, , Title , Contents

2. Australia


Acronyms


ACT Australian Capital Territory
ADI Acceptable Daily Intake
ADI(L) Australian Defence Industries Ltd
ANAO Australian National Audit Office
ANSTO Australian Nuclear Science and Technology Organisation
ANZEC Australia & New Zealand Environment Council
ANZECC Australia & New Zealand Environment and Conservation Council
ARL Australian Radiation Laboratories
AUD Australian Dollar
BTEX Benzene, Toluene, Ethyl Benzene, Xylene
CCS Contaminated Civil Site
CMS Contaminated Military Site
CSIRO Commonwealth Scientific and Industrial Research Organisation
DEH Department of Environment & Heritage - Queensland
DELM Department of Environment and Land Management - Tasmania
DNT Dinitro toluene
DoD Department of Defence of Commonwealth of Australia
DSTO Defence Science and Technology Organisation
EPA(C) Environment Protection Agency (Commonwealth of Australia)
EPA(NSW) Environment Protection Authority (New South Wales)
EPA(SA) Environment Protection Authority (South Australia)
EPA(V) Environment Protection Authority (Victoria)
FASFP First Assistant Secretary of Facilities and Property Division (DoD)
ha hectare(s)
HASP Health & Safety Plan
HEAST Health Effects Assessment Summary
HMAS Her Majesty's Australian Ship
HMX Octahydro-1,3,5,7-tetra nitro-1,3,5,7-tetrazocine
HPLC High Pressure Liquid Chromatography
ICRP International Commission on Radiological Protection
IGAE Intergovernmental Agreement on the Environment
IRIS Integrated Risk Information System
ISV In-Situ Vitrification
MAH Monocyclic Aromatic Hydrocarbons
m AUD million Australian Dollar
MNT Mononitro toluene
NB Nitrobenzene
NEPC National Environment Protection Council
NEPM National Environment Protection Measure
NH&MRC National Health & Medical Research Council
NPI National Pollution Inventory
NSW New South Wales
NT Northern Territory
PAH Polycyclic Aromatic Hydrocarbons
PCB Polycyclic Biphenyls
PGDN Propyl Glycol Dinitrate
PTWI Provisional Tolerable Weekly Intake
PWC Parliamentary Standing Committee on Public Works
QLD Queensland
RDX Cyclo trimethylene trinitramine
RAAF Royal Australian Air Force
RAN Royal Australian Navy
SA South Australia
SCS Suspected Contaminated Site
SEPP State Environment Protection Policy (Victoria)
TAS Tasmania
TCE Trichloroethene
TNT Trinitrotoluene
TPH Total Petroleum Hydrocarbons
USA United States of America
USATHAMA United States Army Toxic and Hazardous Materials Agency
USEPA United States Environmental Protection Agency
UXO Unexploded Ordnance
VIC Victoria
WA Western Australia
WHO World Health Organisation

2.-1.0 Introduction


This part of the study with regard to international expertise on Contaminated Military Sites (CMS) refers to the Commonwealth of Australia. The Commonwealth of Australia is an independent country organised in a Federal System comprising six States: New South Wales (NSW); Victoria (VIC); Queensland (QLD); Western Australia (WA); South Australia (SA); Tasmania (TAS);two mainland Territories: the Australian Capital Territory (ACT) and the Northern Territory (NT) and a number of island territories.
Australia covers an area of about 7.8 million square kilometres, only slightly smaller in extent than the USA, but with a small population of about 18 million people mostly located in coastal cities on the eastern and southern seaboards. The central northern and western parts of Australia have a hot and mostly dry climate with a summer monsoonal season in the north, and are very sparsely populated. They have therefore historically been used for large scale military training and exercises during the world wars, and up to the present. Training areas can be extremely large occupying in some cases in excess of 5,000 square kilometres and ranging within a variety of climates, landforms, water bodies and ecosystems. One training area currently being acquired by the Commonwealth, will effectively double the area of land currently owned by the Commonwealth Government for defence purposes.
Australian infrastructure suffered little from hostile activity during the war periods, with only small scale activity. However, during the bombing and shelling of Darwin, to put it in perspective, the total weight of bombs dropped on Darwin has been estimated as about double that delivered in the attack on Pearl Harbour. Also, extensive training activities have taken place on land both owned by the Commonwealth Government and leased under wartime emergency legislation and on private property. This has left a large reservoir of former military sites mostly located in rural areas. The country has historically approximately 1,200 sites that can be classified as Military Sites. Currently the Commonwealth uses approximately 550 sites of which approximately 526 are owned by the Commonwealth. The rest are leased.
The management of operational military facilities is the responsibility of the respective base commanders within the jurisdiction of the Directors General of the three armed services that occupy the various properties (of which approximately 80% fall under the jurisdiction of the Australian Army). Acquisition or disposal of military properties is the responsibility of the Facilities and Property Division of the Department of Defence (DoD) of the Government of the Commonwealth of Australia. A number of military sites are, or were, jointly operated by Australia and its former WWII allies, Britain and the USA, and therefore also are partly or wholly managed by those countries. These include, for example, the Joint Defence Space Communications Station at Nurrungar SA, and the Space Research Facility at Pine Gap NT, jointly operated with the USA, and the former Woomera Rocket Range and the Maralinga Nuclear test site formerly operated by Britain.

2.-2.0 Definitions


The 1992 Australian & New Zealand Environment and Conservation Council/National Health and Medical Research Council (ANZECC/NH&MRC) "Guidelines for the Assessment and Management of Contaminated Sites" define a contaminated site as "a site at which hazardous substances occur at concentrations above background levels and where assessment indicates it poses, or is likely to pose an immediate or long term hazard to human health or the environment". Background levels in these guidelines refer to "ambient levels of a contaminant in the local area of the site under consideration". There is no legal definition of a Contaminated Military Site either in existing or planned national legislation, in State legislation, or as defined by the DoD.
A suspected contaminated site (SCS) is an area that, due to the nature of historical operations and/or disposal practices, is considered to have a potential to be contaminated. All military sites are considered to have SCS unless proven otherwise.
Although there is no legal definition of a Contaminated Military Site, it is perceived that Contaminated Military Sites (CMS) usually display the same main features exhibited by equivalent Contaminated Civil Sites (CCS). Typically, a military site is a "Broad Acre" site covering large tracts of land in both urban and rural settings with military activities of various types at generally isolated locations spread over very large areas resulting in typically small focussed areas of contamination due to specific operations including some industrial type operations.
The principal difference that defines a CMS as compared to a CCS, apart from their legal status with regard to environmental laws and regulations discussed further in Section 2.-3.0 below, is the potential for the presence in storage, manufacture, use, testing, or disposal of armaments and in particular, explosives, explosive residues, and unexploded ordnance (UXO).
Although many military sites may not have been employed specifically for the storage or use of explosives or armaments, the prevalence of practices involving the handling of arms and ammunition cannot be discounted, in particular disposal practices in the immediate post World War II period were such that burial of surplus or scrap materials was common and records are often incomplete. Burial practices were common right up to the 1980s due to the large areas of available land associated with military bases and a general lack of local responsibility for environmental issues.
Although many military sites are relatively benign in operation as they include mainly housing, educational or storage activities, environmental personnel of the DoD and the Armed Services treat all military sites as SCS as the known history of any site is rarely sufficiently complete to eliminate the possibility of contamination due either to military activities, or in many cases, to previous industrial activities before a site was acquired. This is illustrated by the fact that over 1,000 sites are currently listed by the DoD as potentially contaminated with UXO.
Although not intended as a register of contaminated sites, in June 1990, the Australian and New Zealand Environment Council (ANZEC), the forerunner of ANZECC, produced an inventory of Commonwealth activities potentially leading to pollution and attachments to that document specifically referred to the DoD, Army and Air Force.
The DoD has also just started to compile a register of sites where environmental assessment surveys have been completed. SCS on military sites in Australia can fall into any of the categories or activities listed in Table 2-1.

Table 2-1:
Suspected Contaminated Military Sites






Service Establishments


Armaments
Industry


Explosives &
Munitions


Ranges &
Testing


Services &
Activities


Barracks
Camps
Depots/Storage areas
Training areas/bases
Fortifications
Housing
Airfields
Airbases
Communications
Radar installations
Shipyards
Dockyards
Naval shore bases


Manufacture of:
Guns
Aircraft
Ships
Vehicles
Small arms


Manufacture
Storage
Testing & research
Disposal


Rifle
Gunnery/Land
Gunnery/Sea
bombing
Rocket
Nuclear


Manufacture
& Fabrication
Maintenance/repair Metal Plating
Heating
Fuel Supply/storage
Fire Training
Electrical Equipment
Photography
Waste Disposal:
Sewerage
Solid Waste/Landfill
Incineration


In addition to the above SCS or potentially contaminating activities, Australia has in the last 50 years (following the end of World War II) operated a number of overseas military bases linked to United Nations mandates, peace keeping activities, military actions, or defence co-operation with neighbouring countries including in:
- Korea
- Cambodia
- Somalia
- Vietnam
- Papua New Guinea (Manus Island - Naval)
- Malaysia (Butterworth)
- Zimbabwe
It is Defence Policy to meet, as a minimum, the environmental management require-ments of the host state.

2.-3.0 Legislative Framework, Administrative System, Responsibilities


National Legislative Framework and Environmental Agencies
In Australia, until recently, environmental legislation has remained within the province of the various States and Territories that make up the Commonwealth of Australia and there has been little centralised control exerted by the Commonwealth Government in this area except in relation to matters of wider national interest such as legislation to control dumping at sea, to control the movement - including import and export - of hazardous wastes or banned substances and to preserve national heritage. With regard to Commonwealth owned sites, the federal system is such that Commonwealth land is not covered by the legislation of the individual States or Territories, even though the land lies within the borders of those States or Territories.
Potential environmental impacts from CMS sites have been, or will be, considered by the Commonwealth under the Environment Protection (Impact of Proposals) Act of 1974, for example, the nuclear test site in Maralinga, South Australia, the Albion Explosives Factory in Victoria, the Newington depot in New South Wales, and others.
In July 1991, the Commonwealth Government announced the establishment of the Commonwealth Environment Protection Agency (EPA(C)) to facilitate a coordinated national approach to environment protection and particularly in areas seen to be the Commonwealth Government's area of responsibility.
Primary objectives set for the EPA(C) were the integration of environmental considerations into Commonwealth policy-making frameworks and the overseeing, in partnership with the States and Territories, of the establishment of a National environmental body for the implementation of national approaches to environment protection. Under this framework, the individual State and Territory agencies remain the primary enforcement bodies.
The "Intergovernmental Agreement on the Environment (IGAE)" was signed on 1 May 1992 by the then Heads of Government of the Commonwealth, States and Territories to facilitate a cooperative national approach to the environment.
An outcome of the new cooperative approach was the recent (September 1995) establishment of the National Environment Protection Council (NEPC) by Federal Act of Parliament and mirror legislation in each State and Territory. The NEPC is a Council of Ministers nominated by each of the States, Territories and the Commonwealth, and is authorised to draw up National Environment Protection Measures (NEPMs) which may be a combination of standards, goals and guidelines and protocols, which through complementary implementing legislation will be given effect within all areas of the Commonwealth, States or Territories. NEPMs can cover topics including: ambient air quality; ambient water quality; contaminated sites; hazardous wastes; etc.
National Guidelines relating to the assessment and management of contaminated sites have been prepared. In March 1990 in the draft "National Guidelines for the Management of Contaminated Sites", subsequently finalised in January 1992 as the "Australia and New Zealand Guidelines for the Assessment and Management of Contaminated Sites" which are now generally accepted by environmental authorities and by environmental practitioners countrywide as a suitable approach to the management of contaminated sites. They have also long been accepted as the best approach to management of contaminated sites by Commonwealth Agencies and by the DoD.
The aim of the ANZECC/NH&MRC Guidelines was stated as "to provide a systematic framework for the prevention, assessment, clean-up and management of existing and future contaminated sites". The Guidelines are the main guide for the management of all SCS, whether civil or military, and have been adopted at all levels in DoD and the armed services as the framework for the management of CMS, together with Dutch and USEPA guidelines where relevant.
These guidelines are currently being revised by the Australian and New Zealand Environment & Conservation Council (ANZECC), and the National Health and Medical Research Council (NH&MRC).
ANZECC, NH&MRC and NEPC are to promote a consistent common approach throughout Australia to the question of contaminated sites management. The respective roles of ANZECC, NH&MRC and NEPC on this issue have not yet been determined, but it is likely that NEPC may assume responsibility for much of this work. The objective of ANZECC is defined as "to provide a forum for consultation and co-ordination between State, Territory and Commonwealth Governments of Australia and the Government of New Zealand on environmental and conservation matters" whilst that of the NH&MRC is "to advise the Australian community on the achievement and maintenance of the highest practicable standards of individual and public health to foster research in the interests of improving those standards".
Guidelines have been prepared by DoD for the management of such sites and these refer to the activities performed and the chemicals used or produced on a site by site basis.
State & Territory Legislation
Although Commonwealth property including Defence land is not covered by the individual States' legislation, the requirements of State based environmental laws require compliance when disposing of Commonwealth property, including CMSs. As indicated above, the variability in approach and legislation from State to State has resulted in the formulation of a variety of applicable laws, regulations and guidelines covering all aspects of assessment, management and clean-up of contaminated sites.
The initial approaches by the various State based environmental authorities has in the past been relatively conservative tending to be prescriptive and following the lead established by others, such as the approaches taken in the Netherlands including the general acceptance and adoption of the Dutch "AB & C" criteria for both soil and ground water quality criteria as target investigation and clean-up criteria. There are large differences in climate, soil, vegetation, animal species and human health considerations between typical Australian ecosystems and lifestyles and Western European type ecosystems and lifestyles, including a heavy reliance in the Netherlands on groundwater as a source of potable water, the protection of which formed a large incentive for the establishment of the Dutch criteria. This has lead to the questioning of the relevance of this approach for Australia in the late 1980s and early 1990s and to a search for a more relevant Australian approach including the lead provided by South Australian Health Commission in their publication in 1991 of a "Protocol for the Health Risk Assessment and Management of Contaminated Sites". This was a forerunner of the ANZECC Guidelines and established the risk based approach now adopted nationally.
Nevertheless, Dutch guidelines are not obsolete just yet, as they are still used in some circumstances as a yard stick for clean-up (particularly for groundwater) and may be for a long time given the national approach has only just started and is unlikely to completely replace former state policies for a long time. They are also still relevant to the clean-up of CMS, as for divestment, the CMS must comply with each State's legislation.
With the 1970 Environment Protection Act, Victoria laid the groundwork for the establishment of an approach, now beginning to be adopted by some of the other States (NSW, SA) in the management of contaminated sites. The ANZECC guidelines for management of contaminated sites have been adopted by the EPA in Victoria as part of this approach. However, the key to the approach in Victoria is the integration of planning requirements related to future beneficial uses of the land with appropriate management of that contamination.
The Victorian Minister for the Department of Planning and Housing first issued a directive to local planning authorities in 1989 under the Planning & Environment Act of 1987 which was updated in 1992. It directed that, where SCS is to be re-zoned from industrial mining or other activities (including the storage of chemicals, fuels or wastes) to "sensitive" uses (including residential, public open space, agriculture, child care, pre-school or primary school), an Environmental Auditor appointed under the Environment Protection Act 1970 must complete a Statutory Audit to determine the suitability of the land for the proposed beneficial uses. Re-use of a site for commercial or other industrial uses, or where no re-zoning is required, does not necessarily require a Statutory Environmental Audit. This would be at the discretion of the local planning authority. The Victorian Environmental Audit process is illustrated in Figure 2-1 in Appendix 2-3.
The above approach has been adopted by the DoD and applies to military sites to be closed/re-used in Victoria, NSW and SA as they have to comply with the local State legislation before disposal. Where the CMS remains the property of the Commonwealth Government, it is DoD's policy to comply with relevant State legislation even though there is no legal requirement to do so on Commonwealth owned property.
There is no requirement for the Statutory Audit in Victoria to take into account the presence of contaminated groundwater if there is no potential for an impact on the environmental quality of the land by the contaminated groundwater. In assessing the potential off-site effects of contaminated surface or groundwater, ANZECC has established water quality guidelines for potable water, for marine and fresh water ecosystems, and for agricultural and industrial use. Victoria also employs State Environment Protection Policies (SEPPs) to protect various segments of the environment including surface water bodies and (in development) for groundwater.
The EPA of Victoria (EPA(V)) therefore has a pragmatic approach to the management of contaminated sites and is prepared to accept the presence of some levels of contamination on a site providing that it does not conflict with the proposed land use. The EPA(V) generally accepts the ANZECC investigation levels or "Dutch B" levels averaged across the site as being suitable for residential purposes or other "sensitive uses" without further concern. They also can accept much higher levels of contamination present on a site provided that the environmental audit indicates that they either: do not conflict with the proposed "beneficial use" of the site; or the environmental or health risks from the presence of the contamination can be demonstrated by a site specific environmental or health risk assessment to be at acceptable levels.
The Victorian EPA established guidelines for EPA accredited Environmental Auditors (Contaminated Land) in May 1992, and is currently updating these guidelines (October 1995). The guidelines emphasise a site specific approach that depends more on end use of the property than rigid levels set by any criteria. Levels that might be set by an auditor for "sensitive uses" defined as "residential, child care, kindergarten, schools, etc" would be set at lower levels than those that could be considered acceptable for industrial or commercial purposes for example.
It must also be noted that, where risk assessments are completed for a site, the methodology for performance of ecological and health risk assessments contained in the ANZECC guidelines makes reference to World Health Organisation Provisional Tolerable Weekly Intakes (PTWI) and Acceptable Daily Intakes (ADI), rather than USEPA based methodologies which involve the use of reference doses and slope factors which are inherently more conservative. The resultant site specific criteria calculated for contaminant concentrations using the ANZECC methodology therefore tend to generate soil contamination acceptance criteria that are substantially greater than if they would be generated by the application of the equivalent USEPA methodology. This is discussed further in Section 2.- 7.3.
The Victorian system, which rarely requires the complete or extensive clean-up of a site to background levels, and in many cases can allow levels well above threshold investigation levels, has been highly successful as it has allowed the development of many sites throughout Victoria, which would otherwise not be developed because of the presence of some levels of contamination, without resorting to expensive clean-up programmes. This approach has now been adopted by New South Wales, ACT and South Australia with regulatory bodies in NSW and SA indicating that Victorian appointed auditors be considered appropriate people for quality review and sign-off of contaminated sites in these States. The Victorian EPA has been commissioned to identify and provide accreditation for appropriately qualified people in NSW and SA as Victorian Environmental Auditors, although "Statutory Audits" cannot yet be completed as there is no corresponding legislation in either State.
As well as Victoria, NSW, and South Australia, the other states in the Commonwealth, including Tasmania, Western Australia and Queensland, as well as the Northern Territory and ACT, have also developed their own strategies for the management of contaminated sites and most of the States and Territories have well developed legislation and guidelines that also provide effective approaches to contaminated land issues.
The Victorian system is equally relevant to CMS and CCS, and has resulted in significant changes in the approach to management of CMSs by DoD. However, it is not the only approach to management of contaminated sites that is being used successfully in Australia. The Queensland DEH takes a rather different approach which requires all SCS (as based on site history) to be assessed prior to development with all assessment reports submitted to DEH for sign-off and does not employ an auditor based system. Queensland is a member of the NEPC and the future adoption of National Environmental Protection Measures by the NEPC, may ultimately introduce a national Australian approach to contaminated land management involving an environmental audit process which would then be adopted by all the States and Territories.
Administrative Framework and Responsibility for CMSs
The Commonwealth of Australia owns or leases most CMSs, although from the historical practice of use of large areas of private land in QLD and NT for military training, many SCS are also in private ownership. The Department of Defence (DoD) of the Government of the Commonwealth of Australia has responsibility for the management of military lands through the Facilities and Property Division. The greater majority of sites for which contamination assessments or clean-ups are undertaken are identified through the Commonwealth Disposal of Assets Lists. All sites are purchased for a specific purpose with a definite "use-by" stage, and once this stage is reached Defence's need to retain the property ends.
Acquisition or disposal of military properties owned or leased by the Commonwealth Government is primarily the responsibility of the First Assistant Secretary of Facilities and Property Division (FASFP) of DoD. The structure of the Facilities and Property Division is illustrated in Figure 2-2 in Appendix 2-3.
The management of CMS intended for disposal has historically been largely the responsibility of the Director of the Environment and Heritage Section of the Facilities and Property Division. However, re-organisation of environmental management within the DoD has delegated the management of many contaminated sites to the Estate Management Branch and other areas within the Facilities & Property Division more appropriate for estate management, whilst the future role for the Environment and Heritage Section is planned to be mainly in the formulation of policy, protocols and guidelines.
CMSs are currently allocated into three general classifications as Major sites, Medium Sites and Minor or Small Sites. The classification is partly based on projected costs, but is also based on the degree of complexity of the issues involved which may include the legal framework, litigation, future planning requirements, political or public interest or other aspects of estate management as well as the contamination issues.
Major projects have been allocated to the Directorate of Facilities Projects that are located under the Director General Facilities - Air Force and are funded under provisions for major capital facilities projects. At present major decontamination projects managed in this way include the decontamination of the Albion Explosives Manufacturing Facility in Victoria and the disposal of the Cockatoo Island Naval Facility in NSW where there are major legal issues. Because of these issues, no further details can be presented on Cockatoo Island.
Medium projects are managed partly by the Environment and Heritage Section including sites such as the Defence Science and Technology Organisation (DSTO) facility at Salisbury in SA, RAAF Williams Airbase in VIC, Kingswood Depot in NSW. The bulk of medium sites are now managed by the Major Property Disposals Section of the Estate Management Branch who have responsibility for disposal of a number of sites including Maribyrnong explosives and chemical factory in VIC, Villawood Depot, Holsworthy Gunnery Range NSW, Toowoomba Depot QLD, Newington Armaments Depot NSW.
Newington, located on part of the site for the year 2000 Olympics in Sydney, is relatively straight forward in management terms and classified as a "medium" project although likely to cost in excess of $50 million AUD for clean-up and environmental management, which is greater than projected costs for Albion, for example, which is classified as a major project due to the complexity of issues. The remediation of Newington is to be undertaken by the NSW government as part of the agreement for the sale. Small or Minor projects would be relatively simple or low budget sites and generally comprise the smaller properties such as Army reserve depots, rifle ranges & butts, blacksmith shops, horse training establishment, storage depots, workshops. The small projects are handled by the Defence Property Services Section of the Estate Management Branch which is sub-divided into Army/Navy Programmes and Other Programmes (including Air Force properties).
Occasionally and recently more frequently, CMSs are identified which are not on the Disposal of Assets List. These sites are identified as a result of increased environmental awareness within the armed services. The management of operational military facilities falls under the responsibility of the Directors General of the three armed services and the respective base commanders, who also have responsibility for CMSs in the operational facilities under their command.
All three services have therefore established a framework for environmental management of which the Army's is the most highly developed due to the nature of their operations over large areas and frequent establishment of temporary facilities during training or other activities. In contrast, the Air Force occupies mostly a small number of long term fixed bases for the operation of aircrafts requiring a more modest environmental management infrastructure, whilst the Naval infrastructure is relatively small scale as their primary concern has historically been ship board operations. In all three cases, the responsibility for management of environmental issues rests with the local base commander who is supported by logistics and facilities staff that may include environmentally trained personnel.

2.-4.0 Financing


Assessments, investigations and clean-ups of CCS are financed by site owners or the polluters. Abandoned sites, or sites where there is pressing social need to carry out clean-up work to protect the public, may be funded out of State funds on an individual basis. For CMS, the regional centres for DoD submit budgets for funding requirements on a site by site basis to DoD based on an assessment of the problem and a cost/benefit analysis. DoD fixes the priorities and includes those projects in subsequent budgets.
All projects costing over $6 million AUD must be referred to the Parliamentary Standing Committee on Public Works (PWC) before contracts are let. This is a statutory requirement, and therefore also forms the cut-off point between medium and major projects.
The management of funds with regard to decontamination activities has always been on a site-by-site basis. The recent re-organisation of the Facilities & Property Division of DoD has been carried out with the objective of achieving the best return for the funds invested in each property (e.g. minimizing clean-up costs, maximizing sale price). The organisation of the Facilities & Property Division is detailed in Figure 2-2 in Appendix 2-3.
Whereas previously the DoD spent a lot of effort on chasing contamination on sites to achieve a clean site, much more effort is now invested in achieving beneficial land uses appropriate to the location of the property and to the contamination issues with the use of risk analysis in the forefront of the planning of decontamination goals. This has allowed the current approach to the Newington Site (estimated cost $58 million AUD) whereas initial estimates for clean-up were in excess of $120m AUD.
By careful assessment of the planning options in relation to the use of part of the site for the 2000 Olympics, it has been possible to present a range of options such as containment and monitoring of known areas of contamination that are compatible with the likelihood of future exposure of the general public to the site.
The current approach to maximising return from funding, as implemented on the decontamination of DSTO Salisbury Explosives facility, is by a partnering agreement with a private consultancy. Once the assessment of the site had indicated an appropriate remediation strategy, a "Benchmark" price was established for the remedial works with an indicative time frame. The "benchmark" fee incorporated a fixed lump sum component for administration and design for the contract by the consultant, together with a fee for remediation costs based on the estimated volumes and rates. The incentive for the project manager is that he receives 30% of any savings on the benchmark figure with an upper limit to avoid excessive over-estimation to achieve theoretical savings. As a disincentive to exceed the benchmark figure, the fixed management fee is reduced by 2% for every 100,000 AUD that it exceeds the benchmark up to a maximum of 20% over the benchmark. Any greater overrun is borne by DoD.
The management of Commonwealth contaminated sites and the funds allocated by the Commonwealth is currently under review by the Australian National Audit Office (ANAO) who have circulated draft criteria for the audit. The results of the audit and any recommendations or changes in approach with regard to funding arrangements for CMS will be available in about July 1996.
Over and above the general funding of the Facilities and Property Division activities from the Commonwealth government defence budget, (which currently appears to be the major source of finance for decontamination activities related to CMS) part of the revenue from the sale of a particular site (eg Newington) may be foregone in return for a reduced involvement in the decontamination activity, i.e. the sale price may be lower, but the Commonwealth is released from any costs or liabilities for clean-up.
Other sources of funds include a sharing of expenses where a site was operated jointly with another country. Clean-up of some joint Australian/USA facilities are being negotiated and may be conducted on a 50/50 basis. The decontamination of the former British nuclear testing sites at Maralinga is being managed by the Department of Primary Industries rather than DoD with about 40% of the estimated cost for decontamination being covered by an ex-gratia payment by Britain.
An indirect source of funding for work on assessment and decontamination of contaminated sites was that provided to Australian Defence Industries (ADI(L)). ADI(L) was a semi-government organisation set up for the manufacture of arms and explosives which was corporatised then privatised in 1995. Until 1995, it was partly supported and granted immunity by the Commonwealth Government. As ADI(L) had responsibility for some of the most heavily contaminated explosives factory sites (Albion, Maribyrnong, St Marys etc), it set up its own decontamination division which conducted research into methods for assessment and decontamination of explosives contaminated sites and established and conducted field trials with innovative equipment such as thermal desorption technology.

2.-5.0 Profile of Contamination


There are no statistics available on just how many sites exhibit certain types of contamination or the extent of that contamination and its relationship with the activities that took place on that site. Each CMS has been dealt with on an individual basis. In this Section, a number of the larger CMS that have been identified are discussed in relation to the types of activities, chemicals used and the extent of contamination discovered.
Major Military Bases & Training Areas
Typical military operations include the housing, movement and training of large numbers of people and the movement and operation of their equipment. A typical military base therefore includes the operational areas, storage areas for equipment, housing and catering areas for staff, and large areas of relatively unused space where training activities, weapons testing, and temporary storage of equipment or temporary encampments for personnel may be located.
Air Force bases, some Naval shore bases and long term Army camps or barracks therefore take on the character of small towns with all the ancillary services including shops, service stations, canteens, recreational facilities, waste disposal areas and water, power and sewerage reticulation including sewage treatment plants. Added to that, they have maintenance facilities, stockpiles of fuel and ammunition, and on the large sites, fire training areas, rifle ranges, gunnery and bombing ranges, as well as any specialist activities associated with their particular service requirements.
Training areas are a particular problem as they occupy vast areas and are often on private property where the defence approach is to get permission to use the property and compensate for any damage.
As most military sites in Australia are both secure and tend to be large with extensive open areas that can be readily used for establishment of small specialist operations or for waste disposal they have often been targeted in the past for the establishment of specialised industries related to manufacture and testing of armaments and in some cases explosives.
Gunnery ranges such as Holsworthy in NSW, have been used for the disposal of UXO and burial of surplus equipment. Point Cook airfield was used for military training and fire training activities involved the deliberate release of flammable chemical wastes of unknown sources into pits to produce smoky fires for training of base fire fighting crews. PCBs drained from electrical equipment were stored in a compound on Laverton airfield, part of RAAF Williams Airbase. Surplus machine guns stripped from equipment were buried in concrete in a military depot in Toowoomba QLD and had to be located during clean-up of the site.
The common factors on military sites appear to be the presence of petroleum based fuels for vehicles, aircraft, vessels and for heating. Gunnery and bombing ranges can be very large with small fragments of UXO dispersed over wide areas. Metallic lead in rifle range butts is also a common feature. The extent of contaminated areas on such sites however tends to be relatively small and focused.
Wastes comprising mostly domestic wastes from living areas have commonly been dumped within the boundaries of military sites in the past, although this practice is changing with all the armed services making use of local domestic garbage removal and industrial waste removal services wherever available. However, for the older sites, which represent most of those likely to be decontaminated as part of a disposal programme, the presence of numerous solid waste tips is a common factor.
Most major disposal operations for military bases (such as RAAF Williams) have not progressed much further than the initial characterisation of contamination as most of the early work completed by DoD was on the former explosives manufacturing facilities (Albion, Maribyrnong, St Marys etc). The likely range of contaminants is known to include:
C petroleum hydrocarbons related to all fuel storage, transport, re-fuelling, and usage activities, such as for heating, power generation, workshops, maintenance etc;
C - metals; in particular, copper, lead & zinc, mostly from building materials, electrical equipment, paints and ammunition; but also mercury from electrical switchgear, arsenic and chrome from pesticides, wood preservatives, plating etc, and a range of other metals related to specific uses such as nickel, cadmium, silver etc;
- UXO and explosives residues from ranges and from ammunition storage and disposal;
- PAHs from boiler houses, bunker fuels, bitumen, ash wastes;
- chlorinated hydrocarbons used as degreasing agents in workshops and plating shops;
- solvents (petroleum and aromatic hydrocarbons, phenols etc) in paints and cleaning materials;
- PCBs previously present in electrical equipment;
- organochlorine pesticides from pest control practices;
- asbestos in building materials, lagging, insulation and fire retardants.
Training areas tend to have few contaminants except those associated with domestic landfills, and the use of fuels, explosives and the presence of UXO. However, they can also have particular problem materials such as arsenic impregnated ammunition boxes and phosphorous grenades.
The potential for the presence of UXO is a problem during assessment and decontamination of all CMS as it is impossible to completely screen a site for all possible UXO or fragments of munitions. The DoD approach to UXO contamination is discussed in detail below.
Armaments Factories and Fabrication on Military Sites
As part of the industrial expansion of Australia, particularly during and immediately after WWII, armaments manufacturing facilities were set up both as independent facilities such as aircraft manufacturing, or as small fabrication or maintenance areas within existing military bases such as at Laverton Airfield, part of RAAF Williams, in order to cope with the demand for military equipment to the western allies.
Activities on these sites included: metal fabrication, machining, treatment and finishing including metal pickling (with acids), hardening (cyanide) and plating (metals); component manufacture; painting and assembly of completed armaments; storage, handling and disposal of raw materials and wastes; and other associated industrial operations or processes aimed at manufacture and testing of armaments and weapons including boiler houses, waste water treatment, bulk fuel storage, etc.
The profile of contamination in these areas is generally typical of that which may be associated with similar civilian industrial operations and may include a full range of metals and other inorganics, petroleum hydrocarbons, aromatic hydrocarbons, chlorinated hydrocarbons and semi-volatile organic compounds, PCBs, asbestos etc.
Contamination above investigation thresholds has been detected at several of the factory sites in both soil and groundwater. It is extensive in some areas and groundwater quality across these sites is often poor with a range of contaminants exceeding national water quality guidelines.
Commonly occurring contaminants include:
- petroleum hydrocarbons (C6-C36) from fuels and cutting oils;
- various volatile and semi-volatile chlorinated hydrocarbons & phenols used as cleaning agents and degreasing agents;
- metals including: copper, chromium and cadmium from plating lines
Less common contaminants include:
- benzene
- phthalate
- metals including: arsenic, cobalt, lead, nickel, zinc, manganese, molybdenum, selenium,
- polycyclic aromatic hydrocarbons
- cyanide
- PCBs
It is possible that some of the contamination may come from off-site sources or have been imported with fill materials.
Asbestos is also frequently present on such sites. It is often been incorporated into building materials in the form of asbestos cement sheeting, and is used as lagging in boilers and furnaces and as a fire retardant.
Explosives Manufacturing Sites
Most of the experience obtained with CMS in Australia relates to the major explosives manufacturing facilities established either before or during WWII. They are important with regard to the DoD's approach to management of CMS as most of the experience and expertise within the Facilities & Property Division was gained on these sites.
The Albion site in Victoria was the first to be investigated in the late 1980s, and many of the techniques for assessment of contamination associated with explosive residues were developed on that site. The compounds or contaminants detected on the Albion site were described as follows:
- Explosives Residues: "Red water", "Yellow Water", nitroglycerine, RDX, 2,4-DNT, 2,4,6-TNT, MNT, carbamite;
- Organic compounds: petroleum hydrocarbons, toluene, organic carbon, cyclohexanone, dimethyl aniline;
- Metals: mercury, titanium, lead, barium, calcium, magnesium, potassium, sodium,
- Anions: bicarbonate, carbonate, chloride, sulphate
- Other: asbestos
Albion, like other explosives industry sites occupies a large area comprising mainly buffer zones with very little potential for contamination. The contamination is generally confined to the relatively small proportion of the site where manufacturing took place and to settlement ponds.
Of the wide range of contaminants listed above, TNT, 2,4-DNT, 2,6-DNT, RDX, lead, barium and mercury were found to be the most significant and wide spread. The approximately 500 hectares (ha) are split into two main areas of roughly equal size. Area 1 comprising mainly buffer zones and storage areas is mildly contaminated with a few small discrete areas of higher contamination. Volumes of soil for remediation have been based on grid sampling with an assumption of a contaminated area extending a radius of 7.5 metres around any sampling point, to arrive at an estimate of 100,000 m; of contaminated soil, or about 400 m; per ha. Area 2 represents mainly the manufacturing areas. Approximately 200,000 m; of moderately contaminated soil requiring remediation has been identified at a few scattered sites representing less than 3% of the total area of Area 2.
The St Mary's munitions facility in NSW covers about 1,500 ha, three times the size of Albion. Activities included manufacture of explosives and extensive destruction of surplus explosives after WWII. Approximately 85% of the explosives contamination is concentrated in sediments within former evaporation ponds constructed to receive large volumes of wash waters from the explosive destruction process. Levels of RDX and TNT residues in the ponds ranged from below action levels to 140,000 mg/kg.
The Draft Australian Standard for the Sampling of Potentially Contaminated Soils also lists the following chemicals associated with the manufacture of explosives:
Acetone, nitric acid, ammonium nitrate, pentachlorophenol, ammonia, sulphuric acid, nitroglycerine, calcium cyanamide, lead, ethylene glycol, methanol, copper, aluminium, bis(2-ethyl hexyl) adipate, dibutyl phthalate, sodium hydroxide, mercury and silver.
A groundwater monitoring programme at Albion indicated the presence in groundwater of the following contaminants at concentrations in the ranges indicated:
RDX <50 - 235 µg/L
2,4,6-TNT <10 - 650 µg/L
2,6-DNT <10 - 2,100 µg/L
2,4-DNT <10 - 2,640 µg/L
MNT <10 - 3,190 µg/L
Metals detected in the groundwater at various concentrations were as follows:
barium, chromium, cobalt, copper, iron, manganese, tellurium, titanium, aluminium, beryllium, cadmium, lead, mercury, nickel, silver, and zinc.
Metals tested but not detected included: arsenic, antimony, selenium.
Total dissolved solids in the groundwater varies from negligible to 29,000 mg/L. Background levels of TDS in the vicinity of the site are generally in the range 1,000 to 7,500 mg/L.
The Explosives Factory Maribyrnong occupies a large site in the loop of the Maribyrnong River in Melbourne VIC. Processes included the manufacture of explosives and assembly of armaments and manufacture of other industrial chemicals. In addition to the explosive compounds (as detailed for other sites above), other chemicals included:
- acids (nitric and sulphuric) and alkalies;
- red fumed nitric acid;
- isopropyl nitrate;
- ammonia and ammonium nitrate;
- nitrocellulose;
- lacquers and paints;
- war chemicals including mustard gas, phosgene, and napalm.
Villawood, a 5.2 ha property in NSW was used for manufacture of explosives, tanks and prefabricated houses, and has been used as a stores depot. The site has a range of low level contamination including: heavy metals, organochlorine pesticides, PCBs, PAHs, chlorobenzene, petroleum hydrocarbons from fuel and asbestos. The main focus of decontamination activity is chlorobenzene and 1,2 dichloro benzene. Clean-up is estimated at $0.5 million AUD or $100,000 AUD per ha.
Explosives Handling, Storage, and Testing Sites
Some very large sites established for the storage, distribution and testing of explosives, and for the specialist research have also been in the forefront of sites assessed for contamination, although little actual clean-up has been done. These include sites such as Newington in NSW, the former east coast armaments depot which is being replaced as it no longer meets UN standards due to the proximity of commercial and residential developments. The Newington site forms part of the site chosen for the 2000 Olympics. Other such sites include DSTO Salisbury in South Australia, Ravenhall at Deer Park in Victoria and Marrangaroo in NSW.
Clean-up is currently underway at DSTO Salisbury in SA which covers approximately 1,800 ha (which includes the RAAF Base Edinburgh). The site is occupied by the Defence Science and Technology Organisation (DSTO) for activities that have included missile development and testing, ordnance research and testing and disposal, explosives manufacture and electronic weapons development. It is also partly occupied by the RAAF Base, an army base and associated facilities. Other activities include railway sidings, and cropping and grazing in buffer zones between operational units.
Contaminants are located on 35 sub-sites spread over the area with an estimated volume of 90,000 m; of affected soils for remediation (or approximately 50 m; per ha). Heavy metals are the principal contaminants at the majority of the 35 sub-sites, with a small number that include petroleum hydrocarbons from fuels, volatile organic compounds from solvents, asbestos and explosives residuals from the testing and disposal. Operational areas targeted included areas where detonator formulations were produced including mercury fulminate, lead azide, and lead styphnate. Nine of the sites were waste dumps, and six were filled concrete tanks. Dumped wastes included electroplating wastes. Two sites were contaminated with radioactive wastes including magnesium-thorium alloys from missile and rocket bodies and low level gamma emitters from obsolete amplifier valves.
No significant widespread contamination by explosives was detected. That detected was principally propellants and some instances of RDX, Tetryl, 2,3-DNT and TNT. The metal contamination to be cleaned up includes mercury, zinc, chromium, arsenic (from sheep dips[1]), and to a lesser extent copper and cadmium. The asbestos is principally in the form of asbestos sheeting or vinyl tiles from building materials. Organochlorine termiticides were suspected to be present beneath buildings (However, at the time when this Study was written, neither their presence nor absence was proven.)
Groundwater is principally contaminated with trichloro ethylene (TCE), other associated chlorinated hydrocarbons (including 1,1 dichloro ethene and 1,4 dichloro benzene), PAHs, and petroleum hydrocarbons (C6-C9). However the salinity of the groundwater also makes it unlikely to be suitable for a wide range of beneficial uses and clean-up will be limited to one or two restricted areas of TCE contaminated groundwater, whilst groundwater quality is being extensively monitored on the remainder of the site.
The explosives storage and testing facility at Ravenhall VIC occupied a site of 213 ha comprising mostly buffer zones used for agriculture surrounding the testing facility. Activities included a railway siding and sheds to tranship and store military equipment and explosives, including ammunition and propellants during WWII. Later uses included rocket motor static firing tests, explosive trials for fuses, flares and other pyrotechnics and the destruction of surplus test materials by burning.
Primary contaminants anticipated were copper, lead, zinc, RDX and TNT. A total of up to 2,500 m3 of contaminated soil was estimated for the whole site. However, the site investigation indicated only about 0.1% of the site was contaminated. Contaminants identified were mainly arsenic, copper, lead and zinc. The bulk of the significant contamination was limited to the two main testing areas involving about 350 to 400 m; of contaminated soil over less than 100 m2. About 2,000 m3 was affected by a small proportion of ash & coal. No explosive residues were detected. The buffer zones were found to be uncontaminated, which was confirmed by later investigation for a prison development. Levels of barium of up to 2,200 mg/kg were considered to be naturally occurring trace elements in the basaltic soils. Rumours of disposal of radioactive wastes on the site were investigated using gamma detection equipment with none detected.
The former RAN armaments depot at Newington, together with other NSW State owned land in Homebush bay area of Sydney, forms part of the Olympic site. A major amount of effort has gone into characterising the site contamination. The site covers a range of ecosystems including saline river, brackish wetlands, dry land vegetation and the Newington Ridge Forest all of which have heritage importance. The major source of contamination on the site is a number of landfills, seepage from the landfills and into the wetlands. Numerous extensive investigations since 1989 have identified the following contaminants.
- PAHs (benzo-a-anthracene, naphthalene);
- the metals arsenic, boron, cadmium, chromium, copper, lead, mercury and zinc;
- benzene, toluene, ethyl benzene, xylene, chloro benzene;
- ammonia;
- organochlorine pesticides including DDT and dieldrin;
- asbestos; and
- possibly UXO.
High ecological risks identified were associated with PAHs, ammonia, benzene, toluene, cadmium, copper and zinc. It was initially anticipated that Dioxins would be a major problem on the site, but the testing indicated that this was unlikely.
Marangaroo is a 1,700 ha ammunition depot in NSW, and has also been used for explosive ordnance disposal. The principal contaminants detected were explosive ordnance waste, UXO and chemicals including preservatives, pesticides, herbicides, PAHs, BTEX, PCBs, petroleum hydrocarbons, halogenated hydrocarbons, neutralising agents, asbestos and chemical warfare agents (types not specified). The contamination is spread over 100 sites in the storage and disposal areas, and also in the major watercourses. The contamination is considered to have been spread principally by airborne dispersal from blast and fall out, and burning. The Environmental Assessment at Marangaroo is estimated to cost about $1.5 million AUD, or about $1,000 per ha AUD. Clean-up costs have not yet been estimated.
Naval Dockyards & Shore Bases
Naval dockyards tend to be relatively small and as they are located in Port Areas, they are usually surrounded by similar civilian sites. As they usually contain workshops and metal fabrication areas, paint shops and other services, they potentially have a similar range of contaminants to the armaments manufacturing sites including:
- petroleum hydrocarbons
- solvents, monocyclic aromatic hydrocarbons
- metals
- cyanides
- chlorinated hydrocarbons
- PCBs
- PAHs
- phenols
- organochlorine pesticides
- tributyltin (from anti-fouling paints).
As with other defence industries, there is a ubiquitous presence of asbestos in insulation, lagging, fire proofing and in dockyard buildings as asbestos cement roofing and cladding materials, but also potentially to past stockpiles derived from stripping of asbestos containing materials from ships in the 1980s. Frequently as dockyards and shore establishments are located in filled areas, there is also the potential for fill typically contaminated with metals TPH or PAH. This was found to be the case with the shore establishment HMAS Cerberus in Victoria.
A particular contaminant that may also be present on Naval sites is OTTO Fuel. This is a fuel loaded into torpedoes that does not require oxygen to burn. It comprises propyl- glycol dinitrate (PGDN) which is a carcinogen and is volatile and toxic. This can also be found on airbases where it is used for fuelling of airborne torpedoes. There is no information concerning whether any residues have been detected on CMS.
Nuclear Test Sites
During the 1950s and 1960s, atmospheric nuclear tests were carried out by the British Government on Australian territory. Tests were undertaken at Maralinga and Emu in South Australia, and at the Monte Bello Islands in the Indian Ocean just off the west coast of Western Australia. The first, in the Monte Bello islands involved the atmospheric detonation of a nuclear bomb on a ship and two later ones on land were also atmospheric. Later tests at Maralinga and Emu (about 190 km to the north east of Maralinga) involved the testing of trigger devices above ground specifically to assess the distribution of fall out.
The nuclear weapons testing and development programme in Australia conducted by the British Government included 12 atmospheric tests and a large number of "minor trials". Seven atmospheric tests and hundreds of the "minor trials" were carried out at Maralinga. The "minor trials" dispersed plutonium in narrow plumes extending about 20 kilometres in length which presents a serious radiological hazard at three sites. Residual plutonium in surface layers exists as finely divided dust, as small sub-millimetre particles and as surface contamination on larger fragments of debris. Two of the atmospheric tests and five of the "minor trials" were held at Emu. Clean-up of the contaminant plumes was attempted by the British Government in 1968 (Operation Brumby) by ploughing to a depth of 150-250 mm in an attempt to reduce surface contamination.
In 1986, the Australian and British Governments established a Technical Assessment Group (TAG) to assess clean-up costs and options based on the assumption of some degree of future access to the test site lands by their traditional owners, the Maralinga Tjarutja Aborigines. See Section 2-7.2 - Nuclear Test Sites.
Other Sites with Radioactive Wastes
A proportion of the defence weapons research establishments, depots, operational sites and other facilities have produced quantities of radioactive wastes for various reasons. These have included: radioluminescent instrument dials and compasses (radium); radioactive sources for instruments or hospital equipment; depleted uranium ballast from aircraft & rockets; thorium coatings from aircraft windshields; gaseous tritium light sources from ambush lights and road markers; and minute quantities of plutonium dispersed in soil.
Sites with Unexploded Ordnance (UXO)
All bombing ranges, artillery and naval gunnery ranges have a potential for the presence of UXO, including unexploded shells or bombs, practice bombs and other explosive devices. Common practice within the armed services is to record the location of the fall of these devices and to follow up after use of the range.
UXO includes the unexploded fragments of bombs or shells that may have disintegrated and not completely burned. These may be small and very hard to detect as well as spread over a wide area. The Commonwealth Governments policy with regard to UXO and methods for investigation of sites is discussed in Section 2.-7.0.

2.-6.0 Registration of Suspected Contaminated Sites (SCS)


DoD has organised the management of CMS under Regional Environmental Managers, has established its own registration system and keeps files on sites found by investigations to be contaminated. The DoD does not maintain a central register of SCS and as yet there is no national register that incorporates these sites.
Although DoD and the various services do not keep central registers of chemically contaminated sites, the Logistics Policy Branch of the Logistics Division of the DoD does maintain a register of sites potentially contaminated with unexploded ordnances (UXO). Approximately 1070 such sites have been identified including existing gunnery and bombing ranges, together with a large number of properties mostly located in Queensland. Although the Queensland sites were never owned or permanently occupied by the DoD or the Army, they were used during and immediately after World War II as training areas by both the Australian Armed Services and those of Britain and the USA.
The DoD philosophy appears to be that the very nature of military operations is such that all military sites must be considered as SCS and therefore they are treated on that basis until the information is available to determine the environmental quality of the site. No site is released for sale or lease without an environmental evaluation of the contamination status of the land in relation to the local environmental legislation applicable in that State.
Individual State registers do incorporate some military sites within their lists where there is suspected, known or confirmed contamination. For example, the Victorian State Register of Confirmed Contaminated Sites includes HMAS Lonsdale, a Navy shore establishment. The Queensland register also includes defence sites in general on the basis of their historical military usage in keeping with the Queensland's Department of Environment and Heritage (DEH) policy for the inclusion on the register of all SCS.

2.-7.0 Methods For Investigation of CMS


General
All current site assessments carried out on behalf of DoD on CMS are required to follow the ANZECC Guidelines for the Assessment and Management of Contaminated Sites (Appendix 2-1).
The ANZECC Guidelines are comprehensive and set out the framework for identification and assessment of SCS. This includes: site investigation methods; sampling and analysis requirements; threshold investigation levels; and the methodology for ecological and health risk assessments where contamination exceeds threshold levels. As these are nationally based guidelines and accepted in principal by all environmental authorities throughout Australia, they are a universal reference for all practitioners including DoD. The ANZECC recommended approach to the Assessment and Management of a SCS is summarised in Figure 2-3 attached (in Appendix 2-3).
The laboratory testing performed for environmental assessments is carried out in accordance with the ANZECC guidelines and the results are compared with soil quality acceptance criteria adopted under these guidelines. These criteria are designated A & B levels and are approximately equivalent to the so-called Dutch "A" and "B" criteria for soil contamination (for details see Section 2.-7.3).
For Defence contamination surveys, analytical results from the first stage assessment are also compared with the ANZECC threshold investigation levels (Appendix 2-1), or where they do not exist, the Dutch Guidelines, and/or USEPA guidelines derived from the US-American data benches IRIS (Integrated Risk Information System) and HEAST (Health Effects Assessment Summary Tables).
These USEPA guidelines are used to determine concentrations for contaminants beyond which permanent adverse affects occur to human and ecological receptors. There is no threshold level for genotoxic carcinogens. If the results of the sampling indicate a potential problem, funds may be allocated for a second stage investigation programme to assess the extent of any areas of contamination.
Environmental audits, assessments and clean-ups of CMS are usually carried out or managed on behalf of DoD by specialist environmental consulting and engineering companies. Approximately 6 to 8 such companies regularly perform assessments, environmental monitoring or manage clean-ups for DoD. Equipment for sampling and other surveys is provided by experienced drilling, civil engineering, and specialist contractors. For example, there are two or three specialist companies providing UXO detection services. ADI(L) with its background in the defence industry specialises in the provision of investigation and decontamination contracting services to DoD including UXO detection.

2.-7.1 Registration and Preliminary Assessments


In general, all military sites are considered to be potentially contaminated. A decentralised system for registering sites that actually have been found to be contaminated has been established as detailed in Section 2.-6.0.
Preliminary environmental assessments to identify SCS are generally based on a combination of the known history of contamination on the site, which can be derived from both anecdotal and written records, and an assessment/audit of activities carried out at the site including present activities. Records that may be consulted include: current and historic maps & plans; historical photographs and air photos; government gazettes which may refer to activities such as bombing and artillery ranges; and groundwater databases. A detailed site inspection will be completed to look for evidence of any activities that may have resulted in contamination. As part of the results of the assessment a Sampling and Analysis Plan may be prepared to assess the presence and likely extent of any potential contamination indicated by the historical assessment.
One of the characteristics of CMS is that there are often good records kept by the military authorities regarding former activities on the long established military sites. Record keeping with regard to ordering of materials, the retention of spare parts and equipment, and the organised disposal of surplus materials or wastes is usually comprehensive.

2.-7.2 First Investigation, Detailed Assessment, Risk Assessment


General Strategy for Soil Sampling
Consultants are employed by DoD on the basis of their appropriate experience to develop and conduct work plans which include implementation of the sampling and analysis plans and data management plans. These plans conform to local and international guidelines and standards on sampling, the spacing of samples points and the number and amounts of samples including Quality Assurance/Quality Control samples, methods of collection, storage and handling.
Standards and guidelines referenced include amongst others:
- USEPA SW-846 - Test methods for evaluating solid waste
- Draft Australian Standard on sampling and analysis of potentially contaminated soils
- The Draft ANZECC guidelines for the analysis of contaminated soils
- The Draft guidelines for consultants reporting on contaminated soils (NSW)
- Contaminated sites sampling design guidelines prepared by the EPA (NSW).
New South Wales EPA has also produced guidelines on the assessment of service station sites and for management of environmental issues relating to underground storage tanks and petrol station sites, the Australian Institute of Petroleum has produced Codes of Practice for the design, installation, operation and removal of underground storage tanks.
Anecdotal information on activities and the location of waste disposal sites with careful review of good quality air photos, is followed up by use of specialised geophysical methods such as magnetometers and electromagnetic induction surveys, which often provide the best indication of the location of disposal areas, including unauthorised areas used for burial of wastes.
Sampling at SCS sites can be done by use of hand excavation or augering equipment, mechanical excavators or typically hollow flight auger drills with tube samplers. Spacing varies depending on the size and history of the site. The Draft Australian Standard and EPA (NSW) guidelines indicate the minimum number of sampling points for site characterisation based on hotspot detection by systematic sampling patterns. This ranges from a minimum of 5 points for sites of under 500 m2 (0.05 ha or 100 points per ha to detect a hotspot of 11.8 metre diameter with 95% confidence) in both the guidelines and the standard, up to 120 points on 30 ha (a minimum of 4 points per ha with projected detection of a hotspot of 59 metre diameter with 95% confidence) in the Draft Australian Standard. The EPA (NSW) guidelines, which extend up to a maximum of 55 points over 5 ha (equivalent to 11 points per ha with projected detection of a hotspot of 35.6 metre diameter with 95% confidence), disclaim responsibility for blanket approval of the appropriateness of these minimum spacings and also give no guidance for sites of more than 5 ha.
Each CMS is investigated on an individual basis, usually with a combination of sample points located on a grid pattern together with selected sampling points focussed on SCSs. For example, the chemical screening plan prepared for RAAF Williams on the basis of the initial historical studies and facilities audit, ranked the airbase into four main types of areas on the basis of the potential for contamination as follows:
Level 1: Areas of very low potential for contamination (airfield areas, runways, taxiways and adjoining grass areas where there was no history of potentially contaminating activities).
Level 2: Areas of low potential for contamination (administration and housing areas and with a few localised SCSs such as heating oil storage tanks, petrol service station site, etc)
Level 3: Areas of moderate to high potential for contamination (maintenance, manufacturing, storage areas, aircraft service facilities, bulk fuel storage and refuelling areas, fire training areas etc)
Level 4: Areas of high to very high potential for contamination (landfill areas, liquid disposal sites etc)

On the above rankings, the suggested sampling density was as follows:
Level 1: 500 metre grid with some selected groundwater sampling points.
Level 2: 200 metre grid with a minimum of 2 additional points focussed at each local SCS identified and selected groundwater sampling points.
Level 3: 100 metre grid with a minimum of 2 additional points focussed at each local SCS identified and groundwater sampling points spread throughout each area ranked as Level 3 and individually at each fuel facility.
The strategy for investigation of Level 4 areas was different in concept due to the potential presence of uncharacterised wastes in landfills. Geophysical methods including magnetometers or electromagnetic resonance (EM) are used to define the boundaries of landfills followed-up by the installation of a limited number of boreholes to characterise the wastes together with groundwater monitoring bores on the perimeter to monitor any migration of contaminants to the rest of the site or off-site. Other ranking systems may be developed on a site by site basis.
Handling of Unexploded Ordnance (UXO)
In 1990, the Commonwealth government prepared a policy on the "Management of Land Affected by UXO". This referred both to existing sites and to sites disposed of or held in private hands. It is stated in the policy document that "The Commonwealth is generally under no legal obligation to commit resources to reduce known hazards associated with UXO contamination. Notwithstanding this, the Commonwealth may take action to reduce UXO hazards in some cases".
Such actions proposed by the Commonwealth UXO policy may include:
- Maintain and make available records of SCS
- Seek to influence planning proposals on affected land
- Render safe any UXO discovered by the public
- Inform the public by warning signs
- Restrict access to affected land controlled by the Commonwealth
- Provide technical advice
- Manage all land occupied by the Commonwealth and used for firing live ammunition to restrict access and the level of UXO
- Take reasonable steps to reduce the hazard on Commonwealth land to be divested
- Take action in particular cases on private land affected by UXO.
There are occasional incidents involving UXO. But these are usually found to be due to the mishandling of UXO located by the public. In general, the level of management of UXO is such that the risk to the public can be considered to be low enough that, for example, a naval gunnery range in WA is managed as a bushland reserve and the public is admitted between firings. A great effort is made to locate any UXO after completion of each exercise. There is a distinction here in the rigorous management of impact zones as compared to the surrounding buffer areas which may have public access.
In general, detection methods for UXO include magnetometers, electromagnetic resonance devices (EM61) and ground penetrating radar. However, it is not possible to guarantee complete success in removal of UXO. Geophysical techniques are also used to examine CMS sites for UXO (from possible bombing range activities and disposal of ordnance by burial). However, complete surveys of sites using EM61 type electromagnetic resonance equipment or high resolution magnetometers are time consuming as spacing of survey lines is typically no more than a few metres apart. Computer enhancement of the results to identify anomalous peaks in the data can provide a few scattered point anomalies that require follow-up with ground penetrating radar at individual soil sampling sites, or physical investigation of numerous anomalies from metal fragments, few of which may represent UXO. Even with the most sophisticated equipment available, detection rates cannot be guaranteed to be 100% and some areas, such as adjacent to wire fences, are subject to interference.
Chemical Screening
Preliminary screening for chemical contaminants comprises a basic set of contaminants for which all samples are tested and a secondary set of site specific analytes related to site history. The basic set may normally include metals, TPH, PAH, explosives. Selection of samples for further testing would be based on head space screening with a photo ionisation detector to assess the presence of volatile or semi-volatile compounds, and on visual and odour indications of the potential presence of contamination.
Screening for metals and organics on sites where the historical information is inadequate to indicate the range of contaminants likely to be present, will often include the use of ICP-MS and GC-MS mass spectrometry to screen for a broad range of potential contaminants at moderate cost. Explosive residues are screened using high pressure liquid chromatography (HPLC) with UV detection on acetonitrile extracts of samples prepared as liquid slurries to avoid loss or breakdown of the analytes that may occur using other methods (USATHAMA Methods 8H Explosives in Water by HPLC, 12-27-82 and Method 2C Cyclo trimethylene trinitramine (RDX) in Soil and Sediment samples, 12-3-80). Explosives residues routinely screened by HPLC for CMSs include:
- HMX (Octahydro-1,3,5,7-tetra nitro-1,3,5,7-tetrazocine)
- RDX (Cyclo trimethylene trinitramine)
- NB (Nitrobenzene)
- 1,3-DNB (1,3-Dinitrobenzene)
- 1,3,5-TNB (1,3,5-Trinitrobenzene)
- MNT (Mononitro toluene)
- 2,4-DNT (2,4-Dinitro toluene)
- 2,6-DNT (2,6-Dinitro toluene)
- 2,4,6-TNT (2,4,6-Trinitrotoluene)
- Tetryl (2,4,6-Trinitro phenyl methyl nitramine)
Typically, review of the results of the detailed surveys indicate the absence of contamination over most of the survey area and identifies some isolated hot spots. Further sampling and analysis related to these areas will be based on risk analysis related to the potential end use of the site, the possible need to establish the concentration and lateral and depth distribution of contaminants with upper confidence limits of about 95% for clean-up, for the characterisation of contaminants as to speciation, leachability and bioavailability to provide sufficient data for disposal or treatment options, or for quantitative risk assessment particularly where some contamination is likely to remain on site.
Nuclear Test Sites
The programme methodology employed in the assessment of clean-up options for Maralinga by the Australian/British Technical Assessment Group (TAG) included the following stages:
- Source term definition: aerial and ground surveys to determine the extent of contamination, particle sizing, fragment collection and specific activity measurements to determine its nature;
- Bioavailability: gut transfer, lung dynamics and wound sites in experimental animals; environmental transfer factors for vegetation, fruiting bodies and collectable food animals; soil profiles, physical concentrating factors;
- Exposure routes: quantitative anthropological studies into cultural habits, food sources, food gathering and daily activities, instrumented simulated Aboriginal practices and past-times in contaminated areas, quantification of natural and artificial dust raising activities;
- Dose assessment: using standard International Commission on Radiological Protection (ICRP) dosimetric factors or experimental values;
- Uncertainty analysis: value judgement on upper and lower bounds for experimental dosimetric parameters; worst case value judgements on parameters not amenable to experimental measurement, eg. probability of cuts/wounds, soil ingestion by infants.

2.-7.3 Technical Instruments for Risk Assessments


For Defence contamination surveys, analytical results from the first stage assessment are at first compared with the ANZECC threshold investigation levels (Appendix 2-1).
The "A" Level ANZECC criteria are equivalent to natural (low) background levels and indicate a range of levels, as soils in Australia have a wide range of background "contamination" levels. "Background levels" in Australia can, and often do, exceed levels at which they would be considered to be a potential risk to the environment and/or human health. For example: background levels of arsenic in excess of 1,000 mg/kg can occur in soils associated with the gold mining areas in western Victoria. This can be compared to the ANZECC environmental investigation level of 20 mg/kg and health investigation level of 100 mg/kg; and to the former Dutch "C" criteria of 50 mg/kg and the new Dutch "Intervention" level of 55 mg/kg.
The "B" level ANZECC criteria are threshold levels at which one may have cause to investigate further if the circumstances are warranted, but are not intended as clean-up levels. The ANZECC criteria are summarised in Table 2.-1-1 in Appendix 2-1 for reference.
The ANZECC guidelines do not indicate other reference levels for soil contamination and require that, for levels exceeding the ANZECC threshold values (or in their absence, Dutch B investigation levels), risk assessment techniques be used to assess the potential for adverse health or ecological effects resulting from the presence of contamination on the site, or from potential migration of the contamination to receptors off-site. Although computer programmes for health and ecological risk assessments are available and widely used including "Risk Assistant" based on USEPA protocols, and the Dutch based "HESP" and Canadian based "Aeris", they are not widely favoured for use on CMS by DoD as they all include default values related to European or North American soils, climates and lifestyles. There is no specifically Australian equivalent and risk assessments are generally calculated manually using the protocols established by ANZECC. As discussed above, initial assessments are compared to the ANZECC ecological threshold values and health investigation thresholds and, where ANZECC levels are unavailable, the Dutch criteria are used for reference then. If justified, quantitative ecological and health risk assessments may be completed for specific contaminants related to the proposed end use of the land.
Human health risk assessment is based on WHO numbers for Acceptable Daily Intake (ADI) and Provisional Tolerable Weekly Intake (PTWI) calculated on body weight of individuals and the site specific assessment of exposure pathways for the identified contaminants. Potential absorption is assessed from the bioavailability of each chemical considered and the total amount ingested based on typical ingestion or absorption rates set out in the ANZECC guidelines. For the purposes of exposure assessment it is recommended in the guidelines that an estimated soil ingestion level for children of 1-5 years of 100 mg/day of soil from all routes be used.
Estimated human soil intakes for exposure assessment purposes from ANZECC guidelines are:
- 0-1 year negligible
- 1-5 years 100 mg/day
- 5-15 years 50 mg/day
- Adult 25 mg/day
The above numbers are considered to be typical for total ingestion of soil by all possible routes, including inhalation, but would be generally representative of a European style culture. These numbers would not apply where the opportunities for ingestion of soils are much greater, such as may occur in outback Australia. The outdoor lifestyle typical of traditional Australian Aboriginal culture can afford increased opportunities for ingestion of soils associated with outdoor eating and living in an often dusty environment as was indicated by studies relating to the former nuclear test sites at Maralinga.
The Maralinga studies concluded that the most significant radiological pathways are inhalation of resuspended activity, for which the largest doses are received by 10 year old children, and the ingestion of contaminated soil by infants in the first year of life.
The risk assessment model recommended by ANZECC is based on that established by the USEPA guidelines for superfund sites - the Human Health Evaluation Manual EPA/540/1-85/060 of 1989.

2.-8.0 Clean-up Attainment Goals


Clean-up attainment goals have in the past been defined by State based environmental agencies, more recently with reference to the National guidelines provided by ANZECC. In the absence of any Australian defined clean-up criteria, the Dutch B investigation levels, and in some cases the Dutch C levels for both soils and groundwaters, have been used as de-facto clean-up criteria. Clean-up attainment goals for CMS are established by the DoD on a site by site basis depending on the location and potential land uses and economic restrictions.
The size of military sites makes them attractive for re-development where they are in an urban environment. Clean-up of the contaminated parts of a large training site is less likely if it is in a rural area where property values are low and the cost of decontamination cannot be justified. The target is to find appropriate uses of such properties, for example: grazing for a large training area, or the sale of a rifle range to a rifle club.
Frequently, community perceptions and pressure have also established clean-up goals for contaminated sites in the past, for example Albion where the availability of a large area of land close to the City of Melbourne generated pressure for complete clean-up to provide space for development of housing. These community pressures frequently have resulted in unrealistic goals that are uneconomic to attain ($50-60 million AUD at the tax payers expense for $9 million AUD worth of land at Albion) when the integration of appropriate planning for a site with realistic contamination management goals would provide a better commercial outcome for the community as a whole.
With the establishment of the Accredited Environmental Auditor system in Victoria and its progressive acceptance in other states, DoD and others are now relying more heavily on the Auditors to establish risk based clean-up criteria on a site by site basis in keeping with economically attainable future land use goals.
Acceptance criteria proposed for Albion and St Marys sites were based on health risk assessments which established target criteria for concentrations in soils based on carcinogenicity of the explosives as follows:
Contaminant Albion Criteria St Marys Criteria
2.4 DNT 1.5 mg/kg 1.0 mg/kg
2.6 DNT 0.5 mg/kg 0.5 mg/kg
2.4.6 TNT 30 mg/kg 15 mg/kg
RDX 10 mg/kg 10 mg/kg
Nuclear Test Sites
Following the investigation of Maralinga (see Section 2.-7.2), the Technical Assistance Group report put forward a number of options. The preferred option as agreed between the Commonwealth Government, the Maralinga Tjarutja and the South Australian Government specified remediation of the most heavily contaminated sites and some restrictions on access to less contaminated areas. The rehabilitation project began in 1994 and is due for completion in the year 2000. Details with respect to remedial attainment goals are not available.
The TAG report also concluded that there was no radiological reason why the Monte Bello Islands could not be returned to Western Australian control. It is intended to manage the islands as a Conservation Park and the absence of potable water and their remoteness, ensures that visitation will be casual and present no radiological risks.

2.-9.0 Clean-up Technologies


The ANZECC Guidelines indicate a preferred order of options for site clean-up and management as follows:
- On-site treatment of the soil so that the contaminant is either destroyed or the associated hazard is reduced to an acceptable level;
- Off-site treatment of excavated soil which, depending on the residual levels of contamination in the treated material is then returned to the site, removed to an approved waste disposal site or facility or used as fill for landfill.
Should it not be possible for either of these options to be implemented, then other options that should be considered include:
- Removal of contaminated soil to an approved site or facility, followed where necessary by replacement with clean fill;
- Isolation of the soil by covering with a properly designed barrier.
- Choosing a less sensitive land use to minimise the need for remedial works which may include partial remediation.
- Leaving contaminated material in-situ providing there is no immediate danger to the environment or community and the site has appropriate controls in place.
Soil Technologies
Clean-up technologies trialed and used on Australian sites generally comprise conventional well tested methods as projects are generally too small to invest large sums in trialing innovative technologies.
Those used in Australia include for soils:
- Excavation and Landfill
- Capping and containment
- Solidification
- Soil washing
- In-Situ Vitrification (at Maralinga)
- Bioremediation/Land farming
- Thermal Desorption
- Base Catalysed Dechlorination of PCBs.
High temperature incineration is not an option in Australia due to community pressure although hospital wastes are routinely incinerated in many low temperature incinerators linked to hospitals.
! Excavation and Landfill
Of the foregoing, the excavation and off-site landfill option is the most commonly practised, particularly in Victoria where disposal of contaminated soils to engineered landfills is feasible at relatively modest cost, whilst on-site landfill and/or capping and containment is probably the most common on CMS (eg Newington and DSTO Salisbury sites) where it is planned to contain some existing landfills on site. Containment on site is more desirable where feasible rather than the transfer to another off-site landfill which creates a second contaminated site.
Clean-up methodologies considered for Albion and St Marys have included on and off-site removal of contaminated soils to secure landfills (Albion), bioremediation by land farming or bioreaction, physico/chemical treatment by incineration or steam volatilisation and including thermal desorption (see below) and mechanical separation by soil washing at St Marys. The landfill areas remaining at Albion would be prohibited from future use except for open space including a golf course. Low temperature thermal treatment was selected for decontamination of the St Mary's site.
At present, clean-up on the Albion site has amounted mainly to the stockpiling of contaminated soils in various segregated stockpiles and the treatment of the soils has been minimal. However, an extensive groundwater monitoring programme has been established.
! Clean-up of Radioactive Contamination
On nuclear test sites, an attempted clean-up at Maralinga in the 1960s was unsuccessful. The initial clean-up attempt called "Operation Brumby", was initiated by the British Government, but failed largely due to inadequate funding. The techniques attempted involved ploughing of the footprint of the fall-out plumes to turn over and bury the contaminated soils and contaminated equipment at shallow depth beneath the surface. However wind erosion of the sandy soils rapidly re-exposed the contamination and also exposed more contaminated equipment that was previously buried in the sand.
The current clean-up programme at Maralinga is proceeding under the direction of the Department of Primary Industries and Energy and is managed by Works Australia, a Government owned engineering business. The Australian Radiation Laboratory (ARL) is the project regulator. The methodology is primarily excavation and land filling. It will involve excavation and removal of the top 200 mm of soil and disposal into deep trenches which will then be suitably capped. It is proposed to use aircraft with detection equipment flying at about 50 feet for identification of contaminant plumes and any other radioactive material to assist in the process. The use of in-situ vitrification is being trialed on the Taranaki site at Maralinga and is discussed further below.
For other radioactive wastes, sites such as DSTO Salisbury in South Australia and the Kingswood Depot in NSW have accumulated radioactive wastes from various sources. Clean-up of these sites is planned for sale of the properties. Defence facilities in Victoria, and the St Marys armaments factory in NSW have in the past also accumulated and stored low or medium level wastes from various sources including instruments, experimental nuclear materials and from hospital wastes, universities, and medical practitioners. These have been transferred to the ANSTO radioactive isotope reactor at Lucas Heights in NSW for conditioning and packaging, from where they were recently transferred to the former rocket test range at Woomera in South Australia for temporary medium-term storage in a bunker building.
The handling and storage of these materials follows national guidelines, namely the 1992 NH&MRC "Code of Practice for the Near-Surface disposal of Radioactive Waste in Australia". Material transported to Woomera includes the radionuclides: radium-226; americium-241; strontium-90; cobalt-60; caesium-137; tritium; carbon-14; plutonium-239; europium-152 and caesium-134.
The current situation is considered to be temporary and long-term solutions are still under investigation. It is considered likely that Woomera will be used for storage of all such wastes derived from clean-up of military and civil sites for some years until a permanent solution is found. Costs are unknown.
* Stabilisation and Solidification
Stabilisation and solidification comprises a group of waste-treatment processes designed to: reduce waste solubility, mobility and toxicity; improve handling characteristics; or limit the potential for migration by reducing the exposed surface area. Thus, stabilisation and solidification, when done properly, can be an effective and reliable immobilisation technique for metals.
Nearly all stabilisation and solidification processes involve the addition of materials to the waste, and thus increasing the total waste volume. These volume increases usually range from 30% to 60%. They are therefore unattractive for use on CMS except where contaminated material needs to be stabilised to allow removal off-site to a secure landfill.
* In-situ Vitrification (ISV)
The Department of Primary Industries has contracted the US firm Geosafe to determine the feasibility of stabilising 22 plutonium contaminated burial pits at the Taranaki site at Maralinga. ISV involves the electric melting of soil, waste and debris to destroy contaminants or immobilise them within a high integrity vitrified residual product. The ISV process works by melting soil in place using electricity applied between four graphite electrodes inserted into the ground in a square configuration. Electricity applied to the electrodes flows through a conductive starter path which heats up and causes the surrounding soil to melt. Once the soil is molten it becomes electrically conductive. Continuous application of electricity results in joule heating within the molten soil between the electrodes and leads to a melt zone growing steadily downward and outward through the contaminated soil.
Phase 1 of the feasibility trials completed in 1994 involved engineering scale ISV tests and crucible melt studies using debris and uncontaminated soils from Taranaki. The results indicated that the ISV process could be applied to the soil and debris combinations at the site.
Phase 2 conducted in 1995 involved a series of ten on-site engineering scale tests and three intermediate scale demonstrations using an 85 kW system capable of producing melts up to 5 tons to obtain site specific process data. Two of the intermediate scale demonstrations used radioactive materials, including blast debris from the original weapons tests.
The principal objective of the intermediate scale radioactive ISV demonstrations was to collect sufficient data to determine if the ISV process could be expected to effectively treat the contaminated soil and debris in the Taranaki pits and to obtain data to confirm the behaviour of plutonium in the process. Data from the tests and demonstrations were also gathered to support the design of a full-scale ISV process machine tailored to the conditions of the Taranaki site.
Results of ISV trials are currently under review. A decision on use of the technology at Maralinga will be made later this year.
* Land farming
Land farming of soils contaminated with organic compounds requires large surface areas for remediation to spread the soil in thin layers. It typically requires a long treatment time, but is comparatively less expensive than other remediation techniques.
Land farming or other bioremediation methods to rid the soil of nitro aromatic and other explosive residues has been considered by DoD at a number of sites including Albion and St Marys in conjunction with physico/chemical methods to deal with the remainder of contaminants. At Albion it was estimated this would need a similar or greater amount of organic matter to be added to the soil to be effective (up to 2 or 3 times) and would need frequent turning. DoD considered that they did not have sufficient facilities (or available horse manure!) to achieve this for 600,000 m3 of combined soil and manure. Other concerns of the DoD were the low concentration of residues in much of the soils which it was considered would not sustain the process, and on sites where the levels might be higher such as St Marys, it was anticipated that the toxicity of the contaminants would also kill the bacteria and halt the process. Another concern is that at the low concentrations of Albion, the process would be extremely slow and unable to achieve target levels for residential use of the site.
* Low Temperature Thermal Treatment (Thermal Desorption)
Soils affected with petroleum hydrocarbons or explosive residues can be remediated physically by thermally desorbing the petroleum hydrocarbons from the soil under a slight vacuum. The off gas from desorption is then treated with a thermal oxidiser. The low temperature treatment system comprises a kiln and a dual-venturi collision scrubber. The entire operation can be fuelled by propane.
To treat hydrocarbon affected soils, the soil is fed into a hopper with a telescopic front-end loader. The soil is then conveyed to a heat zone and heated to a pre-determined temperature ranging from 230°C-290°C using infra-red heat.
Thermal desorption has been trialed by ADI (L) on the explosives manufacturing site at St Marys in NSW. It has been used on the explosive residues dispersed through the sediments in settling ponds. It is considered not to be suitable for disposal of UXO materials in soils due to the inherent dangers of explosion during the heating process.
In trials at St Marys (see below) 300 to 350oC were found to be most appropriate for TNT. The off gas is then passed through a thermal oxidiser to form CO2 and water vapour. The flue gas is then passed through a wet scrubber to remove dust and particulate matter and the remediated soil exits with added moisture from the scrubber solution and is ready to be used as backfill. The St Marys' plant has an afterburner that heats the off gases to 980oC.
Using this treatment method, the soil at St Marys was remediated to non-detectable levels with a typical throughput rate of approximately 140 cubic metres per day or around 250 tonnes per day. The St Marys plant was rated at 20 tonnes per hour, a theoretical output of 480 tonnes per day if a twenty four hour operation was run. Trials of thermal desorption at the St Marys site are discussed in Section 2.-13.0.
* Bioremediation
Bioremediation refers to a broad spectrum of water, waste, sludge and soil treatment approaches each having a biological treatment component. Biological treatment can be accomplished by bacteria, fungi, and higher plants. It may be used alone or in conjunction with other unit processes.
Biological systems can be tailored to meet the budgetary limitations for disposal of a CMS by treating wastes, soils, and groundwater over extended time periods after containment is achieved and immediate human health risks are minimised. There is usually sufficient time and space available on CMS to allow for the bioremediation process. It is therefore frequently considered as a component of CMS clean-up.
DoD experience in trials on CMS sites, is that the toxicity of the explosive residues can be a limiting factor on the success of bioremediation. If however, the toxicity is not limiting, optimal nutrient and oxygen conditions can be established.
Applications of bioremediation in Australia on both CCS and CMS include:
- on-site treatment of water, sludge and soil in an impoundment (pit, pond or lagoon) using nutrient addition, aeration and controlled mixing
- treatment of soils or sludges by conventional land-based surface treatments, such as Land farming or composting; these approaches required good soil management and control of soil aeration, pH, temperature and moisture, and nutrient status
- in-situ treatment of contaminated soils and groundwater through stimulation of indigenous organisms by the addition of oxygen and nutrients
- treatment of liquid or solid wastes in bioreactors, such as activated-sludge systems, aerated lagoons, slurry reactors, and so on.
Groundwater Remediation Technologies
Groundwater clean-up is not frequently carried out on CMS. Technologies that are available include:
- Pump & Treat
- Dual phase pumping
- Carbon filtration
- Air stripping
- Vacuum extraction
- Membrane separation
- Bioremediation
- Precipitation, and
- Oxidation (both ozone and hydrogen peroxide).
Most groundwater decontamination activity in Australia is centred on sites where petroleum products have been spilled or leaked from storage tanks and typically involves passive scavenger systems or active scavenger or dual phase pumps to remove non-aqueous phase liquids and contaminated groundwater. Processes include groundwater pumping to oil/water separators, stripping towers, and carbon filtration systems with disposal of excess water to sewer or to land. Many CMS are monitored for migration of contaminants (eg Albion, Newington) and there is recovery and treatment of leachate from landfill areas, but there is very little active groundwater clean-up in progress.
While circumstances surrounding groundwater remediation projects vary from site to site, the most commonly encountered situation involves organic contamination of soils and groundwater in which carbon adsorption and bioremediation may be the most economical solution. In this case, the design is required to design for intangible factors and incorporates the extensive use of computer models which are either available within the industry or are developed in-house by consultants. Several computer models are used for air stripper design and for carbon adsorption unit design. Experience in the application of such remediation methods ranges from pilot-scale to full-scale, but is however limited.
The DoD favours in-situ bioremediation methods on CMS as this is relatively passive and economic, and timescale is not generally a major issue.

2.-10.0 Prioritizing of Sites


Prioritizing of sites for clean-up is on a site by site basis depending on the disposal programme of DoD as described in Section 2.-3.0. Emergency clean-up or decontamination may be carried out on operational sites by the armed services as an appropriate response to a contamination emergency. However all other decontamination activities will depend on commercial considerations for eventual land use or on the potential for on site human health risks or off-site effects to neighbours. Some areas will be isolated, maintained and monitored where appropriate.
Political pressure may change priorities in some limited high profile cases such as Albion and Maralinga. In some cases, like Newington, the priority was originally determined by the limited use of the site for storage of explosives, rather than the onset of the Olympics which has since added urgency to the work.
Prioritizing sites for clean-up of UXO generally follows a policy of the most urgent cases being those where the site has already been developed for residential purposes, or is in the process of being developed. The second category are those areas for which future developments are planned. The remainder fall into the least urgent category and may include rural sites where there is little chance of development, although some consideration is given to former grazing properties that are to be used for agriculture in the future.

2.-11.0 Health & Safety


Health & Safety for work on CMS is based on both national legislation and State legislation. Two relevant acts are applicable in these areas on Commonwealth or Defence property, the National Occupational Health and Safety Commission Act of 1985 which established the National Health & Safety Commission, and the Occupational Health and Safety (Commonwealth Employment) Act of 1991, the purpose of which was to promote the occupational health and safety of persons employed by the Commonwealth, including the Department of Defence.
The Department of Defence therefore takes health & safety of employees and contractors on Defence property very seriously and has active health & safety management in place throughout Defence and the armed services. All activities on CMS are therefore strictly regulated and contracts for assessments and decontamination activities require the preparation of a comprehensive site specific health & safety plan (HASP).
Typically a HASP is required to cover the following areas:
- Organisation & Responsibilities
- Scope of work and range of site conditions
- Identification of hazards
- Standard operating procedures employed to prevent accidents, injuries, exposures, etc.
- Personal Protective Equipment
- Training
- Monitoring
- Emergency Procedures
- Medical Surveillance
- First Aid Equipment
- Accident records
- Safety Inspections
- Implementation of the Plan
- Site Safety Officer.

2.-12.0 Cost Estimates


Costs are estimated for clean-up on a site by site basis as the cost will vary enormously depending on possible future land uses, location of the site, availability and charges for secure landfills, feasibility of containment on-site, and on the complexity of contaminants discovered.
Typical costs for major air or army base sites covering over 500 ha may be in the ranges:
Historical assessments $5,000 - $15,000 AUD
Sampling & analysis $50,000 - $1,500,000 AUD
Risk Assessments $10,000 - $50,000 AUD
As indicated in Section 2.-3.0, costs for decontamination of single CMS are generally categorised by DoD as follows:
Small projects 0 - $1 million AUD
Medium projects $1 - $6 million AUD
Major projects $6 - $60 million AUD (or even more)
As a specific example, clean-up on the DSTO Salisbury site in South Australia is principally done by excavation and landfill on a selected part of the site at a projected cost of about $2.3m AUD for the earthworks and an overall cost (including assessment costs of $0.5m AUD and project management) of around $3 to 4 million AUD or about $45 per m3. It is one of the first sites in SA to be cleaned up under the review of a Victorian Accredited Environmental Auditor.
The clean-up at Maralinga site is expected to be completed in 2000 at a cost of $104 million AUD. The British Government is contributing an ex-gratia payment of $45 million AUD.
Some representative estimated clean-up costs are summarised in Table 2-2 below.

Table 2-2:
Estimated Clean-up Costs








Site


Description


Area[ha]


Estimated
Volume
[m;]


Total Cost
[$million AUD]


Approximate Unit Costs [$AUD/ha - $AUD per m3]



DSTO Salisbury


Explosives testing


1,800


90,000


3-4


1,700-2,200


45


Albion (VIC)


Explosives manufacture


500


300,000


57


110,000


190


Newington (NSW)


Explosives Storage/Land-fill


240


3-6 million


58


240,000


5-10


Marangaroo (NSW)


Explosives Depot


1,700


?


(1.5)
Assessment Only


(900)
Assessment
Only


Villawood (NSW)


Explosives Manufacture


5


?


0.5


100,000


Holsworthy (NSW)


Artillery Range


50


?


3


60,000


Lonsdale (VIC)


Naval Depot


2


3-5


1.5-2.5 m


Ravenhall


Explosives Testing


213


2,500


-


-


-


RAAF Williams


Airbase


583


-


1-6


1,700 -10,300


-


Maralinga


Nuclear Test Site


215


322,000


104


0.5m


320


Note: All of the "Total Cost" figures included in this table are estimates that are based on the reported costs to date together with estimates to complete the remediation process.
In 1994 the annual budget for the DoD for investigation and emergency action on contaminated sites was reported to be $3-4 million AUD. The total budget for the Facilities and Property Division of the DoD for 1995/96 is approximately $530 million AUD for New Works and Acquisitions which is mainly expended on land acquisition and construction of new or additional base facilities.
Approximately another $350 million AUD is allocated in the annual budget for Repairs & Maintenance which includes costs related to property disposals as well as the budgets estimated for on-going base maintenance, both of which may have a component relating to assessment, monitoring or clean-up of contamination.
From individual project budgets listed for 1995/96, those identified as relating to assessments or decontamination projects controlled by the Facilities & Property Division relating to disposals of major or medium sites, comprised approximately $11 million AUD spread over about 30 projects including on-going and new projects.
The budget for environmental costs for assessment and decontamination for disposal of minor sites amounted to slightly under $1 million AUD for 1995/96 for about 35 projects most of which have minimal environmental assessment work components.
Budgets for assessment, monitoring or clean-up of contamination on operational bases branches are assigned, based on priority, from the individual base/facility budgets for maintenance and would comprise some portion of the remainder of the Repairs & Maintenance budget. These figures are not readily available but the total is anticipated not to be large.
The DoD publishes a "Guide to Consultants and Contractors" (The Green Book) which outlines proposed new facilities projects (with budget estimates) and property disposals over the next five years. However, the total budgets for disposals (approximately 100 properties) and for Repairs & Maintenance is not listed. Most of the environmental budgets controlled by the Facilities and Property Division are concentrated on a few major sites.
For example, the amounts budgeted for decontamination in 1995/96, estimates for some of these projects are as shown in Table 2-3.


Table 2-3: Clean-up Budgets for Selected Sites





Site


Total Budget
Estimated for the
Clean-up of the Site


Budget Estimate
for the Period 1995/96


Spent to Date
(up to 1995)


Albion (Explosives Factory) VIC


$47m AUD


$0.4m AUD


$10m AUD#


DSTO Salisbury (Explosives) SA


$3.1m AUD


$3.0m AUD


$0.1m AUD


Holsworthy (Gunnery Range) NSW


$2.8m AUD


$0.25m AUD


Newington (*) (Arms Depot) NSW


$58m AUD


$1.5m AUD


Notes:
* with Newington, the budget figure of $58m AUD is the most recent risk based estimate for rehabilitation of the site. However this does not appear in DoD budget estimates as the site is to be sold without clean-up to the State Government and the $1.5m AUD in the 1995/96 DoD budget is for further site characterisation only and is therefore also considered a "medium" project.
# with Albion, the figures quoted above come from the 1995/96 DoD Additional Estimates for DG-AF and are indicated as decontamination costs only and do not include all earlier costs. In a paper to the trilateral on environmental security, DoD quotes the total budgeted figure for Albion as $57 million AUD, costs to date as $21 million with 60% of the site remediated and projected sale price as $9 million AUD.

2.-13.0 Research & Development


Although the decontamination of some CMS with the expenditure of large budgets has, out of necessity, given impetus to the search for and trial of new technologies, such as thermal desorption at the St Marys explosives site, research and development of alternative technologies is not generally conducted in these areas by the DoD, although there has been some defence funded research with regard to groundwater contamination with explosive residues that is described below. The munitions manufacturing arm of the government ADI(L) as the original operator of the explosives manufacturing sites, through their industrial decontamination division, has been at the forefront of developing new technologies for military sites.
Thermal Desorption
The results of initial laboratory trials for St Marys on a pilot rotary kiln indicated that the thermal desorption process was feasible for explosives residues and a small pilot plant was established for full scale tests. Tests were conducted on samples with levels of 500 mg/kg of TNT. These were reduced to below detection limits at temperatures of about 350 oC in acceptable residence times. This supported a decision to initiate design and fabrication of a full scale thermal treatment unit.
The unit was set up in a central location on site. Careful analysis of the soils in the evaporation ponds minimised the volume of throughput to the plant. The soil was pre-processed to reduce particle size and dry it. The process was run at nominally 20 tonnes per hour, 350oC and with a soil moisture content of 12%. Sampling of the feed stock indicated the level of contaminants varied substantially. However, all of the processed soils were below clean-up criteria in nearly 200 samples.
Some representative test results indicated that, for an RDX initial concentration of 780 mg/kg, the removal rate was 99.99%; and for 2,4,6 TNT at an initial concentration of 200 mg/kg, the removal rate achieved was 99.95%, both examples having final concentrations below the detection limits of 0.1 mg/kg. The end product soil retained its structure and was suitable for engineered fill. One drawback to the thermal desorption process is that it also completely sterilises the soil. Nutrients and mulch would need to be added if it is to be suitable for agricultural re-use.
Plant Uptake Trials
More recently, to establish data on typical contaminants found on CMS for use in risk assessments, some plant uptake trials are being conducted on explosive residues, although no results have yet been published.
UXO Detection Equipment
The Geophysical Research Institute of the University of New England in Armidale, in NSW is currently assessing the effectiveness of various forms of detection equipment for UXO on behalf of ADI(L). Instruments being evaluated include a range of magnetometers, electromagnetic induction equipment, and ground penetrating radar. Preliminary results indicate that, whilst no single instrument or combination of instruments can give a 100% detection rate, the most effective all round instrument for detection of UXO which includes ferrous metal, is a caesium vapour high definition imaging magnetometer. The Geophysical Research Institute has developed its own GRI-TM4 model magnetometer with computer and recorder hardware and software package which can give high quality 2 or 3-dimensional plots of enhanced images.
Other equipment evaluated includes; electromagnetic inductance equipment models EM-61 and EM-31; the "Minelab" series of commercial mine detectors used by the army (models E1A1, F1A3 and SD2000), various non-imaging magnetometers, and the "Pulse Ekko" models of ground penetrating radar. ADI(L)'s views on the radar are that it is slow and cumbersome to use and difficult to interpret and is therefore more suited to location of specific objects over small areas rather than broad area surveys. The DoD considers the EM equipment to be suitable in areas clear of obstructions other than the target UXO, but can be severely affected by fences or other artefacts.
Mobility and In-situ Bioremediation of Explosives Residues in Groundwater
A long term study on the mobility of explosives (munition) residue contaminants in groundwater has been proceeding for some time on the site of the former Albion Explosives Factory, at Deer Park in Melbourne VIC. It is a joint project between DoD and the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and was initiated to determine the mobility of munition residues and their degradative potential in groundwater.
The research has studied the long term variations in concentration of contaminants in the groundwater and their mobility through the underlying fractured basalt aquifer. Recent experiments were conducted to examine the ability of the natural microbial population in groundwater microcosms to degrade the munition compounds and also to examine the effects of addition of amendments (nutrients) to sterile groundwater.
It was found that, in the sterile microcosms, natural degradation occurred in the absence of any "amendment" with TNT the most easily degraded followed by 2,4-DNT then 3-NT. The addition of oxygen gave the highest degradation rate. The addition of carbon and phosphate also increased the degradation rate. It was concluded by CSIRO that the observed decreases in concentration of the munition compounds were probably due to abiotic degradation or adsorption processes, and in the carbon and phosphate amended microcosms, the variability in concentration of the munitions compounds may have been due to buffering of the groundwater by the added carbon or phosphate.
The second phase of experiments was established to determine if degradation of the munition compounds was possible in non-sterile Albion groundwater under sulfate-reducing conditions. A significant decrease in the munitions concentrations in the sterile control was observed. No significant greater loss of munition compounds was observed in any of the non-sterile microcosms except for slightly greater decrease in the concentration of 2,4-DNT in the carbon amended microcosms, and of TNT and 2,4-DNT in the phosphate amended microcosms. Changes in the nitrate and nitrite concentrations indicated that nitrate reduction is the dominant metabolic process.
Further work planned includes, sampling and analysis of water from existing boreholes, field tracer experiments, laboratory investigation of degradative potential in columns of weathered basalt (including with various "amendments"), research on microbial strains capable of degrading munitions, and modelling to determine plume-scale estimates of degradation rates and of the fate of the munition plume in the long term.

Acknowledgements


Dames & Moore would like to thank the following people for providing significant background information and documentation for this Study: Mr Geoff Davis, Assistant Secretary - Resources and Project Management, Department of Defence, Canberra; Mr John Ashe, Assistant Secretary - Environment Assessment Branch, Environment Protection Agency, Canberra; Mr Leigh Edwards, Assistant to First Assistant Secretary of Facilities and Property Division of the Department of Defence, Canberra; Richard Dale, Project Officer with the Government and Infrastructure Section - Environment Assessment Branch of the Environment Protection Agency, Canberra; Mr Pat Davoren, Manager, Rehabilitation/Radioactive Waste Policy, Mineral Industries and Nuclear Policy Branch of the Department of Primary Industries and Energy. Dames & Moore would also like to thank the large number of staff of both the Department of Defence and the Environment Protection Agency who very kindly assisted Dames & Moore either by finding references, by providing verbal information, or by pointing the way to available information sources.

References


Australian National Audit Office: "Draft Criteria for the Efficiency Audit on the Management of Commonwealth Contaminated Sites" . October 1995, (Audit results due mid 1996)
Australian and New Zealand Environment and Conservation Council and National Health and Medical Research Council (ANZECC/NH&MRC): Australian and New Zealand Guidelines for the Assessment and Management of Contaminated Sites. Pages 1-14. January 1992
Australian and New Zealand Environment and Conservation Council (ANZECC): Draft Guidelines for the Analysis of Contaminated Soils. June 1995
Australian and New Zealand Environment and Conservation Council (ANZECC): National Water Quality Management Strategy - Australian Water Quality Guidelines for Fresh & Marine Waters. November 1992
Australian and New Zealand Environment and Conservation Council (ANZECC): Draft Guidelines for the Analysis of Contaminated Soils. June 1995
Commonwealth of Australia: Intergovernmental Agreement on the Environment. May 1992
Commonwealth Government Media Reference MIN 58/95 Announcing Sale of Newington Armaments Depot to the NSW Government. 30 June 1995
Davy, D.R., Davoren, P.J., and Collett, A.C.: "Test site Clean-Up - the Maralinga Rehabilitation Project. US Department of Energy Risk Assessment Forum, Charleston South Carolina. 1996
Department of Defence (Navy Office): Defence Instructions (Navy) OPS 19-1 - Policy for the Disposal of Shipborne Wastes. Commonwealth of Australia. December 1994
Department of Defence (Assistant Chief of the Defence Force for Logistics): Commonwealth Policy on the Management of Land Affected by Unexploded Ordnance. Commonwealth of Australia. November 1990
Department of Defence: Medium Works contract (1994 version) "95/678 - DSTO Salisbury Site Remediation - Phase 2". 1994
Department of Defence: Facilities and Property Plan - 1995-2000. Commonwealth of Australia, Pages 1-3, 22-27. July 1995
Department of Manufacturing and Industry Development Victoria: Arsenic in the Environment. Page 38. February 1991
Directorate of Environment & Heritage, Facilities & Property Division, DoD: Trilateral on Environmental Security Cooperation - Australia-Canada-USA - The Clean-up of Contaminated Sites. Commonwealth of Australia. November 1995
Environment Protection Authority of New South Wales: Draft Guidelines for Consultants Reporting on Contaminated Soils. August 1995
Environment Protection Authority of New South Wales: Contaminated Sites - Sampling Design Guidelines. September 1995
Environment Protection Division, Department of the Arts, Sport, the Environment, Tourism and Territories: Proposed Commonwealth Environment Protection Agency -Position Paper for Public Comment. Commonwealth of Australia, Pages 4-20. July 1991
Environment Protection Agency: National Environment Protection Council. Commonwealth of Australia, Environment Protection Agency - Information Bulletin. December 1995
EPA Victoria: Guidelines For Environmental Auditors - Contaminated Land - Issue of Certificates of Environmental Audit. April 1991
EPA Victoria: Draft Guidelines For Environmental Auditors - (Contaminated Land) - Conducting Environmental Audits of Land. June 1995
EPA Victoria: Personal communication from Mr Phil Sinclair of Environmental Chemicals Branch. December 1995
Federal Ministry of Education Science Research and Technology: International Experience in Remediation of Contaminated Sites - Synopsis, Evaluation and Assessment of the Applicability of Methods and Concepts. Germany. July 1995
Geosafe Corporation: In Situ Vitrification Fact Sheet 11/94.
Langley A J, El Saadi O (eds). South Australian Health Commission: Protocol for the Health Risk Assessment and Management of Contaminated Sites. 1991
Ministry of Housing, Physical Planning and Environment, Staatsuitgeverij: Soil Protection Guideline .The Hague, Netherlands. 1983, rev 1991
Ministry of Housing, Physical Planning and Environment, Staatsuitgeverij: Intervention Values for the clean-up of soils. The Hague, Netherlands. 1993
Rolfe G. Hartley: Overseas Practices in the Assessment and Remediation of Contaminated Military Sites. Former Director Environment and Heritage, Facilities and Property Division, Department of Defence, Internal report. October 1995
Department of Primary Industries and Energy: Rehabilitation of Former British Nuclear Test Sites in Australia, Report by the Technical Assessment Group. Australian Government Publishing Service, Canberra (1990).
Royal Australian Survey Corps for Department of Defence Facilities & Property Division: Map of Commonwealth Owned Defence Establishments and Significant Leased Properties within Australia. March 1993
Standards Australia: DRAFT Australian Standard - Analysis of Soils - The Sampling of Potentially Contaminated Soil (April 1995)
Tozer, N.H., Crain, P., Truong, T.: "The Application of Low Temperature Thermal Desorption for the Removal of Explosives Residues From Soil" Proceedings of the 2nd National Hazardous & Solid Waste Convention - Melbourne Victoria - Pages 460-467. May 1994
Toze, S., Zappia. L., and Davis, G.B.: "Mobility and Degradation of Munition Residues in Fractured Rock Aquifers at the Albion Explosives Factory, Melbourne" Ninth Progress Report to The Department of Defence - prepared by the Centre for Groundwater Studies, CSIRO Division of Water Resources, Western Australia. October-December 1995. Report No 96-8. 1995
USEPA: Test Methods for Evaluation Solid Waste. Publication SW-846, third edition. 1986
Victorian Department of Planning and Environment: Minister's Direction - Potentially Contaminated Land. Commonwealth of Australia. 9 October 1989, updated 14 May 1992
Thompson, L. and Costello, J.M.: Vitrification of TRU-Contaminated Buried Waste: Results from Radioactive Demonstrations at Taranaki. Proceedings of the Symposium on Waste Management at Tucson Arizona 1996. 1996
Withers, N. J.: Embracing Risk Management - The Homebush - Newington Experience. Report of DoD and Olympic Committee - Sydney 2000. November 1995

Appendix

Appendix 2-1:

ANZECC Contamination Assessment Criteria
The information below outlines the current criteria used to assess soil and groundwater contamination in Australia.
ANZECC Guidelines: Contaminated Sites
The "Guidelines for the Assessment and Management of Contaminated Sites", known as the ANZECC/NHMRC guidelines have been adopted by most EPAs and Commonwealth agencies for the assessment and management of contaminated sites.
These environmental soil quality guidelines quote "background" (A Level) and "environmental investigation" (B Level) criteria for a range of contaminants. The guidelines propose the use of site-specific criteria for soil and groundwater depending on the proposed land use and the potential exposure pathways for humans and environmental impairment.
Australian authorities generally comply with the guidelines for assessment and management of contaminated sites (ANZECC/NHMRC, 1992) which include decision making procedures on the need for a detailed site investigation or remedial action. These guidelines contain recommendations for interim A and B levels, where:
- A level = concentration representative of background in soils for which Australian data is available for most contaminants of concern. Should be viewed as indicative values, particularly as the natural levels of a range of chemicals vary tremendously.
- B level = investigation threshold level concentration above which a detailed investigation should take place; the detail of the investigation depending on site specific factors.
These levels are shown in Table 2.-1-1.
Where levels exceed the investigation criteria, further investigation may include human health and/or ecological risk assessments to establish site specific clean-up criteria.

Water Quality Criteria


In assessing potential contamination of groundwater, the criteria that are commonly used for reference (in Victoria) are those published by ANZECC in the "National Water Quality Guidelines for Fresh and Marine Waters", November 1992 and the Dutch "B" criteria for groundwater .
The ANZECC criteria are specified criteria for surface and groundwater in Victoria and the tests on water samples from the site are compared with the ANZECC water quality guidelines for raw waters for drinking purposes. The relevant criteria are summarised in Table 2.-1-2. Guideline values for stock waters, irrigation or marine or fresh water ecosystem protection are in many instances significantly greater than those listed in Table 2.-1-2 and should be referenced separately where relevant.


Table 2.-1-1: Guidelines for Assessment of Soil Contamination




Indicator


A= Reference Level


B= Investigation Threshold


Monocyclic Aromatic Hydrocarbons




* Benzene
* Toluene


0.05 - 1
0.1 - 1


1


Polycyclic Aromatic Hydrocarbons




* Benzo(a)Pyrene (1)
* Total(1)


0.95 - 5


(1)
(20)


Pesticides




* Aldrin
* Dieldrin
* DDT


<0.001 - <0.05
<0.005 - <0.05
<0.001 - 0.97


0.2


Chlorinated Hydrocarbons




* PCB (Total)


0.02 - 0.1


1


Phenolic Compounds




* Phenols


0.03 - 0.05


Table 2.-1-1 (continued): Guidelines for Assessment of Soil Contamination




Indicator


A= Reference Level


B= Investigation Threshold


Heavy Metals




* Antimony (Sb)
* Arsenic (As) (1)
* Barium (Ba)
* Cadmium (Cd) (1)
* Cobalt (Co)
* Chromium (Cr)
* Copper (Cu)
* Lead (Pb) (1)
* Mercury (Hg)
* Manganese (Mn)
* Molybdenum (Mo)
* Nickel (Ni)
* Tin (Sn)
* Zinc (Zn)


4 - 44
0.2 - 30
20 - 200
0.04 - 2
2 - 170
0.5 - 110
1 - 190
<2 - 200
0.001 - 0.1
4 - 12,600
<1 - 20
2 - 400
1 - 25
2 - 180


20
20 (100)
-
3 (20)
-
50
60
300 (300)
1
500
-
60
50
200


Other Chemicals/Parameters




* Sulphate
* pH (pH units)


35 -1000
6 - 8


2000


Soil Concentration Guidelines (all concentrations are in mg/kg in air-dried soil)
Note: (1) The Australian B levels are environmental investigation levels (relevant where the primary concern is for environmental effects), except for PAHs (benzo(a)pyrene and total PAH) and the values also in brackets for As, Cd and Pb, which are health investigation thresholds (where the potential concern is human health effects).


Table 2.-1-2:
Summary of ANZECC Quality Guidelines for Raw Waters for Drinking Purposes



Parameter


Guideline values
(mg/L, unless otherwise stated)


Toxic Inorganic Parameters



Arsenic
Asbestos
Barium
Boron
Cadmium
Chromium
Cyanide
Lead
Mercury
Nickel
Nitrate-N
Nitrite-N
Selenium
Silver


0.05
NR
1.0
1.0
0.005
0.05
0.1
0.05
0.001
0.1
10.0
1.0
0.01
0.05


Organic Contaminants:



Benzene
Benzo(a)pyrene
Carbon tetrachloride
1,1-Dichloroethene
1,2-Dichloroethane
Pentachlorophenol
Polychlorinated biphenyls
Tetrachloroethene
2,3,4,6-Tetrachlorophenol
Trichloroethene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol


10.0µg/L
0.01µg/L
3.0µg/L
0.3µg/L
10.0µg/L
10.0µg/L
0.1µg/L
10.0µg/L
1.0µg/L
30.0µg/L
1.0µg/L
10.0µg/L


Other Chemicals/Parameters:



Aluminium
Ammonia(as N)
Chloride
Copper
Oxygen
Hardness (as CaC03)
Iron
Mangaese
Organics (CCE & CAE)
pH
Phenolics
Sodium
Sulfate
Sulfide
Surfactant (MBAS)
Total dissolved solids
Zinc


0.2
0.01
400.0
1.0
>6.5(>80% saturation)
500.0
0.3
0.1
0.2
6.5-8.5
0.002
300.0
400.0
0.05
0.2
1,000.0
5.0

Appendix 2-2:


Site Use


Suspected range of Contaminants


Contaminants Detected


Significant Contamination Reported


Major Military Bases & Training Areas


PAHs, TPH, Heavy Metals, (As, Cu, Cr, Cd, Ni, Pb, Zn, Hg, Ag)
Explosives, UXO,
Halogenated, Hydrocarbons,
Solvents (BTEX),
Asbestos, Organochloride, Pesticides, PCBs,
Phosphates


PAHs, TPH, Heavy Metals (Commonly As,Cu,Pb,Zn)
UXO & Explosives, Residues, Asbestos,
Organochloride Pesticides


UXO, TPH, PAH,
Heavy Metals,
OC Pesticides


Armaments Factories


PAHs, TPH, Heavy Metals (As, Cu, Cd, Cr, Co,Mn,Mo,Ni,Pb,Zn,Hg,Se), Halogenated, Hydrocarbons,
Solvents - MAHs (BTEX), Chlorinated Volatile Organics,
Phenols, Asbestos
PCBs, Cyanide


PAHs, TPH, volatile/semi volatile chlorinated
hydrocarbons,
MAHs-(Benzene),
Phenols, As, Cd, Cr, Cu, Co, Pb, Ni, Mn, Mo, Se,Zn
Phthalates, Cyanide, PCBs, Asbestos.


TPHs, volatile and semi-volatile chlorinated hydrocarbons Phenols, Cu, Cr, Cd, Asbestos


Appendix 2-2: (continued)





Site Use


Suspected range of Contaminants


Contaminants Detected


Significant Contamination Reported


Explosives Manufacturing Plants


Explosives Residues including: 2,4 DNT, 2,4,6 TNT, MNT, RDX, nitroglycerine, nitrocellulose
Chemicals including:
Acetone, Ammonium nitrate, Acids and Alkalies (sulphuric, nitric, ammonia, sodium hydroxide) calcium cyanamide, ethylene glycol, methanol, bis(2-ethylhexyl)adipate, dibutyl phthalate, isopropyl nitrate, Pentachlorophenol
Metals including: aluminium, lead, copper, mercury, silver, Lacquers and paints
War chemicals
(eg. mustard gas, phosgene and napalm)
Petroleum Hydrocarbons, PAHs, Solvents


2,4 DNT, 2,4,6 TNT,
MNT, RDX, Nitro-glycerine, Carbamite,
Petroleum Hydrocarbons,
Toluene, Organic Carbon,
Hg, Pb, Ba, Cr, Co, Fe, Mn, Ti, As, Be, Cd, Pb, Ni, Ag, Zn, Asbestos,
Chloride, Sulphate,
OC Pesticides, PCBs, PAHs, chlorobenzene


TNT, 2,4,-DNT,
2,6,-DNT, RDX,
Pb, Ba, Hg 1,2 dichlorobenzene, chlorobenzene,
Asbestos


Explosives Handling, Storage and Testing Sites


Heavy metals, Explosive residues including RDX, TNT, DNT etc.
Mercury fulminate, lead azide, lead styphnate,
Dioxins, Organochlorine pesticides, Petroleum hydrocarbons, volatile organic compounds Solvents, Asbestos,
Acids and electroplating wastes (metals & cyanides), radioactive wastes


Metals including: As, Ba, Bo, Cd, Cr, Cu, Pb, Hg, Zn, Ammonia,
OC pesticides, herbicides, Asbestos, UXO, & explosive residues including: RDX, Tetryl, 2,3 DNT, TNT, PAHs, BTEX, PCBs, Petroleum hydrocarbons, Halogenated hydrocarbons, Chemical warfare agents, Trichloroethylene (TCE),
Chlorobenzene, Low level gamma emitters, Magnesiumthorium alloys,


Chlorinated hydrocarbons (inc TCE) PAHs, TPH, benzene, toluene, Metals including: As, Cr, Cu, Pb, Hg, Zn
Ammonia
Radioactive wastes, Asbestos,
UXO, Pesticides
Herbicides


Naval Dockyards
& Shore Bases


Petroleum hydrocarbons, Solvents - MAHs,
Heavy Metals, Cyanides, Chlorinated hydrocarbons,
PCBs, PAHs, phenols, Organochlorine pesticides, Tributyltin,
Asbestos, OTTO Fuel,


Heavy Metals,
TPHs, PAHs,
Asbestos


Nuclear Test Sites


Scatter of radionuclides from atmospheric nuclear tests


Radionuclides in footprint of dispersion plumes


Plutonium


Other Sites with radioactive wastes


Radioluminescent dials and compasses (radium)
Radioactive sources: (instruments or hospital equipment), Depleted uranium ballast (aircraft & rockets), Thorium coatings (aircraft windshields), Gaseous Tritium light sources, Plutonium dispersed in soil


Radium 226, Americium 241, Strontium 90, Cobalt 60, Caesium 134/137, Tritium, Carbon 14, Plutonium 235, Europium 152. (Note: this includes civilian sources as well as CMS)


Other Sites with Unexploded Ordnance (UXO) (eg Bombing Ranges)


Unexploded shells or bombs Practice bombs, other explosive devices including mortars, grenades etc., Fragmented explosives
& detonators


Unexploded bombs, shells, and other ordnance
Detonating devices, Fragment of unexploded bombs or shells


Bombs or missiles with fuse intact, Detonating devices and unstable explosives



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[1] In the past, sheep used to be disinfected with an arsenic-based pesticides in Australia.


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