management procedures to protect human health and the environment. Below in this Section the human health risk assessment process, and the environmental risk assessment process are addressed.
Human Health Risk Assessment Technical Instruments/Process
The USEPA has developed human health baseline risk assessment (HHBRA) guidance that is in accordance with the NCP. The USEPA's methodology is for the most part presented in the following EPA guidance documents:
· Risk Assessment Guidance for Superfund, Volume I, Human Health Evaluation Manual (Part A) (referred to herein as RAGS; USEPA, 1989);
· Risk Assessment Guidance for Superfund, Volume I, Human Health Evaluation Manual (Part B, Development of Risk-based Preliminary Goals) (USEPA, 1991);
· Risk Assessment Guidance for Superfund, Supplemental Guidance, Standard Exposure Factors (USEPA, 1991);
· Exposure Factors Handbook (USEPA, 1990);
· Dermal Exposure Assessment: Principles and Applications (USEPA, 1992);
· Human Health Evaluation Manual, Supplemental Guidance: Interim Dermal Risk Assessment Guidance (Draft) (USEPA, 1992);
· Selecting Exposure Routes and Contaminants of Concern by Risk-Based Screening (USEPA, 1993);
· Risk-Based Concentration Table, January-June 1995 (USEPA, 1995);
· Guidance for Data Useability in Risk Assessment (USEPA, 1992);
· Chemical Concentration Data Near the Detection Limit (USEPA, 1991);
· Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA (USEPA, 1988);
· Supplemental Guidance to RAGS: Calculating the Concentration Term (USEPA, 1992);
· Soil Screening Guidance (USEPA, 1994);
According to RAGS, the key guidance document for Superfund-type HHBRAs, a HHBRA should include:
· Data evaluation and identification of contaminants of potential concern (COPCs);
· Exposure assessment;
· Toxicity assessment; and
· Risk characterization and evaluation of uncertainties.
The following is to expnad on these issues:
* Data Evaluation and Identification of COPCs
RAGS specifies four steps for identifying COPCs:
(1) Assess the validity of data.
(2) Identify site-related contaminants by comparison with background levels.
(3) Eliminate, as possible, site-related contaminants unlikely to pose a human health risk (i.e., analytes that are human dietary nutrients present in safe concentrations).
(4) Retain the remaining site-related contaminants as HHBRA COPCs and quantify their associated risks.
In 1993, EPA Region III issued guidance intended to streamline steps two and three above. The guidance recommends selecting COPCs primarily by screening against risk-based concentrations (RBCs). This eliminates the need to carry large numbers of site-related contaminants through the analysis that do not pose significant health risks. This often results when COPCs are selected primarily by screening against background, which identifies site-related contaminants but does not consider whether they are in concentrations of concern as regards human health. The EPA Region III guidance recommends computing HHBRA screening RBCs by assuming exposure levels appropriate to the site, a target carcinogenic risk of 1E-06 (1 x 10-6), and a target noncarcinogenic hazard of 0.1. The 1993 guidance document includes a list of nearly 600 such HHBRA screening RBCs. It was computed using October 1992 toxicity criteria, now out of date.
Several times a year EPA Region III publishes an "RBC Table" of more generic RBCs for several hundred chemicals (USEPA, 1995). These RBCs are not specifically intended for selecting HHBRA COPCs, but are for general-purpose rapid assessment of contamination levels.
The RBC Table presents RBCs for tap water (i.e., drinking water), ambient air, fish, soil assuming commercial/industrial worker exposure, and soil assuming residential exposure. They are computed using current toxicity criteria, a target carcinogenic risk of 1E-06 and a target noncarcinogenic hazard of 1.0. As a practical matter, the RBCs appearing in EPA Region III's RBC Table differ only from the risk assessment COPC-selection "screening RBCs" by the assumed target noncarcinogenic hazard and the RBC Table's use of more current toxicity criteria. By adjusting the target noncarcinogenic hazard from 1.0 to 0.1, the RBC Table RBCs become COPC-selection RBCs. When an RBC is not available or is actually less than background, the original RAGS methodology is followed which is to select COPCs by comparison with background.
* Exposure Assessment
Exposure assessment consists of identifying populations that may be exposed to site-related contamination, determining how exposure may occur, and quantifying intake for realistic exposures. Potentially exposed populations are identified by developing a conceptual site model that represents the release and transport of contaminants, and by examining current and probable future land uses. These land uses are represented by broad land use scenarios. Potentially exposed current and future populations, and the pathways by which they are exposed are then identified.
Of the identified populations, those retained for exposure quantification must satisfy two criteria: (1) there exists at least one complete exposure pathway from contaminated media to that population, and (2) meaningful exposure is likely. Exposure frequency and duration are the main criteria for deciding whether an exposure is "meaningful" and the pathway merits quantification. A complete exposure pathway typically has four elements:
· a source and mechanism of chemical release
· a retention or transport medium (or media)
· a point of human contact (an "exposure point")
· an exposure route (primarily ingestion, inhalation, or dermal absorption).
Once potentially exposed populations and exposure routes have been identified, exposure is quantified by calculating the intake of each COPC. Intake equations are used to estimate the amount of chemical crossing an individual's "exchange boundary." They take as their independent variable a COPC's exposure point concentration (EPC). Aside from the dermal pathway, intake equates in toxicological terms to the "administered" dose, rather than the dose actually absorbed into the bloodstream. For the dermal pathway, it is the absorbed amount. Intake equations are pathway specific, and include both site-specific and EPA-standardized parameters. The EPC is calculated using site monitoring data.
For many, if not most, Superfund-type HHBRAs, current risks are much lower than those calculated for the future, because future exposure assumptions are generally very conservative. Two key future scenario issues are selecting the most probable future land use (residential is the most conservative choice), and whether exposure to groundwater may occur. Shallow groundwater typically has the highest levels of chemical contamination, but shallow groundwater is often not potable due to other factors such as bacterial contamination, high mineral levels or salt water intrusion. Drinking water wells are typically installed in deeper strata.
The most important component of an HHBRA is the somewhat subjective process of estimating future land uses and the associated exposure assumptions that go along with that land use. Adherence to standard default USEPA exposure assumptions undermines the site-specific aspect of a risk assessment and frequently results in risk estimates that do not reflect reality. The best course of action during this stage of the risk assessment is to engage the regulatory agencies and interested members of the public in dialogue so that they may be part of this subjective decision-making process and also be made to understand that site-specific future exposure assumptions are the objective, rather than arbitrary default assumptions.
After potential land use(s) has been identified, and before chemical exposure (dose) is estimated, the concentration of the chemicals to which exposure will occur must be estimated. A COPC's exposure point concentration is the concentration with which receptors are assumed to make contact. (For details on how to estimate contaminant intake see Appendix 20-1.)
* Toxicity Assessment
Toxicity data for chemicals detected at CCS/CMS are primarily available from EPA's two principle repositories of current toxicity information on chemicals of human health concern:
· the Integrated Risk Information System (IRIS; and
· the Health Effects Assessment Summary Tables (HEAST).
IRIS is EPA's official repository of consensus, or "work group verified," human health risk information; HEAST contains provisional toxicity values. The RfD is used to quantify a chemical's noncarcinogenic effects. It represents the maximum acceptable human uptake of a chemical with noncarcinogenic toxicity, expressed as a dose - usually administered, rather than absorbed - in milligrams per kilogram per day (mg/kg-day) (see also Appendix 20-1).
For carcinogens, the slope factor (SF) is used to assess a chemical's potential human carcinogenic effects. It is an estimate of the increased probability of an exposed individual developing cancer in his or her lifetime. The SF is expressed as lifetime cancer risk per (mg/kg-day)-1. The RfD/SF concept initially was developed for longer term, or "chronic," exposure. Chronic exposure is considered lifetime or near-lifetime in duration.
The RfD/SF methodology was developed in the 1980s. In 1991, EPA changed the method from a dose basis (i.e., RfDi and SFi) to an air concentration basis. For noncarcinogenic effects, the new parameter is the reference concentration (RfC), which represents the maximum acceptable air concentration of the chemical (expressed in milligrams per cubic metre (mg/m3)). The corresponding parameter for carcinogenic effects is the unit risk (UR), expressed as risk per microgram per cubic metre (mg/m3)-1 of chemical in the air. Because the RAGS methodology for quantifying carcinogenic risk and noncarcinogenic hazard was drafted before 1990, it works best with toxicity values expressed in dose (USEPA, 1989b). Therefore, HHBRA's typically convert the currently available RfCs and URs to RfDis and SFis using an assumed human inhalation rate of 20 cubic metres per day (m3/day) and a body weight of 70 kg.
* Risk and Hazard Characterization and Evaluation of Uncertainties
In Superfund-type HHBRAs, hazard and risk are quantified through the use of RfDs and SFs. The excess carcinogenic risk associated with a carcinogen represents cumulative lifetime effects for a large population of receptors. In accordance with the NCP, EPA uses 10-4 to 10-6 summed total risk as a "target risk range" in managing Superfund sites (40 CFR, Part 300.430). For noncarcinogenic effects, the human health toxicity hazard from exposure to a single chemical is calculated according to Appendix 20-1. As with carcinogenic risk, individual contaminant HQs are summed by and across pathways for exposed populations at the given exposure points. The resulting overall sum is called the hazard index (HI).
Uncertainties associated with the following issues typically are addressed by HHBRA's:
· sampling and chemical analysis;
· land use;
· pathways selection;
· exposure parameter values for intake calculation;
· toxicity criteria.
A discussion of methods for calculating uncertainties from the above would be beyond the scope of this study.
Environmental Risk Assessment Process
Environmental Risk Assessments are also referred to as Ecologic Risk Assessments (ERAs) or Ecotoxicological Risk Assessments. In the year 1994 the EPA stated that ecotoxicological risk assessments have to form a key part of every assessment of a Superfund-site (OSWER Directive No. 9285.7-17). The concepts of ecological or ecotoxicological risk assessment are applicable to former military installations and production sites. Until present, usually on overseas bases no risk assessment approach has been used to provide a common sense approach to remediation goals. This is mainly due to the lack of acceptance of the models by host nation authorities.
The procedures for conducting ERAs are not as well established as compared to HHBRAs. This is due to e.g. the requirement to conduct ERAs is relatively new, toxicity data describing the effects of particular chemicals on specific biologic receptors are very scarce. Also, the uncertainties are much larger with ERAs than with HHBRAs.
In spite of the fact that guidance on this topic by the US EPA was available since the end of the eighties, in December 1993 it was the first time that an approach was introduced that is similar to the human toxicological risk assessment procedure. The Wildlife Exposure Factors Handbook provides corresponding exposure algorithms and parameters for a limited number of species which allow a quantitative exposure estimation.
Also, computer programmes have become more available to assist practitioners in the assessment of site risks, e.g. the State of Virginia's "Risk Exposure and Analysis Modelling System (REAMS) or programmes such as Crystal Ball and At Risk. Lists are available in the form of: (1) toxicity data for chemicals, and (2) risk based action levels for chemicals. In this context, data bases such as IRIS and HEAST (described in the above text) should be mentioned.

20.-8.0 Clean-Up Attainment Goals


EPA and State Clean-Up Attainment Goals
* Maximum Contaminant Level
EPA established Maximum Contaminant Levels (MCLs) for inorganic and organic chemicals, turbidity, coliform bacteria, and radiological constituents that pose a human health risk if consumed in drinking water. MCLS are used as guidelines for assessing the suitability of a surface water or groundwater for use as a public water supply. MCLs are updated as identified to be necessary and delineated in Title 40, Parts 141 and 143 of the Safe Drinking Water Act (SDWA).
States can adopt EPA's MCLs or they can develop more stringent requirements. Contaminants in groundwater and surface water are compared to MCLs in order to determine if the media is considered contaminated.
* Water Quality Standards/Groundwater Standards
EPA and state agencies have established and adopted water quality standards for the purpose of meeting and maintaining reasonable and beneficial uses of water sources and propagation and growth of aquatic life. Water quality standards for protecting human health have also been established for water sources used as public water supplies as well as for other surface waters.
Similarly, various states have established groundwater standards which often are dependent on the local groundwater situation and may therefore vary considerably between states. Surface water or groundwater quality standards may reference MCLs.
* Risk-Based Concentrations (RBCs)
Generally, human health risk assessment involves effort-intensive steps. Therefore, in order to maximize effciency of risk asessments, RBCs are used (See also detailed description of the term RBC in Section 20-7.3). RBCs for soil are commonly used during preliminary evaluation of a suspected contaminated site because, in most cases, Federal or state standards for soil and sediment have not been established.
ARARs
At sites which are required to comply with CERCLA, remedial actions must comply with applicable or relevant and appropriate requirements (ARARs) for the site conditions. ARARs are requirements, criteria, limitations, or guidelines developed by Federal, state, or local agencies. ARARs include, but are not limited to, historical and cultural land use; effects on endangered species; presence of wetlands; availability of treatment technologies; and cost of treatment.
A requirement may be either "applicable" or "relevant and appropriate" to a remedial action. The following example is provided in order to differentiate between "applicable" and "relevant and appropriate" requirements. EPA established MCLs (discussed above in this Section) as standards that are applicable to certain public water systems. When establishing site-specific ARARs for a military base, MCLs are not legally applicable to clean-up of groundwater or surface water; however, MCLs may be considered relevant and appropriate in situations where people use private drinking water wells in the area.
ARARs can have two detrimental effects on remedial activities: (1) they can increase the cost of a remediation and (2) they can delay the schedule of remediation. These effects can be caused by expanded activities onsite to meet the regulatory requirements, and additional regulatory parties brought in to review and approve matters within their areas of regulatory expertise. For example, if the contaminated site is located in a designated historic zone or below a historic building, the National Historical Association or other appropriate agency will become involved in determining the method of remediation.

20.-9.0 Clean-up Technologies


Interim Remedial Action
One of DOD's priorities for accelerating clean-up and reducing or eliminating risk to human health and the environment is to focus more effort on interim measures:
· removal actions (source/waste removal, e.g., contaminated soil excavation, drum or container removal, etc.);
· interim remedial actions (capping, installing drainage controls, soil vapour treatment and pumping-and-treating groundwater serve to stabilize sites by controlling or eliminating migration of contaminants);
· installing fences or other site access control measures;
· providing alternate drinking water supplies to reduce risks by eliminating exposure to contaminants.
Many actions such as waste removal and treatment that are initiated as interim measures, are proving to fulfill final clean-up requirements. Interim actions are typically initiated during the investigation stage at a contaminated site and are constantly evaluated during the investigation phase. The number of interim actions completed and the number of interim actions underway have increased over the past several years and are considered key measures of clean-up progress. DOD had completed 681 interim actions at 568 sites in FY 1992, 1,015 interim action at 865 sites in FY 1993, and 1,387 interim actions at 1,173 sites in FY 1994. The cumulative number of interim actions completed by the end of FY 1994 represents an increase of slightly more than 100 percent over the cumulative number of interim actions completed as of the end of FY 1992.
Clean-Up Technologies
* CERCLA Presumptive Remedies
Past CERCLA remedial and removal programmes have identified that similar environmental contamination characteristics are found at certain categories of sites. As a result of compiling evaluation and clean-up data at these sites, Superfund developed presumptive remedies to accelerate future clean-up of contaminated sites. The primary objective of the presumptive remedies initiative is to use past experience to streamline site investigations, accelerate selection of clean-up actions and decrease clean-up costs. Presumptive remedies are preferred technologies for similar types of sites that have been identified based on historical patterns of remedy selection and EPA's scientific and engineering evaluation of performance data on implementation of technology. The use of presumptive methods assists by focusing data collection efforts during site investigations (i.e., RIs, remedial site evaluation) and significantly reducing the evaluation of technologies phase (FS or EE/CA). The Presumptive Remedies identified in EPA's "Presumptive Remedies: Policy and Procedures" document are provided in Appendix 20-7, Table A. The effect of the presumptive remedies on the clean-up process is summarized in Appendix 20-7, Table B.
* Alternative and Innovative Clean-Up Technologies
Because all contaminated sites differ to some extent, especially in their relation to surrounding communities and sensitive ecosystems, a determination must still be made on a site-specific basis as to how a given remedial design is expected to achieve protectiveness during remedial construction as well as during and following remedial action. Protection of human health and the environment is one of two threshold considerations (the other being compliance with ARARs) that must be met in order for an alternative to be eligible for selection as the remedy for any given contaminated site. EPA encourages review of the latest Innovative Technologies Semi-Annual Reports, Engineering Bulletins or other sources for the up-to-date information on the potential effectiveness and applicability of various innovative technologies. It is essential to evaluate whether unusual circumstances exist at a site that create the need to consider non-presumptive remedies based on site-specific conditions and/or community, state, and primary responsible party (PRP) concerns, or the availability of a potentially promising innovative technology.
Alternative treatment technologies are alternatives to land disposal. The most commonly used alternative technologies are solidification/stabilization and incineration. Innovative technologies are alternative remediation technologies that lack performance and cost data in Superfund-type applications.
* Summary of Existing Clean-Up Technologies
There have been many different conventional and innovative remediation technologies implemented at various sites throughout the United States. Some innovative technologies may have only been implemented thus far as pilot-scale studies. Many important site-specific characteristics must be evaluated prior to selecting the most appropriate clean-up technology for a given site. A summary of remediation technologies for soil, sediment and sludges; groundwater; and air are provided in Appendix 20-8, Tables A to C, respectively. These tables provide an overview of types of remedial technologies available, status of the technology, overall cost, targeted contaminants to be treated, time to complete, and brief comments concerning effectiveness or inhibitions. The table also provides information on whether or not each technology is operation and maintenance and/or capital intensive. The list of contaminant groups is intended as a general reference only. A given technology may only treat selected compounds within the constituent groups listed. Secondary contaminant groups identify contaminants that a technology can treat, but is less effective than treating the target constituents or further investigation is required.
* Special Problems posed by UXO and Contaminated Groundwater
Cleaning-up UXO and chemical warfare materials is among the most difficult, dangerous and time consuming and thus expensive tasks DOD is facing. One of the reasons is that some ordnance sites, such as the former naval artillery practice Kahoolawe, Hawaii, are located in remote areas with extremely difficult terrain. Other sites are wooded and difficult to survey.
Until 1994, the US Army Corps of Engineers had identified almost 1,700 sites on which buried ordnance were reported. Current technology to remediate buried ordnance typically involves a survey by operators on foot using hand-held metal detecting equipment. Bulldozers and specially protected heavy equipment are used to dig up buried ordnance and transport it to facilities where it will be de-armed or exploded. The costs are about $65,00 per acre to survey and remediate. Ordnance sites that have been remediated to a specified depth. Experts have testified that buried ordnance sometimes migrates toward the surface with time, so that remediation may be effective only temporarily before an area must be cleaned again. Thus such sites may require periodic monitoring.
Remediation of groundwater remains one of the most vexing problems. Groundwater at many DOD facilities is contaminated by Trichloroethene. In general, current clean-up technology is slow and costly. Determining the location and extent of contamination requires expensive wells for sampling and monitoring. Current systems that pump water from the ground and treat it with scrubbing devices can take years, even decades, to achieve clean-up standards.
* Clean-Up Technology Databases
EPA published a document which lists and describes 25 available Federal databases containing information on contaminated site clean-up technologies; this document is titled "Accessing Federal Data Bases for Contaminated Site Clean-Up Technologies" (EPA, 1992). These databases are periodically updated and provide information such as: clean-up technology descriptions, performance data on existing technology, cost data associated with implementation and operation of various clean-up technologies, and case studies. Some of these databases have user fees. The majority of the Federal databases listed are accessible to the public and many have online capabilities. This document also provides the hardware/software required in order to operate each database.
* Several examples of these data bases include:
· Alternative Treatment Technology Information Centre (ATTIC): contains more than 2,000 abstracts of technical references on alternative treatment methods for remediating hazardous waste.
· CLU-IN Bulletin Board System (BBS): offers messages, bulletins, computer files, and databases that assist in obtaining current information about innovative clean-up technology.
· Defence RDT & E Online System: provides information on DOD's ongoing research and technology efforts.
Post Closure Care (Technologies for Securing)
If upon completion of the closure of a hazardous waste site or completion of the remediation of a contaminated site, it is determined necessary to implement measures to further protect human health and/or the environment, post-closure care measures are identified and implemented. At a minimum, post-closure activities consist of monitoring, reporting, and maintenance activities. Contaminated sites that typically are subject to post-closure activities include former hazardous waste surface impoundments, waste piles, land treatment units and landfills.
Post-closure requirements are implemented if a regulated hazardous waste unit fails to satisfy the regulatory requirements of closure by removal or decontamination. Whenever contaminated soils, subsoils, liners or other substances have been left in place, post-closure activities typically include inspection and maintenance of the final cover and groundwater monitoring wells, as well as the implementation of the applicable groundwater monitoring programme. If all contaminated soils, subsoils, liners and other substances have been removed but the groundwater contamination remains, post-closure activities will include maintenance of the groundwater wells and implementation of the applicable groundwater monitoring programme. For RCRA hazardous waste management units, the list of constituents to sample and analyse for and the analysis methods to be used are identified in the Groundwater Monitoring List in the RCRA regulations. If constituents on the Groundwater Monitoring List were not used or disposed at the hazardous waste management unit in question, analysis of those constituents is not required. Post-closure care is continued for approximately 30 years or a time period defined by the regulating agency, either state or Federal.

20.-10.0 Prioritizing of Sites


Prioritizing sites is necessary because funds are not available to clean-up all contaminated sites at one time; therefore, ranking sites for the purpose of allocating clean-up funds has become an important process in remediating high-risk sites. As discussed earlier in this report, the HRS, developed by EPA, is primarily used to determine if a site should be registered on the NPL. The HRS scoring is conducted with limited data and is not used by EPA to prioritize clean-up at the various sites. Various states have developed prioritizing systems similar to the HRS to evaluate which contaminated sites should be cleaned-up first. This section discusses the mechanisms used by EPA, DOD and DOE for prioritizing contaminated sites for clean-up. Although there are existing prioritizing methods, deficiencies have been identified in each of the systems and a new method that has been developed recently is discussed this Section.
EPA Prioritization
* RI/FS Priority Setting Process
As a result of the unexpected large number of sites on the NPL, EPA has been unable to efficiently complete detailed site studies and remedial action plans. To assist in identifying the more critical sites, EPA developed an informal regional RI/FS priority-setting process which is a systematic procedure that EPA regions must establish to determine priorities for RI/FS projects. This process is applicable to individual sites and is based on a "worst-first" principle. This method is only applicable to sites where the RI/FS could be covered by the Superfund budget which, therefore, excludes CMSs on the NPL list.
* RA Priority-Setting Process
Due to the backlog of unremediated NPL sites, EPA developed an RA priority-setting process in order to determine which sites are to be remediated first. This process incorporates aggregate and subjective evaluations, but is simple so that the reasons for a particular NPL site receiving a given score are clear. Because CMSs are not funded by EPA with the Superfund budget, this process is not applied to DOD sites.
DOD Site Prioritization Processes
In the past, DOD (and DOE) were not under the great external pressure as they currently are to remediate hazardous waste sites. Many DOD sites are located in relatively remote or inaccessible areas as well as national security restricts the public from gaining access to and obtaining information concerning DOD installations. These issues have inhibited public scrutiny of CMSs. The source of funds for DOD clean-ups is the agencies' operating funds, not Superfund; therefore, DOD found it necessary to develop their own priority setting methods: the Defence Priority Model (DMP), to assist in ranking sites for remedial action. Because DOD previously was under less pressure than EPA to make a quick decision of whether a site is contaminated or not, DOD was able to collect more field data for use in the model. The historical practices of DOD for prioritizing which sites to clean-up first are further discussed below.
* General DOD Prioritization
Because CERCLA of 1980 and base closure laws require that all Federal property be cleaned up before it is transferred to non-Federal owners for reuse, DOD, therefore, gives a high priority for clean-up to installations scheduled to close and realign in order to accelerate property transfer to local communities for economic revitalization. DOD also gives high clean-up priority to sites on the EPA's NPL, a register of the nation's worst contaminated sites. Most closing and realigning bases are not on the NPL; therefore, the need for clean-up funding has been accelerated for many installations that would not have been eligible if they were not being closed or realigned. A 1994 GAO report indicated that DOD had too many high priority sites that distracted from remediating the worst sites first.
The Community Environmental Response Facilitation Act (1992) amended CERCLA to expedite the transfer of closed or realigned DOD bases to non-Federal ownership by considering that clean-up actions "have taken place" if they are in place and operating properly and successfully. However, because many of the closed bases are in the early stages of the clean-up process, little of the property has actually been transferred to non-Federal owners. In order to further facilitate non-Federal reuse of the closed bases, Congress in the National Defence Authorization Act (1994) permitted long-term leases of closed base property to non-Federal users; however, few leases have been signed. Issues affecting leases include: (1) government potential liability for hazardous waste generated by tenants; (2) time and effort required to complete documents and processes required by Federal, state, and local laws and DOD policies before property can be leased; and (3) obligation of environmental services to monitor and manage property.
* Defence Priority Model
In November 1987, the Office of Deputy Assistant Secretary of Defence (Environment) of DOD, proposed to establish a prioritization method, the Defence Priority Model (DPM), for relative ranking of IRP sites requiring remedial action. This DPM was not to replace using EPA's HRS, but was to be applied to a site after a RI/FS has been completed as opposed to the HRS which is applied to sites where relatively little information is known (i.e., only PA or SI conducted).
The DPM was used to identify those sites with the highest environmental and health significance so that DERA funding for remedial action was made available to those sites. The DPM scores CMSs based on the following three (3) factors:
· the potential for contaminant transport (pathway subscore);
· characteristics and concentration of each contaminant (hazard subscore); and
· the presence of potential receptors (receptor subscore).
This DPM score, along with other pertinent information such as regulatory requirements and programme efficiencies, is used to determine the relative priority of a remedial action project. The DPM is not intended for use in ranking all CMSs at DOD facilities. Sites posing imminent threats from contamination receive top priority for clean-up and do not become part of the DPM evaluation. In addition, higher priority is assigned to bases undergoing closure - which is not incorporated into the DPM.
The DPM is (absolute) risk-based, includes both human health and ecological impacts (with a significantly greater weight on human health), can be used to rank sites, is not amenable to cost-benefit interpretation, and deliberately omits social and economic impacts from the formal calculations. The model was not developed as a tool for dynamic tracking. It has only been recently that site clean-up has been restricted by lack of funds. With an increasing number of sites with detailed characterization completed, stiffer competition for funds is expected to become evident in the near future. Thus, a need for a prioritizing system that incorporates a larger number of factors is needed. Based on the analyses of the existing prioritizing methods published in "Ranking Hazardous Waste Sites for Remedial Action" (National Research Council, 1994), DOD decided to discontinue use of their modelling approach referred to as the DPM. DOD has developed a new method, Relative Risk Site Evaluation, that is discussed below.
* DOD Relative Risk Site Evaluation
The DOD has developed a Relative Risk Site Evaluation framework as a method of categorizing and prioritizing sites in the DERP into high, medium and low relative risk groups. This categorization of sites is based on the evaluation of contaminants (contaminant hazard factor), contaminant migration pathways (migration pathway factor), and human and ecological receptors of contaminant exposure (receptive factor) in groundwater, surface water, sediment and surface soils. The air media is not currently considered by the relative risk evaluation framework because the risk via the air pathway from DOD sites without soil contamination is currently minimal and the preliminary remediation goals (PRGs) for contaminated soils and water include consideration of inhalation of volatiles and/or contaminated particulates (for soil only). The different sites located at each DOD installation are evaluated separately and each assigned a high, medium or low priority ranking. The evaluation framework assists DOD in ensuring that the DERP funds are directed at those sites and SCSs that pose the highest risk to human health and the environment to the maximum extent feasible. The results of the Relative Risk Site Evaluations will be combined with the assessment of other risk management concerns pertaining to the site, such as regulatory enforcement status of sites and technology availability, prior to the allocation of DERP funds to a particular site.
This rating procedure uses site information gathered from investigations conducted to date and from interviews with site personnel or knowledgeable members of the public and regulatory community. The rating for a site can change by reevaluating that site as additional information becomes available. Sites and SCSs that lack reliable data of contaminant concentrations are not rated using this method but are designated "Not Evaluated" and are deferred, programmed for additional data collection, a removal action if warranted, or other appropriate response action before they are evaluated.
The rating for the contaminant hazard factor (CHF) is determined based on the ratio of the maximum concentration of a contaminant in the media to a risk-based concentration standard for that contaminant. For human health, the risk-based concentration standard for carcinogens is the concentration that presents a 1 in 10,000 risk of increased cancer incidence, which is the remedial action threshold for carcinogens defined by EPA (OSWER Directive 9355.0-30). The original Region IX EPA RBCs, which are based on a one-in-one million risk of increased cancer incidence, were multiplied by 100 to be used in the CHF factor. Region IX EPA updates the RBCs/PRGs on a semiannual basis; therefore, PRGs used in calculating the CHF would also require updating.
The concentration standard for non-carcinogens is the concentration that provides an exposed individual with the daily referenced dose (RfD). The RfD is the estimated daily exposure level of a contaminant to a human population below which adverse non-cancer health effects are not anticipated (see also Section 20.-7.3 and Appendix 20-1). Residential concentrations were used for the soil PRGs provided in Appendix B of the DOD Relative Risk Site Evaluation. Conducting risk assessments and identifying remedial clean-up goals based on the current and future usage of the property in question is currently an important issue being discussed by the Federal government regulators. Considering potential future land use when identifying clean-up goals would increase PRG contaminant concentrations, decrease clean-up cost, and decrease remedial activity time frames.
The development of this Relative Risk Site Evaluation process is relatively new and results of implementation of this evaluation method for prioritizing remedial action at sites are not available.
DOE's ERPS
The DOE developed their own priority setting model called the Environmental Restoration Priority System (ERPS). A brief summary of the technical features of ERPS is described below because it offers another choice in priority setting models; however, because the focus of this report is not on DOE practices, the discussion is brief. ERPS is a comprehensive model that addresses both radioactive and nonradioactive hazardous wastes and is applicable to all DOE sites. Dynamic tracking is an important feature of ERPS that is not offered by DPM. This involves updating the model on an annual basis to be considered in each year's funding allocations and tracks the reductions of risks achieved by ongoing remediations. Similar to DPM, ERPS is used to address longer-term problems; immediate risks were to be addressed separately from ERPS. ERPS includes cost estimation for remediation and associated risk reduction achievements. ERPS allows input of subjective judgement in the scoring process if adequate scientific data are not available for the site in question. This allows for "user friendliness" but can also lead to poor decision-making if abused or used by unqualified personnel.

20.-11.0 Health and Safety


Historical incidents created concerns for the safety and health of communities in the vicinity of contaminated sites. In addition, historical accidents and contaminant exposure incidents caused concern for employees exposed from working in the areas of contamination, those handling hazardous waste and those involved with the investigation and clean-up of hazardous waste.
In 1985, a consortium of federal agencies consisting of NIOSH, OSHA, USCG, and the EPA, published the "Occupational Safety and Health Guidance Manual for Hazardous Waste Site Activities". This guidance document, not regulation, was produced due to the need for direction for workers that had been employed to carry out the work detailed in CERCLA. In 1986, Section 126 of SARA mandated OSHA to promulgate a rule that would protect both emergency response and hazardous waste workers from the effects of hazardous materials exposure during their work. In December 1986, OSHA established the Interim Final Rule 29 CFR 1910.120, Hazardous Waste Operations and Emergency Response, which was basically a rewrite of the 1985 guidance document. The final rule passed in March 1989 and became effective March 6, 1990.
OSHA's 29 CFR 1910.120 addresses health and safety programmes including site work plans and site-specific health and safety plans; site characterization and analysis such as required personal protective equipment, monitoring equipment required, risk identification and other essential factors; site control; training requirements; medical surveillance programme requirements; drum and container handling requirements; decontamination; emergency response measures; and other health and safety factors.
Various DOD components, such as the US Army Corps of Engineers (USACE) and the Air Force have their own health and safety manuals which are prepared based on 29 CFR 1910.120 health and safety requirement. Other DOD components follow OSHA health and safety requirements.

20.-12.0 Cost Estimates


In the period 1984 to 1995, DOD had devoted more than 10 years and $11 billion to identifying, studying and cleaning-up contamination on thousands of military installations across the nation. Defence agencies have identified more than 27,000 suspected contaminated sites on more than 9,700 military installations and former defence properties in all 50 states. About 17,000 sites are expected to require environmental clean-up. Using today´s technology, the cost to remediate DOD sites alone is estimated at $30 to 35 billion, and the total cost of clean-up at current and former defence sites including DOE sites is projected to exceed $200 billion. How carefully such estimates have to be viewed at, is shown by the development of cost estimates over the last years: in 1989 DOD estimated that completing the clean-up programme would cost between $6.9 and $13.7 billion (1995 dollars). Now, it is considered that the programme costs may exceed $30 billion. The Inspector General of DOD found that average clean-up costs for defence facilities scheduled to be closed were typically about 60 percent higher than initial estimates.
During the last decade, DOD´s spending for environmental clean-up in average has increased 23% each year. In 1984, DOD spent about $200 million for clean-up; in 1995, the Congress authorized DOD to spend about $2.5 billion on environmental clean-up programmes. A similar amount will be required in 1996. DOD, however, expects significant reductions in spending for environmental clean-up in the next years, when many projects will begin the transition from study and analysis to remediation. Until 1994, most of the clean-up budget was allocated for studies; clean-up costs first exceeded 50 percent in 1994 when relatively few sites were actually in the final phase of clean-up. Emerging technologies now being developed or field tested also suggest a significant potential for cost savings (see Sections 20.-4.0 and 20.-13.0).
There is much uncertainty about future costs. For example, each year the department identifies new contaminants on existing sites as well as additional polluted sites. Furthermore, most sites are still in the study phase and the price development at the clean-up market in the time needed to complete studies, analyses and remediation is difficult to project. Recent court rulings could also drive costs by leading to stricter clean-up standards than those DOD originally has planned to meet.
The different DOD components utilize various cost estimating systems for developing detailed cost estimates and cost engineering analyses of projects that need to be implemented. Costs developed are used to assist DOD in budget planning for the various types of environmental projects (site investigations, remedial/removal activities, O&M activities, and projects necessary to maintain or achieve regulatory compliance). The Navy utilizes the Naval Facilities (NAVFAC) Cost Engineering System (CES) software and the Army and Air Force utilize the Microcomputer Aided Cost Estimating System (MCACES) software for developing detailed cost estimates and cost engineering analyses. Cost estimates using both of these cost estimating systems can be prepared using the standard building system structure as well as the new DOD Work Breakdown Structure. If cost estimates for certain products, labour or other tasks are not available in the NAVFAC CES or MCACES databases, Means Cost Data Books and/or ECHOS Environmental Restoration: Assemblies Cost Book are used as sources for obtaining cost estimates. Both sources update cost estimates on a regular basis.
Cost estimates are typically generated by contractors at the same time the remediation designs are prepared. Once the design(s) accompanied by the associated cost estimate(s) is submitted for a CMS and funds have been allocated, the design project is advertised for contractors to submit bids for completing the remediation.

20.-13.0 Research and Development (R&D)


The development of innovative technology is essential to increasing efficiency and effectiveness of fulfilling environmental restoration demands facing DOD. Innovative technologies are likely to provide significant potential for cost savings both during site characterisation and during clean-up (see Section 20.-4.0). DOD thus has developed and implemented a strategy that is designed to foster technologies that address DOD environmental needs, identify cost-effective technologies, overcome barriers to the application of technologies, expedite commercialization of technologies, and enhance US competitiveness in the global market.
The methodology for technology development is supported by the integrated efforts of the DOD components and is coordinated through the Office of the Secretary of Defence. In order to support research and development (R&D) technologies for remediation, sampling and analysis, and other such actions, DOD is using programmes outside of DERA and BRAC, such as the Strategic Environmental Research and Development Programme (SERDP), the services' Research, Development, Testing and Evaluation (RDT&E) programmes, and the DOD National Environmental Technology Demonstration Programme (DOD/NETDP).
A list of clean-up projects funded through SERDP in the financial years 1995 and 1996 is contained in Appendix 20-9. It exhibits that the clean-up programme of SERDP focuses on conducting research and development on the issues remediation technologies, monitoring and characterization methods and technologies, and assessment methods. In 1996, there is evidence of a certain shift of focus as new projects - among others - serve to better understand the fate of contaminants under natural conditions. The relevant projects involve research on the natural attenuation of contaminants and subsurface bioremediation process monitoring indicators.
DOD components and EPA are selecting characterized CMSs with appropriate contaminants to serve as test locations, developing common Quality Assurance and Quality Control procedures, and developing coordinated dissemination mechanisms for reporting results of technology demonstrations and evaluations. The components and EPA will establish partnerships with government and private interests to carry out technology demonstrations at selected sites and will provide researchers and developers with technical and field support. The following sites in DOD/NETDP already have been identified:
· Port Hueneme Naval Construction Battalion Centre sites for technologies for fuel hydrocarbon remediation
· Volunteer Army Ammunition Plant sites for demonstration involving technologies for the remediation of energetics and heavy metals contamination
· Wurtsmith Air Force Base for development and testing of integrated biological/Physicochemical remediation processes and evaluation of innovative monitoring and measurement technologies
· McClellan Air Force Base sites for demonstrating technologies for solvent remediation
· Dover Air Force Base to house the Groundwater Remediation Field Laboratory.
DOD's Environmental Security Technology Certification Programme (ESTCP) is designed to move promising new technologies that address DOD specific environmental problems from DOD laboratories to CMSs for demonstration and validation. DOD's innovative technologies are shared with other federal agencies and are introduced to the commercial market in order to expedite restoration of CMSs and to receive economic benefits for DOD's R&D investments. DOD has reviewed innovative technologies and is currently selecting technologies that appear promising to fund for demonstration. DOD expects to fund up to 40 technology demonstrations, the majority of which will feature clean-up technologies. More detailed information on what types of technologies are likely to be tested were not yet available.
The Federal Remediation Technologies Round table (the Round table) was created to exchange information on hazardous waste site remediation technologies, to consider cooperative efforts of mutual interest, and to develop strategies that could lead to a greater application of innovative technologies. The member agencies of the Round table consist of the USEPA, DOE, DOI and DOD (includes Army, Navy and Air Force). The Round table compiles information and data collected in case studies on remedial technology including bioremediation, groundwater treatment, soil vapour extraction, thermal desorption, soil washing, in situ vitrification, and other remedial technologies. As additional information is gathered on these technologies, documentation is be developed and supplemented. The Round table also established guidelines to documenting cost and performance for evaluating remediation projects.

References


AEHA (U.S. Army Environmental Hygiene Agency): Health Risk Assessment for Consumption of Deer Muscle and Liver From Joliet Army Ammunition Plant. Joliet, Illinois, Project No. 75-51-YF23, Aberdeen Proving Ground, Maryland. June 1994
Anslow, W. P., and Houck, C. R.: Systemic Pharmacology and Pathology of Sulfur and Nitrogen Mustards. Chemical Warfare Agents and Related Chemical Problems, Chapter 22, Summary of Technical Report of Division 9, NDRC, pp. 440-478 and 731-737. 1946
APG (U.S. Army Aberdeen Proving Ground): Focused Feasibility Study, Operable Unit A (Draft). Prepared by Dames & Moore for Hazardous Waste Remedial Actions Program, Oak Ridge, Tennessee, under contract to U.S. Army Aberdeen Proving Ground Installation Restoration Program. January 1995
APG (U.S. Army Aberdeen Proving Ground): Risk Assessment Framework Carroll Island and Graces Quarters, Aberdeen Proving Ground, Edgewood, Maryland (Draft). Prepared by Dames & Moore for Hazardous Waste Remedial Actions Program, Oak Ridge, Tennessee, under contract to U.S. Army Aberdeen Proving Ground, Maryland. May 1995
ATSDR (U.S. Agency for Toxic Substances and Disease Registry): Toxicological Profile for Cadmium, Draft Version for Public Comment. 1991
ATSDR (U.S. Agency for Toxic Substances and Disease Registry): Toxicological Profile for Selected PCBs (Aroclor-1260, -1254, -1248, -1242, -1232, -1221, and -1016,) Draft Version for Public Comment. 1991
Burmaster, D. E. and Lehr, J.H.: It's Time to Make Risk Assessment a Science. Ground Water Monitoring Review, Vol. 11, No. 3, pp. 5-15. 1991
Butler, J. D., et al.: Some Observations on the Polycyclic Aromatic Hydrocarbon (PAH) Content of Surface Soils in Urban Areas. The Science of the Total Environment, Vol. 33, pp. 75-85. 1984
Chemical Stockpile Disposal Program: Final Programmatic Environmental Impact Statement, Program Executive Officer-Program Manager for Chemical Demilitarization, Aberdeen Proving Ground, Maryland. 1988
Congressional Budget Office: Cleaning Up Defense Installations: Issues and Options. CBO Papers. January 1995
Daley, P.: Military Marches Toward New Horizons in Pollution Control. Pollution Engineering, Peter Daley. February 1984
Department of Defense: Restoration Advisory Board Report to Congress for Fiscal Year 1995. 1996
Deputy Secretary of Defense: Memorandum for Secretaries of the Military Departments Under Secretary of Defense, Environmental Remediation Policy for DOD Activities Overseas. October 1995
Ehreth, D.: Notes from Defense Clean-up Conference: 26-27 October 1995 (Dames & Moore internal document)
Environmental Law Institute: Superfund Deskbook. The Environmental Law Reporter, Environmental Law Institute. 1989 Edition.
Farkas Berkowitz & Company: Overview of the DOD Remediation Market in the Northeast. Farkas, Borkowitz & Company. 1995
Federal Remediation Technologies Round Table, 1995: Guide to Documenting Cost and Performance for Remediation Projects. USEPA/542/B-95/002. March 1995
Federal Remediation Technologies Round Table, 1995. Abstracts of Remediation Case Studies, USEPA/542/R-95/001. March 1995
Federal Remediation Technologies Round Table, 1992: Accessing Federal Databases for Contaminated Site Clean-Up Technologies. 2nd Edition, USEPA/542/B-92/002. August 1992.
Forester, W. S. and Skinner, J. H.: International Perspectives on Hazardous Waste Management. 1987
Gilbert, R.O.: Statistical Methods for Environmental Pollution Monitoring, Van Nostrand Reinhold, New York. 1987
Hazardous Materials Control Resources Institute: 1994 Federal Environmental Restoration III and Waste Minimization Conference and Exhibition Proceedings. New Orleans, LA. 27-29 April 1994
Hazardous Waste Action Coalition (HWAC): HWAC Government Affairs Committee Meeting. 18 December 1995
Houghton, A. and Siegel, L.: An Excerpt from the Military Contamination and Clean-up Atlas for the United States. 1995
ICF-Clement Associates, Inc.: Comparative Potency Approach for Estimating the Cancer Risk Associated With Exposure to Mixtures of Polycyclic Aromatic Hydrocarbons. Interim Final Report. Contract No. 68-02-4403, USEPA. 1988
Kingery, A.F., and Allen, H.E.: Environmental Fate of Alkyl Methylphosphonates Arising from Chemical Surety Material (CSM) and Potential Non-CSM Sources in Soil and Aqueous Media, Final Report, U.S. Army Environmental Center, Technical Support Division, Aberdeen Proving Ground, Maryland. March 1994
McKone, T.E.: Conventional Weapons Demilitarization: A Health and Environmental Effects Data Base Assessment. Methods for Estimating Multi-Pathway Exposures to Environmental Contaminants. Final Report, Phase II. UCRL-21064. Lawrence Livermore National Laboratory. June 1988
Mecler, F.J.: Mammalian Toxicological Evaluation of DIMP and DCPD (Phase 3-IMPA), U.S. Army Medical Research and Development Command, Environmental Protection Research Division, Fort Detrick, Maryland. 1981
Munch, D.: Soil Contamination Beneath Asphalt Roads by Polynuclear Aromatic Hydrocarbons, Zinc, Lead and Cadmium. The Science of the Total Environment, Vol. 126, pp. 49-60.1992
National Research Council: Ranking Hazardous Waste Sites for Remedial Action. National Research Council, 1994
National Research Council: Recommended Dietary Allowances. 10th rev. ed., Food and Nutrition Board, National Research Council, National Academy of Sciences Press, Washington DC. 1989
Norback, D.H., and Weltman, R.H.: Polychlorinated Biphenyl Induction of Hepatocellular Carcinoma in the Sprague-Dawley Rat. Environmental Health Perspective, Vol. 60, pp. 97-105. 1985
Reynolds, M. L., et al.: Relationship Between the Biodisposition of (3H)soman and its Pharmacological Effects in Mice. Toxicol. Appl. Pharmacol. Vol. 80, No. 3, pp. 409-420. 1985
Roach, M.C., et al.: Fluorescence Detection of Alkylphosphonic Acids Using p-(9-anthroyloxy) Phenacyl Bromide. Army Research Office, Research Triangle Park, NC, Government Reports Announcements and Index, Issue 18 (NTIS/AD-A180 870/9). 1987
Roels, H.A., et al.: Assessment of the Permissible Exposure Level to Manganese in Workers Exposed to Manganese Dioxide Dust. British Journal of Industrial Medicine, Vol. 49, pp. 25-34. 1992
Rosenblatt, D., et al.: Problem Definitions on Potential Environmental Pollutants II, Physical, Chemical, Toxicological, and Biological Properties of 16 Substances. U.S. Medical Research and Development Laboratory, Frederick, Maryland. 1975
Scott, C.D., and Worthy, E.G.: The Toxicity of Methylphosphonic Acid to Some Aquatic Species of Plants. Edgewood Arsenal Technical Memorandum, EB-TM-73011, Biomedical Laboratory, Edgewood Arsenal, Aberdeen Proving Grounds, MD 21010. E.G. 1974
Sax, N.I., and Lewis, R.J. Sr.: Dangerous Properties of Industrial Materials. Seventh Edition, Van Nostrand Reinhold Publishers, New York, pp. 756. 1989
Shroeder, H.A. and Mitchener, M.: Life-Term Studies in Rats: Effects of aluminum, Barium, Beryllium, and Tungsten. J. Nutrition, Vol. 105, pp. 421-427. 1975
Shacklette, H.T., and Boerngen, J.G.: Element Concentrations in Soils and Other surficial Materials of the Conterminous United States. U.S. Geological Survey Professional Paper 1270. 1984
Takada, H., Onda, T., Ogura, N.: Determination of Polycyclic Aromatic Hydrocarbons in Urban Street Dusts and Their Source Materials by Capillary Gas Chromatography. Environmental Science and Technology, Vol. 24, pp. 1179-1186. 1990
USAEC (U.S. Army Environment Center): Recommended Analytical Methods for Obtaining Adequate Quantitation Limits for Use in Risk Assessments at Aberdeen Proving Ground. Aberdeen Proving Ground, Edgewood, Maryland. March 1995
USAEC (U.S. Army Environment Center): Reference Sampling and Analysis Program: Soil Sediment, and Surface Water Reference Data Report. Draft Final, Aberdeen Proving Ground, Edgewood, Maryland. March 1995
U.S. Army: Policy and Guidance for Identifying U.S. Army Environmental Program Requirements. Environmental, Pollution Prevention, Control and Abatement Report RCS DD-P&L (SA) 1383 (OMB A-106 Report), Vol. II, Edition III. July 1993
U.S. Army: Policy and Guidance for Identifying U.S. Army Environmental Program Requirements. Environmental, Pollution Prevention, Control and Abatement Report RCS DD-P&L (SA) 1383 (OMB A-106 Report), Vol. I, Edition III. 4 September 1992
U.S. Army Corps of Engineers (USACE), latest revision. Safety and Health Requirements Manual. EM 385-1-1, latest revision.
U.S. Army Corps of Engineers (USACE): Expediated Clean-up Subcommittee Report on Streamlining Environmental Site Remediation. U.S. Army Corps of Engineers and HWAC. 1 November 1995
U.S. Army Waterways Experiment Station: Wetlands Delineation Manual, Technical Report Y-87-1, U.S. Army Corps of Engineers. 1987
Department of Defense,: Defense Environmental Restoration Program. Annual Report to Congress for Fiscal Year 1994. 31 March 1995
U.S. Department of Defense: Relative Risk Site Evaluation. Summer 1994 (Interim Edition). 27 October 1995
U.S. Department of Defense: Defense Environmental Clean-Up Program. Annual Report to Congress for Fiscal Year 1993, 31 March 1994
U.S. Environmental Protection Agency (USEPA): Personal communication, Doug Gritzinger, Dames & Moore, with Charles Ris, USEPA Office of Research and Development, Office of Health and Environmental Assessment, Human Health Assessment Group. 25 January 1995
USEPA: Risk-Based Concentration Table. January-June 1995, memorandum from R.L. Smith, USEPA Region III, to RBC Mailing List. 7 March 1995
USEPA: Health Effects Assessment Summary Tables (HEAST). FY 1994 Edition, Office of Research and Development, Washington DC. March 1994
USEPA: Integrated Risk Information System (IRIS), online (updated monthly). Office of Health and Environmental Assessment, Environmental Criteria and Assessment Office, Cincinnati, Ohio. 1994
USEPA: Revised Interim Soil Lead Guidance for CERCLA Sites and RCRA Corrective Action Facilities. memorandum from E. P. Laws, Assistant Administrator, Office of Solid Waste and Emergency Response, to USEPA Regional Administrators. 14 July 1994.
USEPA: Soil Screening Guidance. USEPA/540/R-94/101, Office of Solid Waste and Remedial Response, Washington DC. December 1994
USEPA: Subchronic and Chronic Systemic Toxicity Information for Multiple Chemicals (Joliet Army Ammunition Plant LAP Area/Joliet, IL), Attachment I, Risk Assessment Issue Paper for Derivation of a Provisional Subchronic Inhalation RfC for Benzene (CASRN 71-43-2). memorandum from Joan Dollarhide, Superfund Health Risk Technical Support Center, Environmental Criteria and Assessment Office, Cincinnati, Ohio, to Nan Gowda, USEPA Region V, Chicago, Illinois. 13 June 1994
USEPA: Memorandum: Role of the Ecological Risk Assessment in the Baseline Risk Assessment. OSWER Directive No. 9285.7-17. Washington DC. 1994
USEPA: Presumptive Remedies: Policy and Procedures. USEPA 540-F-93-047. September 1993
USEPA: Provisional Guidance for Quantitative Risk Assessment of Polycyclic Aromatic Hydrocarbons. USEPA/600/R-93/089, Office of Research and Development, Washington DC. July 1993
USEPA and U.S. Air Force: Remedial Technologies Screening Matrix. Reference Guide. Version I. July 1993
USEPA: Selecting Exposure Routes and Contaminants of Concern by Risk-Based Screening. Technical Memorandum (USEPA/903/R-93-001), USEPA Region III, Hazardous Waste Management Division, Office of Superfund Programs. January 1993
USEPA: Wildlife Exposure Factors Handbook. Volume I and II. USEPA/600/R93/187a. Washington DC. December 1993
USEPA: Dermal Exposure Assessment: Principles and Applications (Interim Report). EPA/600/8-91/011B, Office of Research and Development, Washington DC. 1992
USEPA: Guidance for Data Useability in Risk Assessment (Part B). Publication 9285.7-09B, Office of Emergency and Remedial Response. May 1992
USEPA: Human Health Evaluation Manual, Supplemental Guidance: Interim Dermal Risk Assessment Guidance (Draft). Office of Emergency and Remedial Response, Washington DC. September 1992
USEPA: Supplemental Guidance to RAGS: Calculating the Concentration Term. Publication 9285.7-081, Office of Emergency and Remedial Response. May 1992
USEPA: Systemic and Carcinogenic Information for Multiple Chemicals, Attachment 1, Risk Assessment Paper for Systemic Toxicity and Carcinogenicity of Aluminum (CASRN 7429-90-5). memorandum from the Office of Emergency and Remedial Response, Washington DC, to Pat VanLeeuwan, EPA Region V, Chicago, Illinois. 4 May 1992
USEPA: Risk Assessment Guidance for Superfund, Supplemental Guidance, Standard Exposure Factors (Interim Final), Office of Emergency and Remedial Response, Washington, DC. 1991
USEPA: Risk Assessment Guidance for Superfund - Volume 1 Human Health Evaluation Manual (Part B, Development of Risk-Based Preliminary Remediation Goals) (Interim). Office of Emergency and Remedial Response, Washington DC, PB92-963333. 1991
USEPA: Chemical Concentration Data Near the Detection Limit. Region III, Hazardous Waste Management Division, Philadelphia, Pennsylvania. 1991
USEPA: Exposure Factors Handbook. EPA/600/6-89/043. Office of Health and Environmental Assessment, Washington DC. 1990
USEPA: RCRA Orientation Manual. 1990 Edition. 1990
USEPA: Risk Assessment Guidance for Superfund - Volume 1 Human Health Evaluation Manual (Part A) (Interim Final), Office of Emergency and Remedial Response, Washington DC, EPA/540/1-89/002. 1989
USEPA: Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA, OSWER Directive 9335.3-01. Office of Solid Waste and Emergency Response. Washington, DC. 1988
USEPA: Guidelines for Carcinogenic Risk Assessment. 51 Federal Register, 185:33, 992.1986
U.S. General Accounting Office: Environmental Protection: Challenge in Defense Environmental Program Management. GAO/T-NSIAD-95-121.
Versar: Moving Sites Faster Through Streamlined Oversight. U.S. Air Force Project MUHJ947070. August 1995
Wolff, M. S., et al.: Polycyclic Aromatic Hydrocarbon (PAH) Residues on Skin in Relation to Air Levels Among Roofers. Archives of Environmental Health, Vol. 44, No. 3, pp. 157-163. 1989

Appendix

Appendix 20-1:

Details on Calculating Risk Assessment Parameters
Estimating Contaminant Intake
The generic equation for estimating contaminant intake is:

Click here for Picture

where:
I = intake
EPC = exposure point concentration
CR = contact rate (mg/day)
FI = fraction ingested
EF = exposure frequency (days/yr)
ED = exposure duration (years)
BW = body weight (kilograms)
AT = averaging time (days).
The EPC is expressed in mg/kg for soil and sediment and in µg/L for water. CR is the amount of contaminated medium contacted per unit of time or event via the given exposure route (for this HHBRA, ingestion, inhalation, and dermal). EF is the annualized frequency of contaminant contact. ED is the duration of contact. BW is the average weight of the receptor over the period of exposure. AT is the period over which the exposure is averaged. For noncarcinogens, AT is the total duration of exposure in days (i.e., 365 days times the ED); for carcinogens, it is the average human lifespan, assumed to be 70 years, in days. This difference is due to differences in how noncarcinogenic and carcinogenic effects are modelled. For carcinogens, a high dose in a brief period is modelled as equivalent to a lower dose over an extended period; for noncarcinogens, the magnitude of intake per unit of time matters.
Appendix 20-1: (continued)
Reference Dose
A chemical's RfD is most often based on its no observed adverse effects level (NOAEL) or lowest observed adverse effects level (LOAEL) in human or animal studies. To account for variability and uncertainties in human responses, the effects level is divided by uncertainty and modifying factors (UFs and MFs), which are typically two to three orders of magnitude. In equation form:
Click here for Picture


The Human Health Toxicity Hazard
For noncarcinogenic effects, the human health toxicity hazard from exposure to a single chemical is calculated as follows:
Click here for Picture

where:
HQ = hazard quotient
I = intake (mg/kg-day)
RfD = reference dose (mg/kg-day).

Appendix 20-2:

CMS Categories and Site Types


CMS Categories Site Types



Base Operations:
Building Demolition/Debris Removal
Contaminated Buildings
Dip Tank
Incinerator
Oil Water Separator
Storage Area
Washrack
Maintenance Yard


Radioactive Areas:
Mixed Waste Areas
Radioactive Waste Areas


Storage Tanks:
ASTs
POL Lines
USTs
UST Farm


Surface Discharge Areas:
Drainage Ditch
Industrial Discharge
Sewage Effluent Settling Ponds
Storm Drain
Surface Impoundment/Lagoon
Surface Runoff
Spill Site Area
Surface Disposal Area


Industrial Operations:
Optical Shop
Pesticide Shop
Plating Shop
Sewage Treatment Plant
WWTP
Waste Lines


Subsurface Disposal Areas:
Chemical Disposal
Disposal Pit/Dry Well
Landfill
Leach Field


Training Areas:
Burn Area
Explosive Ordnance Disposal Area
Fire/Crash Training Area
Firing Range
Pistol Range
Small Arms Range
Unexploded Munitions/Ordnance Area


Contaminated Media:
Contaminated Fill
Contaminated Groundwater
Contaminated Sediments
Contaminated Soil Piles
Soil Contamination After Tank Removal


Other:
Miscellaneous Areas


Appendix 20-3:

Site Type Definitions and Contamination Profiles


Site Category


Site Type


Site Description1


Primary Contaminants


Base
Operations


Building Demolition/
Debris Removal


· Consists of bldgs. and/or debris that are unsafe or must be removed.


· Asbestos
· Construction debris
· Lead paint


Contaminated Building


· Results from releases within or on the outside of a structure of a substances that has been contained within the building.


· POLs · PCBs
· Plating waste · Propellants
· Metals · Pesticides
· POL sludge · Solvents
· Asbestos · Acids


Dip Tank


· Typically metal or concrete units located in coating shops that range in size from 50 to more than 500 gallons.
· Used to clean parts prior to treatment, or to coat parts with various materials including metals and plastics.


· POLs · Metals
· Chlorinated solvents · Acids


Incinerator


· Consist of a furnace and stack unit used for a variety of disposal activities including the incineration of medical waste, or an installation DOD's dunnage.
· Vary in size and may either be freestanding or part of other operations such as hospitals.


· Ash
· Metals
· Ordnance compounds


Oil/Water Separator


· Typically small units that skim oil from stormwater runoff.
· Consists of the unit and any associated piping.


· POLs · Solvents
· Industrial wastewater · PCBs


Storage Tanks


Storage Area


· Area where spills and leaks occurred from stored containers or equipment.


· POLs · Metals
· Solvents · Acid
· POL sludge · PCBs


Washrack


· Typically consists of a building designed for washing vehicles such as tanks, aircraft, and other military vehicles.
· May consist of a paved area where washing of vehicles occurs.


· POLs


Maintenance Yard


· Consists of paved or unpaved areas where vehicles and other maintenance equipment is stored and often serviced.
· Typically used for storage of maintenance supplies.


· POLs
· Metals
· Solvents


Storage
Tanks


ASTs


· Result from release of substances to surrounding areas of ASTs, containers and any associated piping.


· POLs (e.g., heating oil, jet fuel, gasoline, and POL sludges)


POL Distribution Line


· Used to transport POL products from storage to dispensing facilities.


· POLs (e.g., heating oil, · POL sludge
jet A, diesel & other fuels)


USTs


· Result from the release of substances from USTs and any associated piping.


· POLs · Solvents
· POL sludges · Metals


UST Farm


· Result from the release of substances from multiple, typically large, USTs and associated piping which make up a tank farm complex.


· POLs · Solvents
· POL sludges · Metals


Industrial
Operations


Optical Shop


· Typically consist of laboratory units located within a building.
· Activities include grinding lenses used in eye glasses or other optical instruments.


· Solvents


Pesticide Shop


· Used to store and prepare large volumes of pesticides and solvents for maintenance activities.
· May be located in a freestanding bldg. or attached to another bldg.
· Areas near unit may have been used for disposal of off-specification pesticides.


· Pesticides
· Metals
· POLs


Industrial
Operations


Plating Shop


· Typically consists of a bldg. or room within a bldg. used for coating metals parts.
· The unit contains several tanks of solvents which are used in the plating process.


· Metals · Acids
· Solvents · Industrial wastewater


Sewage Treatment
Plant


· Consists of a complex of tanks, piping, and sludge management areas used to treat sanitary sewage generated at an installation.
· May use chemical or biological treatment methods.
· Lagoons associated with the biological treatment of sewage currently may be considered to be separate units.


· Metals · Solvents
· Industrial wastewater · POLs


WWTP


· Results from releases of substances of plants that were used to treat and dispose of domestic and/or industrial wastewater.


· POLs · Plating sludges
· Solvents · Explosive chemicals
· Industrial wastewater


Waste Line


· Underground piping used to carry industrial wastes from shop facilities to WWTP.


· Solvents · Metals
· Plating sludges · Pesticides
· Explosive chemicals


Training
Lines


Burn Area


· Consists of piles or surface areas that were used for open-air incineration of waste.


· POLs (e.g., spent motor · Explosives
oil and jet fuel) · Propellants
· Solvents (e.g., spent · Ordnance
paint thinners, and
degreasing agents)


Explosive/Ordnance
Disposal Area


· Consists of open-air areas that were used to detonate, demilitarize, bury, or dispose of explosives.


· Unexploded ordnance · Explosive chemicals
(UXO) · Metals
· Ordnance compounds


Fire/Crash
Training Area


· Consists of trenches and/or pits where flammable materials were ignited periodically for demonstrations and training exercises.


· POLs · POL sludges
· Solvents · Metals


Firing Range


· Consists of large areas of land used for practice firing of large artillery or mortars, or as a practice bombing range for aircraft.
· Typically contaminated with unexploded ordnance which may be found both on and below the ground surface.


· Metals · UXO
· Ordnance compounds · Radionuclides
· Explosives


Pistol Range


· May be located indoors or outdoors and are used for target practice.
· Outdoor units include a soil or sandbag berm located behind the targets to prevent bullets from travelling outside the range area.


· Metals


Small Arms Range


· Typically located outdoors and used for target practice of small arms, usually 50 caliber or less.
· May include a soil or sandbag berm, or hill located behind the targets to prevent bullets from travelling outside the range area.


· Metals
· Ordnance compounds


Unexploded Munitions/
Ordnance Areas


· Consists of areas that have been used for munition and ordnance training.


· UXO · Explosive chemicals
· Metals · Ordnance compounds


Mixed Waste Areas


· Consists of areas used to store or dispose of hazardous wastes that have been mixed with or contaminated by radioisotopes.


· Solvents
· Mixed waste


Low-Level
Radioactive Waste Area


· Consists of areas used to store or dispose of low-level radioactive materials of various types (e.g., radium paint, and radioactive instruments and propellants).


· Low-level radioactive waste


Surface
Discharge
Area


Drainage Ditch


· Typically consists of a natural or man-made ditch used as a runoff control structure for rainfall.
· May also be used for runoff from other sources such as process operations.
· Man-made units may be concrete lined.


· POLs · Metals
· Solvents · Explosive chemicals
· PCBs


Industrial Discharge


· Consists of a pipe system used to discharge industrial effluent to the environment.
· May discharge to a natural or man-made water body, or to dry creek bed or some other natural feature.


· Metals
· Industrial wastewater


Sewage Effluent
Settling Pond


· Consists of a lagoon used for the settling of solids and/or biological treatment of sewage.
· May also be used as infiltration galleries.


· Metals
· Ordnance compounds
· Solvents


Storm Drain


· Typically consists of a natural or man-made drain used as a runoff control structure for rainfall.
· May also be used for runoff from other sources such as process operations.
· Man-made units may be concrete lined.


· POLs · Pesticides
· Metals · Industrial wastewater
· POL Sludge · Solvents


Surface Impoundment/
Lagoon


· Consists of unlined depressions, excavations, or diked areas which were used to accumulate liquid waste, waste containing free liquid, or industrial waste waters.


· POLs · Metals
· Solvents · Ordnance compounds
· Explosive chemicals · Industrial wastewater


Surface Runoff


· Consists of an area with sheet runoff from rain.
· May occur anywhere within a facility, particularly adjacent to industrial areas and airfield aprons.


· POLs · Solvents
· Metals · Explosive chemicals


Surface Discharge Area


Spill Area


· Are small areas where spills from drums, tanks, and other waste storage units have taken place.


· POLs · Metals
· Solvents · PCBs
· POL Sludge


Surface Disposal Area


· Consists of small areas formerly used for disposal of solid wastes with little or no free liquids.
· Typical materials include rags, filters, paint cans, small capacitors, and batteries.


· POLs · Metals
· Solvents · Acids
· Pesticides · PCBs
· Paints


Subsurface
Disposal Areas


Chemical Disposal


· Are areas that have been used for the disposal of chemicals, typically of an unknown type.
· May be a burial area where bottles or packages of chemicals were placed or an area where liquids were disposed of on the soil.


· POLs · Solvents
· Metals · Explosive chemicals


Disposal Pit/
Dry Well


· Consists of small unlined excavations and structures that were used over a period of time to dispose of small quantities of liquid wastes.


· POLs (e.g., motor oil) · Explosive chemicals
· Acids (e.g., battery acid) · Ordnance compounds
· Metals · Solvents


Landfill


· Are typically areas formerly used to dispose of both domestic and industrial hazardous waste.


· POLs · Pesticides
· Solvents · Metals
· Paint · Ordnance compounds


Surface Discharge Area


Leach Field


· Typically consists of a subsurface area generally associated with septic tanks.
· Serves the purpose of biologically treating sanitary sewage; however, in cases where these units were used at industrial facilities, there is also contamination from non-biodegradable industrial contaminants.


· Metals
· Solvents


Contaminated
Media


Contaminated Fill


· Consists of contaminated fill resulting from excavations for construction, tanks, and other purposes.


· POLs · Explosive chemicals
· Metals · Paint waste
· Ordnance compounds


Contaminated
Groundwater


· Results from various types of releases of known or unknown origin, such as migration of leachate from disposal areas and migration of substances from contaminated surface and subsurface soils.


· POLs · Metals
· Chlorinated solvents · Explosive chemicals
· Non-chlorinated solvents


Contaminated
Sediments


· Includes sediments of water bodies that have been contaminated by surface runoff, subsurface migration, or direct discharge of contaminants.


· POLs · Metals
· PCBs · Solvents
· Pesticides · Explosive chemicals


Contaminated
Soil Piles


· Consists of soil that has been staged after an excavation activity.


· POLs · Solvents
· Sludge · PCBs
· Metals · Ordnance compounds


Soil Contaminated
After Tank Removal


· Consists of soil that has been removed during a tank removal operation and staged prior to treatment.


· POLs
· POL sludge


Notes:
1 The site descriptions provided in this table are not intended to be all-encompassing or exact regulatory definitions.
They provide only general descriptions of the different categories of DOD sites.
AST Aboveground storage tanks
bldg. building
PCB Polychlorinated biphenyl
POL Petroleum, oil and lubricants
UST Underground storage tank
UXO Unexploded ordnance
WWTP Wastewater Treatment Plant

Appendix 20-4:

Total Number of Contaminated Sites by Category1 DOD and its Components


Site
Category


Site Types


Total Number of Military Sites







Army


Navy


Air Force


DLA


FUDS


DOD Total2


Base Operations


Building Demolition/Debris Removal; Contaminated Buildings; Dip Tank; Incinerator; Oil Water Separator; Storage Area; Washrack; Maintenance Yard


4,120


762


167


129


421


5,599


Storage Tanks


ASTs; POL Lines; USTs; UST Farm


1,668


905


885


77


924


4,459


Industrial
Operations


Optical Shop; Pesticide Shop; Plating Shop; Sewage Treatment Plant; WWTP; Waste Lines


457


139


283


8


9


896


Training Areas


Burn Area; Explosive Ordnance Disposal Area; Fire/Crash Training Area; Firing Range; Pistol Range; Small Arms Range; Unexploded Munitions/Ordnance Area


722


288


397


25


908


2,340


Radioactive
Area


Mixed Waste Area; Radioactive Waste Area


40


33


78


0


15


166


Surface
Discharge Area


Drainage Ditch; Industrial Discharge; Sewage Effluent Settling Ponds; Storm Drain; Surface Impoundment/Lagoon; Surface Runoff; Spill Site Area; Surface Disposal Area


1,699


1,215


2,033


69


145


5,161


Subsurface
Disposal Area


Chemical Disposal; Disposal Pit/Dry Well; Landfill; Leach Field


1,229


551


1,281


64


143


3,268


Contaminated
Media


Contaminated Fill; Contaminated Groundwater; Contaminated Sediments; Contaminated Soil Piles; Soil Contamination After Tank Removal


288


177


41


121


467


1,094


Other


1,188


0


258


28


441


1,915


TOTAL


11,411


4,070


5,423


521


3,473


24,898


Appendix 20-4: (continued)
Source: DERP FY 1994 Annual Report
1 The number of sites presented in this table includes sites with investigations or remediation
in progress and sites where investigation and/or remedial activities have been completed.
2 DOD total, including FUDs.

Appendix 20-5:

Progression of Active CMSs 1


Previous Years


FY 92


FY 93


FY 94


Active sites remaining


10,924


10,158


10,439


New sites


+1,135


+280


+869


Sites reopened


+0


+619


+862


Response completed based on investigation


-1,685


-487


-178


Response completed based on clean-up


-216


-131


-207


End of Year Total Active Sites2


10,158


10,439


11,785


Total No. of Sites (Active and Response Complete)


NR


19,694


21,425


Total No. of Installations with CMSs


NR


1,722


1,769


1 These numbers do not include FUDS.
2 The number of sites identified in this table are the number of sites undergoing site investigation, interim action, remedial design and/or clean-up. The numbers do not include the number of sites with response completed to date. As of September 30, 1994, it is reported that 9,640 sites with response complete exist. Each DOD installation can have more than one site.
NR = Not reported
Source: DERP Annual Report for Fiscal Year 1994

Appendix 20-6:

CERCLA, RCRA, and UST Investigations and Clean-Up Processes


Activity


CERCLA


RCRA Corrective Action


Underground Storage Tanks


Investigation


Preliminary Assessment (PA)
(or Initial Assessment Study (IAS))
Site Inspection (SI) (or Confirmation Study (CS)
Remedial Investigation (RI)
Feasibility Study (FS)
Engineering Evaluation/Cost Analysis (EE/CA)


RCRA Facility Assessment (RFA)
RCRA Facility Investigation (RFI)
Corrective Measures Study (CMSt)


Initial Site Characterization
Investigation for Soil and Groundwater Clean-Up
Corrective Action Plan (CAP)


Interim
Action


Removal Action
Interim Remedial Action (IRA)


Interim Measures


Initial Abatement Measures
Free Product Removal


Design


Remedial Design (RD)


Corrective Measures Design (Remedy Design)


Design


Clean-Up


Remedial Action (RA)
Operation and Maintenance (O&M)
Long-Term Monitoring


Corrective Measures Implementation (CMI)
Operation and Maintenance (O&M)
Long-Term Monitoring (LTM)


Corrective Action
Operation and Maintenance (O&M)
Long-Term Monitoring (LTM)

Appendix 20-7:

A: Current Presumptive Remedies 1


Site Type


Presumptive Remedy(ies)


References


General Policy and Procedures


NA


Presumptive Remedies: Policy and Procedures


Volatile Organic Compounds (VOCs) in Soils


Soil Vapour Extraction,
Thermal Desorption, Incineration


Presumptive Remedies: Site Characterization and Technology Selection for CERCLA Sites with VOCs in Soils


Wood Treaters


For Organic - Incineration,
Bioremediation, Dechlorination
For Inorganics - Immobilization


Presumptive Remedy: Wood Treating Sites
Technology Selection Guide for Wood Treater Sites (5/93)


Municipal Landfills


Contaminant (could include capping, leachate collection and treatment, landfill gas treatment, institutional controls, etc.)


Presumptive Remedy for CERCLA Municipal Landfill Sites


Military Landfills


TBD


Guidance for Municipal Landfill presumptive remedies applied to military landfills expected by end of 1995 to early 19962


Contaminated Groundwater


Pump and Treat (will specify preferred treatment technologies
and describe overall approach)


TBD


Region 7 Pilots - PCB Sites, Coal Gas Sites, Grain Storage


TBD


TBD


PCB = Polychlorinated Biphenyls
TBD = To be determined
NA = Not applicable
1 Source: Presumptive Remedies: Policy and Procedures, EPA, 1993.
2 Source: Moving Sites Faster Through Streamlined Oversight, Versar, 1995.

Appendix 20-7:

B: Effect of Presumptive Remedies on Clean-up Process


Appendix 20-7:
B: Effect of Presumptive Remedies on Clean-up Process



Phases of Clean-Up Process


Effect on
Clean-Up Process


SITE ASSESSMENT:



PA/SI or Removal Site Evaluation


Focused


Scoping:


· Collect and analyse existing data


Not impacted


· Identify initial project/OUs and remedial action objectives


Streamlined


· Identify range of likely alternatives


Streamlined


· Identify initial DQOs


Not impacted


· Prepare project plans


Not impacted


Remedial Investigation:


· Conduct field investigation


Focused1


· Define nature and extent of contamination


Not impacted


· Identify ARARs


Not impacted


· Conduct baseline risk assessment


Not impacted


FEASIBILITY STUDY OR EE/CA:



Remedy Selection:


· Identify potential treatment technologies and containment/disposal requirements


Eliminated


· Screen technologies


Eliminated


· Identify alternatives by assembling technologies


Eliminated


· Screen alternatives to reduce number subject to detailed analysis


Eliminated


· Further refine alternatives, as necessary


Streamlined


· Analyse alternatives against the nine criteria and each other


Streamlined


Proposed Plan


Streamlined


Record of Decision


Streamlined


Remedial Design


Streamlined

1 Streamlined for municipal landfills

Appendix 20-8 :

A: Remediation Technologies for Soils, Sediments and Sludges


Technology


Status


Contaminants Treated1



Overall
Cost2
($/metric ton)


Capital or
O&M Intensity


Time
to
Complete


Comments


Target


Secondary


In Situ Biological Processes









Biodegradation


Full-Scale/
Innovative


nonH-VOCs,
nonH-SVOCs,
FH


H-VOCs
H-SVOCs
pesticides


$110-330


O&M


>3 yrs.


May not be applicable if high concentrations of heavy metals, highly chlorinated organics or inorganic soils are present; groundwater should be near surface and contaminated.


Bioventing


Full-Scale/
Innovative


nonH-VOCs
nonH-SVOCs, FH


H-VOCs,
H-SVOCs,
pesticides


$20/
cubic meter


Neither


1-3 yrs.


Not recommended for high water table, saturated soil lenses, or impermeable soil.


In-Situ Physical/Chemical Processes









Soil Vapour Extraction (SVE)


Full-Scale/
Innovative


H-VOCs,
nonH-VOCs,
FH


-


<$110


O&M


1-3 yrs.


Inhibited by high humic content, low soil permeability and heterogeneous soil conditions.


Soil Flushing


Pilot-Scale/
Innovative


H-VOCs,
nonH-VOCs,
inorganics


H-SVOCs,
nonH-SVOCs,
FH, pesticides


I


O&M


>3 yrs.


Cannot treat low permeable soil; requires favorable hydrology.


Solidification/
Stabilization


Full-Scale/
Conventional


inorganics


H-SVOCs,
nonH-SVOCs,
pesticides


<$110


Capital


<1 yr.


Dependent on depth of contaminants; can significantly increase volume of waste.


Pneumatic
Fracturing
(enhancement)


Pilot-Scale/
Innovative


-


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides,
inorganics


$6-11


Neither


NA


Potential exists to create new pathway for spread of contaminants.


In Situ Thermal Processes









Vitrification
(in situ)


Pilot-Scale/
Innovative


inorganics


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides


>$330


Both


<1 yr.


Requires homogeneity of media. Vitrification possible to maximum depth of 9 meters.


Thermally Enhanced SVE


Full-Scale/
Innovative


H-SVOCs,
nonH-SVOCs,
pesticides


H-VOCs,
nonH-VOCs,
FH


$110-330


Both


<1 yr.


Limited to a 5 degree slope or less. Debris and large objects buried can cause problems.


Ex Situ Biological Processes (assuming excavation)









Slurry Phase Biological Treatment


Full-Scale/
Innovative


nonH-VOCs
FH


H-VOCs,
H-SVOCs,
nonH-SVOCs,
pesticides


$110-330


Both


0.5-1 yr.


Requires soil excavation.


Controlled Solid Phase Biological Treatment


Full-Scale/
Innovative


nonH-VOCs,
FH


H-VOCs,
H-SVOCs,
nonH-SVOCs,
pesticides


<$110


Neither


0.5-1 yr.


Requires large amount of space. Not very effective for halogenated compounds and explosives.


Landfarming


Full-Scale/
Conventional


nonH-VOCs,
FH


H-VOCs,
H-SVOCs,
nonH-SVOCs,
pesticides


<$110


Neither


>1 yr.


Large amount of space required.


Ex Situ Physical/Chemical Processes (assuming excavation)









Soil Washing


Full-Scale/
Innovative


H-SVOCs,
nonH-SVOCs,
FH,
inorganics


H-VOCs,
nonH-VOCs,
pesticides


$110-330


Both


<0.5 yr.


High humic content in soil and complex waste mixtures can cause problems.


Solidification/
Stabilization


Full-Scale/
Conventional


inorganics


H-SVOCs,
nonH-SVOCs,
pesticides


<$110


Capital


<0.5 yr.


Treatability studies required. Increases waste volume.


Dehalogenation
(Glycolate)


Full-Scale/
Innovative


H-SVOCs,
pesticides


H-VOCs


>$330


Both


>1 yr.


Not cost effective for large waste volumes; water content and chlorinated organics (>5%) can be inhibitive.


Dehalogenation
(BCD)


Full-Scale/
Innovative


H-SVOCs,
pesticides


H-VOCs


I


I


I


Limited use; heavy metals and certain non-halogenated volatiles will not be destroyed.


Solvent Extraction
(Chemical Extraction)


Full-Scale/
Innovative


H-SVOCs,
nonH-SVOCs,
pesticides


H-VOCs,
nonH-VOCs,
FH


>$330


Both


>1 yr.


Factors decreasing performance include presence of detergents, emulsifiers, very high molecular weight organic, very hydrophilic substances, and certain soil types/moisture content.


Chemical Reduction/
Oxidation


Full-Scale/
Innovative


inorganics


nonH-VOCs,
nonH-SVOCs,
FH,
pesticides


$110-330


Neither


<0.5 yr.


Not cost effective for high contaminant concentrations; intermediate contaminants can occur.


Soil Vapour
Extraction


Full-Scale/
Innovative


H-VOCs,
nonH-VOCs


-


<$110


Neither


1-3 yrs.


Inhibited by high humic content of soil; clean-up time highly dependent on soil and chemical properties.


Ex Situ Thermal Processes (assuming extraction)









Low-Temperature
Thermal Desorption


Full-Scale/
Innovative


H-VOCs,
nonH-VOCs,
FH


H-SVOCs,
nonH-SVOCs,
pesticides


<$110


Both


<2 mths.


Dewatering may be required.


High-Temperature
Thermal Desorption


Full-Scale/
Innovative


H-SVOCs,
nonH-SVOCs,
pesticides,


H-VOCs,
nonH-VOCs,
FH


$110-330


Both


0.5 yr.


Dewatering may be required.


Vitrification


Full-Scale/
Innovative


inorganics


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides


$770


Both


0.5-1 yr.


Organic and inorganic off-gases must be controlled; high energy required.


Incineration


Full-Scale/
Conventional


H-SVOCs,
nonH-SVOCs,
pesticides


H-VOCs,
nonH-VOCs,
FH


>$330


Both


<3 mths.


Metals in waste stream can cause problems.


Pyrolysis


Pilot-Scale/
Innovative


H-SVOCs,
nonH-SVOCs,
pesticides


H-VOCs,
nonH-VOCs,
FH


>$330


Both


<0.5 yr.


Requires low moisture content soil.


Other Process









Natural Attenuation


Conventional


nonH-VOCs,
nonH-SVOCs,
pesticides


H-VOCs,
H-SVOCs,
pesticides


<$110


Neither


>3 yrs.


Monitoring required.


Excavation and
Off-Site Disposal


Conventional


-


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides,
inorganics


$330-510


Neither


2 mths.


Distance from CMS to disposal facility effects cost. Land ban restrictions must be considered.


Source: EPA and Air Force, July 1993
1 Listing of contaminant groups is intended as a general reference only. A technology may treat only selected compounds within the contaminant groups listed.
Further investigation is necessary to determine applicability to specific contaminants.
2 Costs are provided in 1993 U.S. currency per 1,000 liters of groundwater treated unless otherwise indicated.
3 Time required to clean-up a "standard" site using the specified technology. The "standard" site is 18,200 metric tons for soils (0.41 hectare, 3.04 meters deep).
FH = fuel hydrocarbons
H = halogenated
nonH = non-halogenated
SVOCs = semi-volatile organic compounds
VOCs = volatile organic compounds
O&M = Operations & Maintenance

Appendix 20-8:

B: Groundwater Remediation Technologies


Technology


Status


Contaminants Treated1



Overall
Cost2
($/1,000
liters)


Capital or
O&M Intensity


Time
to
Complete


Comments


Target


Secondary


In Situ Biological Processes









Oxygen Enhancement with Hydrogen Peroxide


Full-Scale/
Innovative


nonH-VOCs,
nonH-SVOCs, FH


H-VOCs
H-SVOCs
pesticides


$0.79-
2.64


O&M


1-3 yrs.


Higher permeability zones cleaned up faster; high iron content at subsurface can reduce hydrogen peroxide concentration.


Co-Metabolic Processes


Pilot-Scale/
Innovative


H-VOCs, H-SVOCs


nonH-VOCs,
nonH-SVOCs,
FH, pesticides,


$0.79-
2.64


O&M


1-3 yrs.


Higher permeability zones cleaned up faster.


Nitrate Enhancement


Pilot-Scale/
Innovative


nonH-VOCs
nonH-SVOCs, FH


H-VOCs
H-SVOCs
pesticides,


<$0.79


Neither


1-3 yrs.


Higher permeability zones cleaned up faster; primarily used for BTEX concentration.


Oxygen Enhancement with
Air Sparging


Full-Scale/
Innovative


nonH-VOCs
nonH-SVOCs, FH


H-VOCs,
H-SVOCs,
pesticides


<$0.79


Neither


1-3 yrs.


Permeability differential (e.g. clay layer) can reduce effectiveness; where vertical air flow is restrictive, contaminated groundwater can be pushed away from injection point; vapours can build up in bldg. basements.


In-Situ Physical/Chemical Processes









Slurry Walls


Pilot-Scale/
Innovative


-


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides,
inorganics


<$0.79


Capital


<1 yr.


Cannot withstand strong acids, bases, salt solutions and some organic chemicals.


Passive Treatment Walls


Pilot-Scale/
Innovative


H-VOCs,
H-SVOCs,
inorganics


nonH-VOCs,
nonH-SVOCs,
FH


I


Capital


>3 yrs.


Only applicable to relatively shallow aquifers.


Hot Water or Steam Flushing/ Treatment


Pilot-Scale/
Innovative


H-SVOCs,
nonH-SVOCs, FH


H-VOCs,
nonH-VOCs


$0.79-
2.64


Capital


<1 yr.


Soil type will significantly impact process effectiveness.


Hydrofracturing
(enhancement)


Pilot-Scale/
Innovative


-


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides,
inorganics


$0.79-
2.64


Neither


<1 yr.


Potential exists to open new pathways for unwanted spread of contaminants.


Air Sparging


Full-Scale/
Innovative


H-VOCs,
nonH-VOCs, FH


-


<$0.79


Neither


<1 yr.


Used with SVE systems.


Directional Wells
(enhancement)


Full-Scale/
Innovative


-


H-VOCs,
H-SVOCs,
nonH-VOCs,
nonH-SVOCs,
FH,
pesticides,
inorganics


I


Neither


<1 yr.


Potential well collapse exists; well failures possible.


Dual Phase
Extraction


Full-Scale/
Innovative


H-VOCs,
nonH-VOCs, FH


-


$0.79-
2.64


O&M


1-3 yrs.


Complementary technology required for long-chained hydrocarbons and high yielding aquifer.


Vacuum Vapour
Extraction


Full-Scale/
Innovative


H-VOCs,
H-SVOCs, FH


nonH-VOCs,
nonH-SVOCs,
pesticides,
inorganics


$0.79-
2.64


Capital


1-3 yrs.


Shallow aquifers may limit effectiveness.


Free Production
Recovery


Pilot-Scale/
Innovative


nonH-SVOCs,
FH


-


<$0.79


Neither


<1 yr.


Site specific geology may limit effectiveness.


Ex Situ Biological Processes (assuming pumping)









Bioreactors


Full-Scale/
Innovative


nonH-VOCs,
nonH-SVOCs, FH


H-VOCs,
H-SVOCs,
pesticides


<$0.79


Capital


NA3


Solid residuals may require treatment; metals may need to be removed prior to treatment in bioreactors; low temperatures inhibit effectiveness. Cost highly dependent on contaminant types and concentrations.


Ex Situ Physical/chemical Processes (assuming pumping)






Air Stripping


Full-Scale/
Conventional


H-VOCs,
nonH-VOCs


H-SVOCs,
nonH-SVOCs
FH


<$0.79


O&M


NA4


Inorganic (especially dissolved ferrous iron) and biological fouling of equipment potentially can occur. Pre-heating required for low-volatile compounds.


Carbon Adsorption
(Liquid Phase)


Full-Scale/
Conventional


H-SVOCs,
nonH-SVOCs


H-VOCs, FH,
pesticides,
inorganics


>$2.64


O&M


NA4


Metals can foul system; high costs if used as primary treatment with high contaminant concentration levels.


UV Oxidation


Full-Scale/
Innovative


H-VOCs,
H-SVOCs,
pesticides


nonH-VOCs, FH


$0.79-
2.64


Capital


NA4


Inorganics and naturally occurring soil organics (humic substances) can cause adverse affects. Cost highly dependent on influent pretreatment requirements.


Other Processes









Natural Attenuation


Conventional


nonH-VOCs,
nonH-SVOCs, FH


H-VOCs,
H-SVOCs,
pesticides


<$0.79


Neither


>3 yrs.


Applicable only to low risk situations.


Source: EPA and Air Force, July 1993
1 Listing of contaminant groups is intended as a general reference only. A technology may treat only selected compounds within the contaminant groups listed.
Further investigation is necessary to determine applicability to specific contaminants. Technology can be used for treatment of "secondary" contaminants; however, results are typically less effective or else the technology is in the developmental stages for these contaminants.
2 Costs are provided in U.S. currency per 1,000 liters of groundwater treated.
3 Time required to clean-up a "standard" site using specific technology. The "standard" site is a normalized site of 0.41 hectare, 3.04 meters deep with an average porosity of 30% and a shallow aquifer. Site volume is 3,785,000 liters.
4 Time to complete is not applicable (NA) because these treatment technologies are either support technology and clean-up time is dependent upon primary treatment, or the clean-up time is highly dependent upon contaminant concentrations and/or types and clean-up time cannot be predicted without such site-specific knowledge.
FH = fuel hydrocarbons SVOCs = semi-volatile organic compounds
H = halogenated VOCs = volatile organic compounds
nonH = non-halogenated O&M = Operation and Maintenance

Appendix 20-8:

C: Air Emissions/Off-Gas Treatment Processes


Technology


Status


Contaminants Treated1
Target (Secondary)


Overall
Cost2


Capital or
O&M Intensity


Time to
Complete


Comments


Carbon Adsorption
(vapour phase)


Full Scale/
Conventional


H-VOCs,
H-SVOCs, nonH-VOCs, nonH-SVOCs, FH,
pesticides


Less than
$3.17/kg


Neither


NA3


High contaminant concentrations limit effectiveness


Catalytic Oxidation
(non-halogenated)


Full Scale/
Conventional


nonH-VOCs,
nonH-SVOCs, FH


Less than
$3.17/kg


Neither


NA3


Presence of sulfur or halogenated compounds can poison/deactivate catalyst


Catalytic Oxidation
(halogenated)


Full Scale/
Innovative


H-VOCs,
H-SVOCs


Less than
$3.17/kg


Neither


NA3


Catalyst can be poisoned/deactivated and require replacement; system has been evaluated primarily with contaminants TCE and, in some instances, PCE.


Biofiltration


Full Scale/
Innovative


nonH-VOCs, FH,
(H-VOCs)


Less than
$3.17/kg


Neither


NA3


Fugitive fungi may cause a problem


Thermal Oxidation


Full Scale/
Conventional


nonH-VOCs,
nonH-SVOCs, FH


Less than
$3.17/kg


Neither


NA3


Chlorinated materials in waste stream can create problem


Source: USEPA and Air Force, 1993
1 Listing of contaminant groups is intended as a general reference only. A technology may treat only selected compounds within the contaminant groups listed.
Further investigation is necessary to determine applicability to specific contaminants.
2 Costs are provided in 1993 U.S. dollars.
3 Time to complete is not applicable (NA) because these treatment technologies are support technologies used to treat off-gases produced by another remediation
technology; therefore, the site clean-up is wholly dependent upon the clean-up time associated with the primary treatment.
FH = fuel hydrocarbons
H = halogenated
nonH = non-halogenated
SVOCs = semi-volatile organic compounds
VOCs = volatile organic compounds
kg = kilogram
O&M = Operation and Maintenance

Appendix 20-9:

Financial Year 1995 and 1996 SERDP Clean-up Projects


FY 1995 SERDP Clean-Up Projects


Actual
Funding
FY 95 $ (K)


Characterization, Monitoring, Modeling, Measurements, Methods-Field


Accelerated Tri-Services SCAPS Sensor Development (A/AF/N)


1,060


The Sensitive Detection of Unexploded Ordnance and other Hazardous Materials (A)


94


Field Potable FTS Fiber Optic VOC Sensor (AF)


150


In-Situ "Inside-Out" Nuclear Magnetic Resonance Sensor for Contaminant Identification (A)


200


Integrated Characterization Program Combining DOE UFA and DoD
Sensor Technologies (DOE/N)


100


Subsurface Gas Flowmeter (DOE)


250


Removal of VOCs from Contaminated Groundwater and Soils by Pervaporation (EPA/N)


250


Subsurface Bioremidiation Process Monitoring Indicators (EPA)


200


UXO Detection Feasibility Study (A/N/AF/DOE)


100


Mobile Underwater Debris Survey System (N)


575


Rapid Detection of Explosives and Other Pollutants (N)


125


Hazard Risk Assessment, Modeling, Methodologies


Trichlorethylene Risk Assessment (AF/EPA)


0


Treatment Technologies - Groundwater/Surface Water


Biosorption Treatment of Plasticizers and Solvents (A)


681


Enhancing Bioremediation Processes in Cold Regions (A)


220


Peroxene Treatment of Contaminated Groundwaters (A)


180


Aerobic Bioremediation of a Contaminated Aquifer (AF)


600


Bioremediation of Hydrazine/Energetic Materials (AF/A)


0


Catalytic In Situ Treatment of Chlorinated Solvents (AF/EPA)


300


Joint US/Germany In-Situ Bioremediation Demonstration (AF)


200


Aquifer Restoration by Enhanced Source Removal (EPA/AF)


860


Removal and Encapsulation of Heavy Metals from Groundwater (EPA/DOE/A)


100


Encapsulated Bacteria for In Situ PAH Bioremediation (N)


0


In Situ Bioremediation of Fuel and Efficacy Monitoring (N/EPA)


850


Treatment Technologies - Soils/Sludges


Air Sparging and In-Situ Bioremediation Research (A/USGS)


271


Explosives Conjugation Products in Remediation Matrices (A)


146


Integrated Biotreatment Research Program: From Flask to Field (A)


1,101


Surfactant-Enhanced Biodegradation of Contaminants (A)


234


Fuel Hydrocarbon Remediation (N)


280


DoD National Environmental Technology Demonstration Program


Volunteer Army Ammunition Plant (VAAP) - Chattanooga, TN (A)


350


Naval Construction Battalion Center (NCBC) - Port Hueneme, CA (N)


900


Dover AFB Groundwater Remediation Field Lab - Dover, DE (AF)


1,279


McClellan AFB - Sacremento, CA (AF)


0


National Center for Integrated Bioremediation R&D Wurtsmith AFB- Oscoda, MI (EPA)


2580


Site Characterization Consortium (EPA)


350


Cleanup Total


14,586


FY 1996 SERDP Clean-Up Projects



Project Title


Service


Accelerated Tri-Services SCAPS Sensor Development


ARMY


Catalytic In-Situ Treatment of Chlorinated Solvents


USAF


Explosives Conjugation Products in Remediation Matrices


ARMY


Rapid Detection of Explosives and other Pollutants


NAVY


UXO Detection Feasibility Study


ARMY


Aquifer Restoration by Enhanced Source Removal


EPA


Mobile Underwater Debris Survey System (MUDSS)


NAVY


Integrated Biotreatment Research Program: From Flask to Field


ARMY


Air Sparging and In-Situ Bioremediation Research


ARMY


Field Portable FTS Fiber Optic VOC Sensor


USAF


Peroxone Treatment of Contaminated Groundwaters


ARMY


Aerobic Bioremediation of a Contaminated Aquifer


USAF


In-Situ Bioremediation of Fuel and Efficancy Monitoring


NAVY


Trichloroethylene Risk Assessment


USAF


Enhancing Bioremediation Processes in Cold Regions


ARMY


Subsurface Gas Flowmeter


DOE


Surfactant-Enhanced Biodegradation of Contaminants


ARMY


Biosorption Treatment of Plasticizers and Solvents


ARMY


Removal and Encapsulation of Heavy Metals from Groundwater


EPA


Subsurface Bioremediation Process Monitoring Indicators


EPA


The Engineering Design of In-Situ Bioremediation


DOE


Fuel Hydrocarbon Remediation - National Test Site


NAVY


In-Situ "INSIDE-OUT" NMR Sensor for Contaminant Identification


NAVY


Joint US/Germany In-Situ Bioremediation Demo


USAF


Encapsulated Bacteria for In-Situ PAH Bioremediation


NAVY


Removal of VOCs from Contaminated Groundwater and Soils by Pervaporation


EPA


Bioremediation of Hydrazine


USAF


Bioremediation of Energetic Materials


USAF


Integrated Characterization Program Combining DOE (PNL) UFA and DoD (NRAD)


DOE


Sensitve Detection of Unexploded Ordinance and other Hazardous Materials


ARMY


Natural Attenuation of Contaminants


ARMY


National Environmental Technology Test Sites Program


ARMY


Volunteer Army Ammunition Plant sites


ARMY


Dover Air Force Base


USAF


McClellan Air Force Base


USAF


Port Hueneme Naval Construction Battalion Center


NAVY


Wurtsmith Air Force Base


EPA


NERL/LV


EPA

Acronyms :


A Army
AF Air Force
DoD Department of Defence
DOE Department of Energy
EPA Environment Protection Agency
FTS Fourier Transform Spectrometer
FY Financial Year
MUDSS Mobile Underwater Debris Survey System
N Navy
NMR Nuclear Magnetic Resonance
PAH Polyaromatic Hydrocarbons
PNL Pacific Northwest Laboratory
SCAPS Site Characterisation and Analysis Penetrometer System
USGS United States Geological Survey
UXO Unexploded Ordnances
VOC Volatile Organic Carbons


, , Title , Contents